journal article·2025-02-08Open access

Review on Advancements in Carbon Nanotubes: Synthesis, Purification, and Multifaceted Applications

Anil Kumar Madikere Raghunatha Reddy, Ali Darwiche, Mogalahalli Venkatashamy Reddy, Karim Zaghib

Batteries· Volume 11· Issue 2

Abstract

Since their discovery over two decades ago, carbon nanotubes (CNTs) have captivated researchers due to their exceptional electrical, optical, mechanical, and thermal properties, making them versatile candidates for various advanced applications. CNTs have transformed numerous scientific domains, including nanotechnology, electronics, materials science, and biomedical engineering. Their applications range from nanoelectronics, robust nanocomposites, and energy storage devices to innovative materials, sensors, conducting polymers, field emission sources, and Li-ion batteries. Furthermore, CNTs have found critical roles in biosensing, water purification, bone scaffolding, and targeted gene and drug delivery. The chemical reactivity and functional versatility of CNTs are profoundly influenced by their structural and physicochemical properties, such as surface area, surface charge, size distribution, surface chemistry, and purity. This review comprehensively explores the current state of CNT research, focusing on widely used synthesis, purification, and characterization techniques alongside emerging applications. By highlighting recent advancements and addressing unresolved challenges, it aims to present a novel perspective on the transformative potential of CNTs, fostering innovation across diverse scientific and technological fields.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Supercapacitor Materials and Fabrication · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical and Materials Engineering, Concordia University, 1455 De Maisonneuve Blvd. West, Montreal, QC H3G 1M8, Canada

SOLiTHOR, Ondernemerslaan 5429, 3800 Sint-Truiden, Belgium

Nouveau Monde Graphite (NMG), Saint-Michel-des-Saints, QC J0K 3B0, Canada

Funding

Concordia University

References (100+)

