Organosilicon polymer-derived ceramics: An overview
Source abstract
Abstract
Abstract Polymer-derived ceramics (PDCs) strategy shows a great deal of advantages for the fabrication of advanced ceramics. Organosilicon polymers facilitate the shaping process and different silicon-based ceramics with controllable components can be fabricated by modifying organosilicon polymers or adding fillers. It is worth noting that silicate ceramics can also be fabricated from organosilicon polymers by the introduction of active fillers, which could react with the produced silica during pyrolysis. The organosilicon polymer-derived ceramics show many unique properties, which have attracted many attentions in various fields. This review summarizes the typical organosilicon polymers and the processing of organosilicon polymers to fabricate silicon-based ceramics, especially highlights the three-dimensional (3D) printing technique for shaping the organosilicon polymer- derived ceramics, which makes the possibility to fabricate silicon-based ceramics with complex structure. More importantly, the recent studies on fabricating typical non-oxide and silicate ceramics derived from organosilicon polymers and their biomedical applications are highlighted.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advanced ceramic materials synthesis · Bone Tissue Engineering Materials · Ferroelectric and Piezoelectric Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Zhao ZG, Li KZ, Li W, et al. Preparation, ablation behavior and mechanism of C/C-ZrC-SiC and C/C-SiC composites. Ceram Int 2018, 44: 7481–7490.10.1016/j.ceramint.2018.01.125 ↗
2. Du B, Hong CQ, Zhang XH, et al. Preparation and mechanical behaviors of SiOC-modified carbon-bonded carbon fiber composite with in situ growth of three-dimensional SiC nanowires. J Eur Ceram Soc 2018, 38: 2272–2278.10.1016/j.jeurceramsoc.2018.01.002 ↗
3. Zhang LL, Pei LN, Li HJ, et al. Preparation and characterization of Na and F co-doped hydroxyapatite coating reinforced by carbon nanotubes and SiC nanoparticles. Mater Lett 2018, 218: 161–164.10.1016/j.matlet.2018.01.158 ↗
4. Idesaki A, Colombo P. Synthesis of a Ni-containing porous SiOC material from polyphenylmethylsiloxane by a direct foaming technique. Adv Eng Mater 2012, 14: 1116–1122.10.1002/adem.201100354 ↗
5. Eckel ZC, Zhou C, Martin JH, et al. Additive manufacturing of polymer-derived ceramics. Science 2016, 351: 58–62.10.1126/science.aad2688 ↗
6. Sun SY, Wang Q, Ge YY, et al. Synthesis of well-dispersed columnar Si3N4 using carbothermal reduction—nitridation method. Powder Technol 2018, 331: 322–325.10.1016/j.powtec.2018.03.046 ↗
7. Chen AN, Wu JM, Han LX, et al. Preparation of Si3N4 foams by DCC method via dispersant reaction combined with protein-gelling. J Alloys Compd 2018, 745: 262–270.10.1016/j.jallcom.2018.02.238 ↗
8. Han L, Wang JK, Li FL, et al. Low-temperature preparation of Si3N4 whiskers bonded/reinforced SiC porous ceramics via foam-gelcasting combined with catalytic nitridation. J Eur Ceram Soc 2018, 38: 1210–1218.10.1016/j.jeurceramsoc.2017.10.043 ↗
9. Nguyen VL, Zera E, Perolo A, et al. Synthesis and characterization of polymer-derived SiCN aerogel. J Eur Ceram Soc 2015, 35: 3295–3302.10.1016/j.jeurceramsoc.2015.04.018 ↗
