journal article·2017-06-01Open access

Unique crystallization behavior of sodium manganese pyrophosphate Na2MnP2O7 glass and its electrochemical properties

Morito Tanabe, Tsuyoshi Honma, Takayuki Komatsu

Abstract

sCrystallization behavior of Na2MnP2O7 precursor glass was examined. Layered type Na2MnP2O7 was formed at 461 °C for 3 h in N2 filled electric furnace. Irreversible phase change was confirmed from layered Na2MnP2O7 to β-Na2MnP2O7 over 600 °C. At 650 °C crystallized phase was completely changed to β-phase. By means of charge and discharge testing it is found that layered Na2MnP2O7 is also active as cathode in sodium ion batteries. We found glass-ceramics technology is one of the suitable process for the synthesis of layered Na2MnP2O7 cathode without any complicate process.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Microwave Dielectric Ceramics Synthesis

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Affiliations

Department of Materials Science and TechnologyNagaoka University of TechnologyKamitomioka-cho 1603-1Nagaoka Niigata940-2188Japan

Funding

the Ministry of Education, Science, Sport, Culture, and Technology, Japan

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