Evaluation of microstructure evolution and mechanical properties of Al-10Zn-1.63Si/ Irvingia gabonensis particulates alloy composites

This study demonstrates the feasibility of using Irvingia gabonensis shell particulates (IGSp) as alternative reinforcing materials in the development of aluminium-based composites. In this experimental study, the microstructure, phase composition, and mechanical behaviour of Al-10Zn-1.63Si/xIGSp (wt%, x = 1, 3, 5 and 7) composites were investigated. The Al-10Zn-1.63Si based composites were fabricated using the stir-casting technique. Different weight percentages (1, 3, 5 and 7) of IGSp were added to the Al-10Zn-1.63Si matrix. The chemical constituents of the IGSp were determined using X-ray fluorescence (XRF). The grain characteristics and phase(s) compositions were determined using Scanning Electron Microscopy (SEM) and X-ray diffractometer (XRD). The ultimate tensile strength, hardness, and impact strength of the developed composites were also determined. The SEM and XRD results revealed the presence of different phases: aluminium phosphate (Al ₁₆ P ₁₆ O ₆₄ ), gahnite (ZnAl ₂ O ₄ ), andalusite (Al ₂ SiO ₅ ), Quartz (SiO ₂ ) and aluminium silicate (Al ₂ O _3.5 .SiO ₂ ). Results show that addition of IGSp led to an increase in ultimate tensile strength, with the highest value (128 MPa) obtained at 3 wt% IGSp. The hardness of the composites increased with increasing concentrations of IGSp, reaching a maximum value of 285 HV after adding 7 wt% IGSp. The impact strength improved with the addition of IGSp, with the highest value (30 J) obtained at 1 wt% IGSp. The improvements in mechanical properties were attributed to the dispersion of three major phases: aluminium silicate (Al ₂ O _3.54. SiO ₂ ), Al ₁₆ P ₁₆ O ₆₄ and Al ₂ O _3.54. SiO ₂ . These phases contributed to the enhanced strength and hardness of the composites. The study noted a sudden decrease in ultimate tensile strength with higher concentrations of IGSp due to the increase in the intensities of Al ₁₆ P ₁₆ O ₆₄ and precipitation of hard but brittle new phase; Al ₂ Si _60. 6O126.33. The study concludes that IGSp has the potential to serve as an alternative reinforcing material for aluminium-based composites.