10. Bernardo E, Parcianello G, Colombo P, et al. SiAlON ceramics from preceramic polymers and nano-sized fillers: Application in ceramic joining. J Eur Ceram Soc 2012, 32: 1329–1335.10.1016/j.jeurceramsoc.2011.02.035 ↗
11. Qing ZJ, Zhou WZ, Xia WJ, et al. Crystallization kinetics, sintering, microstructure, and properties of low temperature co-fired magnesium aluminum silicate glass-ceramic. J Non-Cryst Solids 2018, 486: 14–18.10.1016/j.jnoncrysol.2018.02.006 ↗
12. Yu QQ, Han YM, Wang XC, et al. Copper silicate hollow microspheres-incorporated scaffolds for chemo-photothermal therapy of melanoma and tissue healing. ACS Nano 2018, 12: 2695–2707.10.1021/acsnano.7b08928 ↗
13. Xu SF, Lin KL, Wang Z, et al. Reconstruction of calvarial defect of rabbits using porous calcium silicate bioactive ceramics. Biomaterials 2008, 29: 2588–2596.10.1016/j.biomaterials.2008.03.013 ↗
14. Pavarajarn V, Precharyutasin R, Praserthdam P. Synthesis of silicon nitride fibers by the carbothermal reduction and nitridation of rice husk ash. J Am Ceram Soc 2010, 93: 973–979.10.1111/j.1551-2916.2009.03530.x ↗
15. Arcos D, Vallet-Regí M. Sol–gel silica-based biomaterials and bone tissue regeneration. Acta Biomater 2010, 6: 2874–2888.10.1016/j.actbio.2010.02.012 ↗
16. Colombo P, Bernardo E, Parcianello G. Multifunctional advanced ceramics from preceramic polymers and nano-sized active fillers. J Eur Ceram Soc 2013, 33: 453–469.10.1016/j.jeurceramsoc.2012.10.006 ↗
17. Ionescu E, Kleebe HJ, Riedel R. Silicon-containing polymer-derived ceramic nanocomposites (PDC-NCs): Preparative approaches and properties. Chem Soc Rev 2012, 41: 5032–5052.10.1039/c2cs15319j ↗
18. Bernardo E, Fiocco L, Parcianello G, et al. Advanced ceramics from preceramic polymers modified at the nano-scale: A review. Materials 2014, 7: 1927–1956.10.3390/ma7031927 ↗
19. Bernard S, Miele P. Polymer-derived boron nitride: A review on the chemistry, shaping and ceramic conversion of borazine derivatives. Materials 2014, 7: 7436–7459.10.3390/ma7117436 ↗
20. Gmeiner R, Deisinger U, Schönherr J, et al. Additive manufacturing of bioactive glasses and silicate bioceramics. J Ceram Sci Tech 2015, 06: 75–86.
21. Riedel R, Mera G, Hauser R, et al. Silicon-based polymer-derived ceramics: Synthesis properties and applications-A review. J Ceram Soc Jpn 2006, 114: 425–444.10.2109/jcersj.114.425 ↗
22. Colombo P, Mera G, Riedel R, et al. Polymer-derived ceramics: 40 years of research and innovation in advanced ceramics. J Am Ceram Soc 2010, 93: 1805–183710.1111/j.1551-2916.2010.03876.x ↗
23. Zhu M, Huang T, Du X, et al. Progress of the 3D printing technology for biomaterials. Journal of University of Shanghai for Science and Technology 2017, 39: 473–489. (in Chinese)
24. Xin C, Qi X, Zhu M, et al. Hydroxyapatite whisker-reinforced composite scaffolds through 3D printing for bone repair. J Inorg Mater 2017, 32: 837–844. (in Chinese)10.15541/jim20170171 ↗
25. Du XY, Fu SY, Zhu YF. 3D printing of ceramic-based scaffolds for bone tissue engineering: An overview. J Mater Chem B 2018, 6: 4397–4412.10.1039/C8TB00677F ↗
26. Pei P, Tian ZF, Zhu YF. 3D printed mesoporous bioactive glass/metal-organic framework scaffolds with antitubercular drug delivery. Microporous Mesoporous Mater 2018, 272: 24–30.10.1016/j.micromeso.2018.06.012 ↗