Show source-provided references
1. Harris, P.J.F. (2009). Carbon Nanotube Science—Synthesis, Properties and Applications, Cambridge University Press.10.1017/CBO9780511609701 ↗
2. Filamentous growth of carbon through benzene decomposition10.1016/0022-0248(76)90115-9 ↗
3. Helical microtubules of graphitic carbon10.1038/354056a0 ↗
4. Carbon nanotubes: Synthesis and properties, electronic devices and other emerging applications10.1179/174328004X5655 ↗
5. Kaushik, B.K., Majumder, M.K., Kaushik, B.K., and Majumder, M.K. (2015). Carbon nanotube: Properties and applications. Carbon Nanotube Based VLSI Interconnects: Analysis and Design, Springer.10.1007/978-81-322-2047-3 ↗
6. Carbon nanotubes: Opportunities and challenges10.1016/S0039-6028(01)01558-8 ↗
7. Pure Carbon Nanoscale Devices: Nanotube Heterojunctions10.1103/PhysRevLett.76.971 ↗
8. Optical properties of single-wall carbon nanotubes10.1016/S0379-6779(98)00278-1 ↗
9. Carbon nanotube synthesis in a flame using laser ablation for in situ catalyst generation10.1007/s00339-003-2196-3 ↗
10. Through-skull fluorescence imaging of the brain in a new near-infrared window10.1038/nphoton.2014.166 ↗
11. Carbon materials for drug delivery & cancer therapy10.1016/S1369-7021(11)70161-4 ↗
12. Ultra-Low Doses of Chirality Sorted (6,5) Carbon Nanotubes for Simultaneous Tumor Imaging and Photothermal Therapy10.1021/nn4006472 ↗
13. Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: A review10.1016/j.compscitech.2011.11.019 ↗
14. Xiong, Z., Yun, Y., and Jin, H.-J. (2013). Applications of Carbon Nanotubes for Lithium Ion Battery Anodes. Materials, 6.10.3390/ma6031138 ↗
15. An Overview of Carbon Nanotubes: Synthesis, Purification and Characterization10.2174/13852728113179990087 ↗
16. Carbon nanotubes: Properties, synthesis, purification, and medical applications10.1186/1556-276X-9-393 ↗
17. Wang, C., Ma, L., and Yang, W. (2011). Advanced Polymer Science and Engineering, Proceedings of the Advanced Polymer Processing International Forum, Qingdao, China, 21–23 October 2010, Trans Tech Publications Ltd.
18. Bottom-Up Approach Carbon Nanotub. Interconnects10.1063/1.1566791 ↗
19. Progress and Challenges for the Bottom-Up Synthesis of Carbon Nanotubes with Discrete Chirality10.1016/j.cplett.2010.04.067 ↗
20. A Modular and Size-Selective Synthesis of [n]Cycloparaphenylenes: A Step toward the Selective Synthesis of [n,n] Single-Walled Carbon Nanotubes10.1002/anie.201005734 ↗
21. Concise Synthesis and Crystal Structure of [12]Cycloparaphenylene10.1002/ange.201007232 ↗
22. Synthesis and Racemization Process of Chiral Carbon Nanorings: A Step toward the Chemical Synthesis of Chiral Carbon Nanotubes10.1021/ol200730m ↗
23. Selective and Random Syntheses of [n]Cycloparaphenylenes (n = 8–13) and Size Dependence of Their Electronic Properties10.1021/ja2020668 ↗
24. Hydrothermal synthesis of multiwall carbon nanotubes10.1557/JMR.2000.0370 ↗
25. Synthesis of SWNTs and MWNTs by a molten salt (NaCl) method10.1016/S0009-2614(02)01447-1 ↗
26. Preparation of short carbon nanotubes by mechanical ball milling and their hydrogen adsorption behavior10.1016/S0008-6223(03)00302-6 ↗
27. Single Walled and Multi Walled Carbon Nanotube Structure, Synthesis and Applications
28. Etchant-induced shaping of nanoparticle catalysts during chemical vapour growth of carbon nanofibres
29. Effect of purification of carbon nanotubes on their electrocatalytic properties for oxygen reduction in acid solution10.1016/j.carbon.2011.05.048 ↗
30. The production of carbon nanotubes using two-stage chemical vapor deposition and their potential use in protein purification10.1016/j.cej.2011.01.045 ↗
31. Solid C60: A new form of carbon10.1038/347354a0 ↗
32. Large-scale synthesis of carbon nanotubes10.1038/358220a0 ↗
33. Patterns in the bulk growth of carbon nanotubes10.1016/0009-2614(93)87206-I ↗
34. Effect of processing conditions on the morphology and yield of carbon nanotubes10.1016/0008-6223(93)90004-T ↗
35. Preparation of Carbon Nanotubes by Arc-Discharge Evaporation10.1143/JJAP.32.L107 ↗
36. Arc discharge synthesis of carbon nanotubes: Comprehensive review10.1016/j.diamond.2014.10.001 ↗
37. The Preparation of Carbon Nanotubes10.1080/15363839408009542 ↗
38. Carbon Nanotubes Grown on the Surface of Cathode Deposit by Arc Discharge10.1080/10641229608001160 ↗
39. Preparation of high-grade carbon nanotubes by hydrogen arc discharge10.1016/S0008-6223(97)00033-X ↗
40. Morphology of carbon allotropes prepared by hydrogen arc discharge10.1016/S0022-0248(98)00995-6 ↗
41. Influence of NH3 atmosphere on the growth and structures of carbon nanotubes synthesized by the arc-discharge method10.1134/S0020168509110090 ↗
42. New synthesis of multi-walled carbon nanotubes using an arc discharge technique under organic molecular atmospheres10.1007/s003390100821 ↗
43. Single-pulse arc production of carbon nanotubes in ambient air10.1088/0022-3727/37/19/015 ↗
44. Production of carbon nanotubes by single-pulse discharge in air10.1016/j.jmatprotec.2008.10.049 ↗
45. Carbon nanotubes: A novel material for multifaceted applications in human healthcare10.1039/C6CS00517A ↗
46. High-yield synthesis of multi-walled carbon nanotubes by arc discharge in liquid nitrogen10.1007/s00339-002-1718-8 ↗
47. Synthesis of single-walled and multi-walled carbon nanotubes by arc-water method10.1016/j.carbon.2004.08.014 ↗
48. Structure of nanocarbons prepared by arc discharge in water10.1016/j.matchemphys.2007.04.022 ↗
49. The production of carbon nano-materials by arc discharge under water or liquid nitrogen10.1016/S1872-5805(08)60005-0 ↗
50. Arc discharge boron nitrogen doping of carbon nanotubes10.1016/j.mtcomm.2016.08.001 ↗
