Low dielectric loss in vanadium-based zircon ceramics via high-entropy strategy

Zircon ceramics have potential applications in next-generation wireless communication because of their low permittivity and adjustable temperature coefficient in microwave frequency. However, the vast challenge of realizing ultra-low dielectric loss still existed. Here, we propose a high-entropy strategy to enhance the bonding of the A-site dodecahedron in zircon and design (Nd_0.2Eu_0.2Y_0.2Ho_0.2Yb_0.2)VO₄ ceramic with a high quality factor (high Q×f, that is, low dielectric loss). The (Nd_0.2Eu_0.2Y_0.2Ho_0.2Yb_0.2)VO₄ high-entropy ceramic, which belongs to the tetragonal zircon structure with the I4₁/amd space group, exhibits low permittivity (ε_r = 11.55), a negative temperature coefficient of resonant frequency (τ_f = -37.3 ppm/°C), and a high Q×f of 76,400 GHz (at 12.31 GHz). The high Q×f value can be attributed to the high chemical bond strength and structural stability. Furthermore, the relationship between the crystal structure and the microwave dielectric properties of (Nd_0.2Eu_0.2Y_0.2Ho_0.2Yb_0.2)VO₄ high-entropy ceramic has been analyzed through the HR-TEM, Raman, far-infrared reflection spectrum, and chemical bond theory. This work provides an effective avenue to design microwave dielectric materials with low loss to meet the demanding applications of passive components.