27. Jones RG, Holder SJ. High-yield controlled syntheses of polysilanes by the Wurtz-type reductive coupling reaction. Polym Int 2006, 55: 711–718.10.1002/pi.1945 ↗
28. Kashimura S, Tane Y, Ishifune M, et al. Practical method for the synthesis of polysilanes using Mg and Lewis acid system. Tetrahedron Lett 2008, 49: 269–271.10.1016/j.tetlet.2007.11.088 ↗
29. Krempner C. Polysilane dendrimers. Polymers 2012, 4: 408–447.10.3390/polym4010408 ↗
30. Lodhe M, Babu N, Selvam A, et al. Synthesis and characterization of high ceramic yield polycarbosilane precursor for SiC. J Adv Ceram 2015, 4: 307–311.10.1007/s40145-015-0165-x ↗
31. Chen JX, He GM, Liao ZN, et al. Control of structure formation of polycarbosilane synthesized from polydimethylsilane by Kumada rearrangement. J Appl Polym Sci 2008, 108: 3114–3121.10.1002/app.27262 ↗
32. Cheng XZ, Xie ZF, Song YC, et al. Structure and properties of polycarbosilane synthesized from polydimethylsilane under high pressure. J Appl Polym Sci 2006, 99: 1188–1194.10.1002/app.22594 ↗
33. Wang GD, Song YC. Enhancing the yield of polycarbosilane synthesis via recycling of liquid by-product at atmospheric pressure. Ceram Int 2018, 44: 6474–6478.10.1016/j.ceramint.2018.01.045 ↗
34. He LJ, Zhang ZB, Yang XG, et al. Liquid polycarbosilanes: Synthesis and evaluation as precursors for SiC ceramic. Polym Int 2015, 64: 979–985.10.1002/pi.4889 ↗
35. Li HB, Zhang LT, Cheng LF, et al. Polymer–ceramic conversion of a highly branched liquid polycarbosilane for SiC-based ceramics. J Mater Sci 2008, 43: 2806–2811.10.1007/s10853-008-2539-8 ↗
36. Ma Y, Wang S, Chen ZH. Raman spectroscopy studies of the high-temperature evolution of the free carbon phase in polycarbosilane derived SiC ceramics. Ceram Int 2010, 36: 2455–2459.10.1016/j.ceramint.2010.08.003 ↗
37. Wang YC, Xiao P, Zhou W, et al. Microstructures, dielectric response and microwave absorption properties of polycarbosilane derived SiC powders. Ceram Int 2018, 44: 3606–3613.10.1016/j.ceramint.2017.11.101 ↗
38. Long X, Shao CW, Wang J, et al. Synthesis of soluble and meltable pre-ceramic polymers for Zr-containing ceramic nanocomposites. Appl Organometal Chem 2018, 32: e3942.10.1002/aoc.3942 ↗
39. Shukla SK, Tiwari RK, Ranjan A, et al. Some thermal studies of polysilanes and polycarbosilanes. Thermochim Acta 2004, 424: 209–217.10.1016/j.tca.2004.06.003 ↗
40. Gardelle B, Duquesne S, Vu C, et al. Thermal degradation and fire performance of polysilazane-based coatings. Thermochim Acta 2011, 519: 28–37.10.1016/j.tca.2011.02.025 ↗
41. Bakumov V, Gueinzius K, Hermann C, et al. Polysilazane-derived antibacterial silver–ceramic nanocomposites. J Eur Ceram Soc 2007, 27: 3287–3292.10.1016/j.jeurceramsoc.2007.01.004 ↗
42. Vakifahmetoglu C, Menapace I, Hirsch A, et al. Highly porous macro- and micro-cellular ceramics from a polysilazane precursor. Ceram Int 2009, 35: 3281–3290.10.1016/j.ceramint.2009.05.022 ↗
43. Günthner M, Kraus T, Dierdorf A, et al. Advanced coatings on the basis of Si(C)N precursors for protection of steel against oxidation. J Eur Ceram Soc 2009, 29: 2061–2068.10.1016/j.jeurceramsoc.2008.11.013 ↗