51. Double-walled carbon nanotubes fabricated by a hydrogen arc discharge method10.1016/S0008-6223(00)00187-1 ↗
52. New Synthesis of High-Quality Double-Walled Carbon Nanotubes by High-Temperature Pulsed Arc Discharge10.1021/nl034183+ ↗
53. Synthesis of double-walled carbon nanotubes from coal in hydrogen-free atmosphere10.1016/j.fuel.2006.05.024 ↗
54. Synthesis and High Thermal Stability of Double-Walled Carbon Nanotubes Using Nickel Formate Dihydrate as Catalyst Precursor10.1021/jp068672k ↗
55. Synthesis and characterization of double-walled carbon nanotubes from multi-walled carbon nanotubes by hydrogen-arc discharge10.1016/j.carbon.2004.10.028 ↗
56. Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls10.1038/363605a0 ↗
57. Radial single-layer nanotubes10.1038/366637a0 ↗
58. Improving conditions towards isolating single-shell carbon nanotubes10.1016/0009-2614(94)00739-X ↗
59. Large-scale production of single-walled carbon nanotubes by the electric-arc technique10.1038/41972 ↗
60. High yield of single-wall carbon nanotubes by arc discharge using Rh-Pt mixed catalysts10.1016/S0009-2614(98)00921-X ↗
61. Large-scale rooted growth of aligned super bundles of single-walled carbon nanotubes using a directed arc plasma method10.1016/S0009-2614(01)00631-5 ↗
62. Askeland, D.R., and Phul, P.P. (2003). The Science and Engineering of Materials, Springer.
63. Saito, R., Dresselhaus, G., and Dresselhaus, M. (1998). Physical Properties of Carbon Nanotubes, World Scientific. [4th ed.].10.1142/9781860943799 ↗
64. Raman spectroscopic and thermogravimetric studies of high-crystallinity SWNTs synthesized by FH-arc discharge method10.1016/j.diamond.2009.01.026 ↗
65. Fabrication and dispersion evaluation of single-wall carbon nanotubes produced by FH-arc discharge method10.1166/jnn.2010.2015 ↗
66. Influence of Mo on the Growth of Single-Walled Carbon Nanotubes in Arc Discharge10.1166/jnn.2010.1971 ↗
67. Improving the synthesis of single-walled carbon nanotubes by pulsed arc discharge in air by preheating the catalysts10.1016/j.carbon.2008.07.005 ↗
68. Synthesis of single-walled carbon nanotubes by low-frequency bipolar pulsed arc discharge method10.1016/j.vacuum.2014.11.025 ↗
69. C60: Buckminsterfullerene10.1038/318162a0 ↗
70. Catalytic growth of single-walled manotubes by laser vaporization10.1016/0009-2614(95)00825-O ↗
71. Dendrimers: Synthesis, applications, and properties10.1186/1556-276X-9-247 ↗
72. Production of single-wall carbon nanotubes by a XeCl excimer laser ablation10.1016/j.tsf.2005.08.037 ↗
73. Preparation and mechanical characterization of laser ablated single-walled carbon-nanotubes/polyurethane nanocomposite microbeams10.1016/j.compscitech.2009.12.004 ↗
74. Gore, J.P., Sane, A., and Yellampalli, S. (2011). Flame Synthesis of Carbon Nanotubes. Carbon Nanotubes—Synthesis, Characterization, Applications, InTech. Chapter 7.10.5772/21012 ↗
75. Crystalline Ropes of Metallic Carbon Nanotubes10.1126/science.273.5274.483 ↗
76. Methods for carbon nanotubes synthesis-review10.1039/c1jm12254a ↗
77. Catalytic growth of carbon microtubules with fullerene structure10.1063/1.109315 ↗
78. Laser Ablation Process for Single-Walled Carbon Nanotube Production10.1166/jnn.2004.072 ↗
79. Pulsed laser deposition of multiwalled carbon nanotubes thin films10.1016/j.apsusc.2007.08.045 ↗
80. A novel CW laser-powder method of carbon single-wall nanotubes production10.1016/S0925-9635(01)00641-0 ↗
81. Analytical solution to predict laser ablation rate in a graphitic target10.1007/s10853-009-4112-5 ↗
82. Pulsed laser deposition of carbon nanotube and polystyrene–carbon nanotube composite thin films10.1016/j.optlaseng.2010.06.002 ↗
83. Carbon nanotubes part I: Preparation of a novel and versatile drug-delivery vehicle10.1517/17425247.2015.1003806 ↗
84. A black body absorber from vertically aligned single-walled carbon nanotubes10.1073/pnas.0900155106 ↗
85. A Review of Carbon Nanotube Synthesis via Fluidized-Bed Chemical Vapor Deposition10.1021/ie060955b ↗
86. Chemical Vapor Deposition of Carbon Nanotubes: A Review on Growth Mechanism and Mass Production10.1166/jnn.2010.2939 ↗
87. Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes10.1126/science.1104962 ↗
88. The effects of catalyst pretreatment, growth atmosphere and temperature on carbon nanotube synthesis using Co-Mo/MgO catalyst10.1016/j.diamond.2015.10.025 ↗
89. Growth model for carbon nanotubes10.1103/PhysRevLett.69.3100 ↗
90. Synthesis and mechanical properties of carbon nanotubes produced by the water assisted CVD process10.1002/pssb.200982269 ↗
91. Nickel catalyst faceting in plasma-enhanced direct current chemical vapor deposition of carbon nanofibers
92. Carbon nanotubes: From macromolecules to nanotechnology10.1073/pnas.96.25.14199 ↗
93. Carbon Nanotubes: Synthesis, Properties, and Applications10.1080/02726350902775962 ↗
94. Carbon Nanotube Mass Production: Principles and Processes10.1002/cssc.201100177 ↗
95. Carbon nanotubes synthesis using carbonization of pretreated rice straw through chemical vapor deposition of camphor10.1039/C7RA04882C ↗
96. Synthesis of carbon nanostructures by the pyrolysis of wood sawdust in a tubular reactor10.1016/j.jmrt.2016.11.003 ↗
97. One step direct synthesis of multiwalled carbon nanotubes from coconut shell derived charcoal10.1016/j.matlet.2016.11.014 ↗
98. Single Nanotube Raman Spectroscopy10.1021/ar0101537 ↗
99. Ni-Mo and Co-Mo alloy nanoparticles for catalytic chemical vapor deposition synthesis of carbon nanotubes10.1016/j.jallcom.2014.09.220 ↗
100. Single-wall carbon nanotube–polymer solar cells10.1002/pip.604 ↗