journal article·2026-06Open access

Multicomponent hexaborides with high infrared emissivity and low thermal conductivity for ultra-high temperature thermal protection applications

Xin Wang, Mohan Zhang, Di Wu, Jianyu Li, Tao Chen, Minzhong Huang, Liyan Xue, Kaixian Wang, Ting Zhou, Xiaohui Ma, Huimin Xiang, Fan Yang, Heng Chen

Journal of Advanced Ceramics· Volume 15· Issue 6

Abstract

Abstract As the flight speed of hypersonic vehicles increases, the airframe temperature rises sharply, which puts forward greater demands for ultrahigh temperature thermal protection materials with high infrared emissivity and low thermal conductivity. In this work, LaB6, (La1/3Eu1/3Ca1/3)B6 (MEB6), and (La1/5Eu1/5Ca1/5Ba1/5Sr1/5)B6 (HEB6) were prepared by boron–carbon thermal reduction and spark plasma sintering. To regulate the thermal conductivity and infrared emissivity, alkaline earth metal elements are introduced into the design of multicomponent hexaborides. Among them, the infrared emissivity of HEB6 in the 1.28–5 μm wavelength range increased from 81.487% to 95.662% compared to LaB6. Compared with LaB6, the thermal conductivity of HEB6 is reduced significantly from 57.640 to 17.041 W·m−1·K−1. Among all samples, HEB6 exhibited the lowest electrical conductivity of 2952.667 S·cm−1, which was much lower than that of LaB6 (75,826.000 S·cm−1). This strategy improves the infrared emissivity and reduces thermal conductivity. On the one hand, the introduction of alkaline earth metals reduces the electron density of the material and modulates the electronic band structure, thereby reducing the conductivity and increasing the infrared emissivity. On the other hand, large atomic mass and size differences aggravate the asymmetry of crystal structural units, resulting in enhanced phonon scattering and reduced thermal conductivity. Hence, the increase in emissivity and the decrease in thermal conductivity are simultaneously regulated, providing a new strategy for the development of thermal protection materials for hypersonic vehicles.
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Research context

OpenAlex topics: Thermal properties of materials · Carbon Nanotubes in Composites · Advanced Thermoelectric Materials and Devices

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