journal article·2012-07-31Open access

Experimental Investigation on Reaction Rate and Self-healing Ability in Fly Ash Blended Cement Mixtures

Seung Hyun Na, Yukio Hama, Madoka Taniguchi, Osamu Katsura, Takahiro Sagawa, Mohamed Zakaria

Abstract

This paper investigates the hydration rate in fly ash blended cement paste and self-healing ability in mortar incorporating fly ash for long-term period. The hydration rate of fly ash and consumption of calcium hydroxide in fly ash paste containing calcium hydroxide reagents were examined at different ages and curing temperatures. Five types of fly ash blended cement paste, each of which with 10% by mass fly ash replacement ratio, were prepared for the acceleration test at 80°C. Four fly ash cement pastes, with two types of fly ash and with fly ash replacement ratios by mass 10% and 30%, were tested to measure the rate of reaction of fly ash in the mixtures. Ten mixtures were tested to evaluate the self-healing ability of mortar incorporating fly ash, considering different types of cement and fly ash. Compressive strength, bending strength, accelerated carbonation depth, after applying freeze/thaw cycling until 60% and 80% relative dynamic modulus of elasticity, and porosity were examined. The experimental results revealed that incorporating fly ash in cement paste would affect the hydration rate of fly ash and consumption of calcium hydroxide. Curing temperature can affect hydration rate, acceleration rate and velocity of reaction rate in fly ash cement paste. Moreover, it is confirmed that self-healing ability, carbonation rate coefficient and the pore volume modification in mortar incorporating fly ash rely on the curing conditions. Finally, it is suggested that the practical fly ash replacement ratio in concrete could be 10% to 15% and 11% to 20% for water to cement ratios 0.50 to 0.55 and 0.55 to 0.60, respectively.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Concrete and Cement Materials Research · Concrete Properties and Behavior · Microbial Applications in Construction Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Graduate School of Engineering, Muroran Institute of Technology, Hokkaido, Japan.

Environmental Engineering Division, Northern Regional Building Research Institute, Hokkaido Research Organization, Hokkaido, Japan.

Nittetsu Cement Co. Ltd., Product Development Department, Muroran, Hokkaido, Japan.

Dept. of Civil Engineering, Aswan Faculty of Engineering, Aswan University, Aswan, Egypt.

References (21)

Show source-provided references
1. Asaga, K., Ishizaki., M., Takahashi, K. and Konishi, K., (1992). “Effect of curing temperature on the hydration of portland cement compounds.” In: 9th International Congress on the Chemistry of Cement, 4, 181-187.
2. de Larrard, F., (2002). Construire en beton, ENPC Press, Paris.
3. Delmi, M. M. Y., (2004). Etude de l'hydratation et du couplage carbonatation-echanges hydriques dans les mortiers et betons. PhD Thesis of the University of La Rochelle.
4. Hoshino, S., Hirao, H., and Yamada, K., (2005). “The application of XRD/Rietveld method to cements with amorphous admixture as quantitative tool of mineral composition.” Cement Science and Concrete Technology, 59, 14-21. (in Japanese)
5. Itoh, T., Masaki, K. and Igarashi, H., (2002). “Relationship between property of early hydration of cement and aluminate contents determined by rietveld method.” Cement Science and Concrete Technology, 56, 29-35. (in Japanese)
6. Izumi, F. and Ikeda, T., (2000). “A Rietveld-analysis program RIETAN-98 and its application to Zeolites.” Mater. Sci. Forum, 321-324.
7. JCI, (2009). “Technical committee reports on autogenous healing in cementitious materials.” Tokyo, Japan Concrete Institute. (in Japanese)
8. Koh, E. and Hasegawa, T., (1981), “On the test method for resistance of concrete to freezing and thawing.” Concrete Journal, 16 (9), 16-22. (in Japanese)10.3151/coj1975.19.9_16 ↗
9. Matsui, J. and Ikabata, T., (1999). “Hydration rate and strength development of low heat portland cement with large amount of pozzolan.” Cement Science and Concrete Technology, 53, 229-236. (in Japanese)
10. Matsumura, T. Katsura O. and Yoshino, T., (2003), “Properties of frost damaged concrete and the estimation of the degree of frost damage.” Journal of Structural and Construction Engineering, Transaction of AIJ, 563, 9-13.10.3130/aijs.68.9_1 ↗
11. Ohsawa, S., Sakai, E. and Daimon, M., (1999). “Reaction ratio of fly ash in the hydration of fly ash-cement system.” Cement Science and Concrete Technology, 53, 96-101. (in Japanese)
12. Saeki, T., and Monteiro, P. J. M., (2004). “A model to predict the amount of calcium hydroxide in concrete containing mineral admixtures.” Cement and Concrete Research, 35(10), 1914-1921.10.1016/j.cemconres.2004.11.018 ↗
13. Saeki, T. and Nagataki, S., (1997). “Fundamental study on reaction between fly ash and calcium hydroxide.” JCA proceedings of cement and concrete, 51, 162-167. (in Japanese)
14. Sagawa, T., Katsura, O., Sekiguchi, T. and Wakasugi, S., (2004). “Effect of water to cement ratio and curing condition on hydration of portland cement compounds.” Cement Science and Concrete Technology, 58, 23-30. (in Japanese)
15. Sagawa, T. Katsura, O., Sekiguchi, T. and Wakasugi, S., (2005). “Hydration rate of portland cement compounds and strength development in consideration of particel size distribution.” Cement Science and Concrete Technology, 59, 45-52. (in Japanese)
16. Scrivener, K.L., Füllmann, T., Gallucci, E., Walenta, G. and Bermejo, E., (2004). “Quantitative study of portland cement hydration by X-ray diffraction/Rietveld analysis and independent methods” Cement and Concrete Research, 34(9), 1541-1547.
17. Termkhajornkit, P., Nawa, T., Nakai, M. and Saito, T., (2005). “Effect of fly ash on autogenous shrinkage.” Cement and Concrete Research, 35(3), 473-482.10.1016/j.cemconres.2004.07.010 ↗
18. Termkhajornkit, P., Nawa, T., Yamashiro, Y. and Saito, T., (2009). “Self-healing ability of fly ash-cement systems.” Cement and Concrete Composites, 31, 195-203.10.1016/j.cemconcomp.2008.12.009 ↗
19. Whitfield, P. S. and Mitchell, L. D., (2003). “Quantitative Rietveld analysis of the amorphous content in cements and clinkers.” Journal of Materials Science, 38(21), 4415-4421.10.1023/A:1026363906432 ↗
20. Yamaguchi, G., Takemoto, H. and Uchikawa, H., (1960). “Rate of hydration of cement compounds and portland cement estimated by X-ray diffraction analysis.” In: 4th International Symposium on Chemistry of Cement, 1, 496-499.
21. Yamamoto, T. and Kanazu, T., (2004). “Investigation on the pozzolanic reaction of fly ash-clarification of the mechanism of pozzolanic reaction and optimization of accelerated chemical test (API method).” Laboratory Rep. No.N04008, Central Res. Inst. of Electric Power Industry, Civil Engineering Research.