44. Günthner M, Wang KS, Bordia RK, et al. Conversion behaviour and resulting mechanical properties of polysilazane-based coatings. J Eur Ceram Soc 2012, 32: 1883–1892.10.1016/j.jeurceramsoc.2011.09.005 ↗
45. Chiu HT, Sukachonmakul T, Kuo MT, et al. Surface modification of aluminum nitride by polysilazane and its polymer-derived amorphous silicon oxycarbide ceramic for the enhancement of thermal conductivity in silicone rubber composite. Appl Surf Sci 2014, 292: 928–936.10.1016/j.apsusc.2013.12.081 ↗
46. Sarkar S, Zou JH, Liu JH, et al. Polymer-derived ceramic composite fibers with aligned pristine multiwalled carbon nanotubes. ACS Appl Mater Interfaces 2010, 2: 1150–1156.10.1021/am1000085 ↗
47. Hörz M, Zern A, Berger F, et al. Novel polysilazanes as precursors for silicon nitride/silicon carbide composites without “free” carbon. J Eur Ceram Soc 2005, 25: 99–110.10.1016/j.jeurceramsoc.2004.07.020 ↗
48. Kroke E, Li YL, Konetschny C, et al. Silazane derived ceramics and related materials. Mat Sci Eng R Rep 2000, 26: 97–199.10.1016/S0927-796X(00)00008-5 ↗
49. Qi GJ, Zhang CR, Hu HF, et al. Preparation of three-dimensional silica fiber reinforced silicon nitride composites using perhydropolysilazane as precursor. Mater Lett 2005, 59: 3256–3258.10.1016/j.matlet.2005.04.057 ↗
50. Sun F, Jiang SL. Synthesis and characterization of photosensitive polysiloxane. Nucl Instruments Methods Phys Res Sect B Beam Interactions Mater Atoms 2007, 254: 125–130.10.1016/j.nimb.2006.10.067 ↗
51. Li Z, Li J, Qin J, et al. Synthesis and characterization of polysiloxanes containing carbazolyl and sulfonyl-indole based chromophore as side chains. Polymer 2005, 46: 363–368.10.1016/j.polymer.2004.09.079 ↗
52. Narisawa M. Silicone resin applications for ceramic precursors and composites. Materials 2010, 3: 3518–3536.10.3390/ma3063518 ↗
53. Boehm P, Mondeshki M, Frey H. Polysiloxane-backbone block copolymers in a one-pot synthesis: A silicone platform for facile functionalization. Macromol Rapid Commun 2012, 33: 1861–1867.10.1002/marc.201200365 ↗
54. Chojnowski J, Cypryk M, Kurjata J. Organic polysilanes interrupted by heteroatoms. Prog Polym Sci 2003, 28: 691–728.10.1016/S0079-6700(02)00084-9 ↗
55. Zhou WJ, Yang H, Guo XZ, et al. Thermal degradation behaviors of some branched and linear polysiloxanes. Polym Degrad Stab 2006, 91: 1471–1475.10.1016/j.polymdegradstab.2005.10.005 ↗
56. Soraru GD. Silicon oxycarbide glasses from gels. J Sol-Gel Sci Technol 1994, 2: 843–848.10.1007/BF00486362 ↗
57. Widgeon S, Mera G, Gao Y, et al. Nanostructure and energetics of carbon-rich SiCN ceramics derived from polysilylcarbodiimides: Role of the nanodomain interfaces. Chem Mater 2012, 24: 1181–1191.10.1021/cm2038238 ↗
58. Mera G, Riedel R, Poli F, et al. Carbon-rich SiCN ceramics derived from phenyl-containing poly(silylcarbodiimides). J Eur Ceram Soc 2009, 29: 2873–2883.10.1016/j.jeurceramsoc.2009.03.026 ↗
59. Iwamoto Y, Völger W, Kroke E, et al. Crystallization behavior of amorphous silicon carbonitride ceramics derived from organometallic precursors. J Am Ceram Soc 2004, 84: 2170–2178.10.1111/j.1151-2916.2001.tb00983.x ↗
60. Oishi M, Minakawa M, Imae I, et al. Synthesis and characterization of optically active hyperbranched poly (carbosiloxane)s. Macromolecules 2002, 35: 4938–4945.10.1021/ma0120815 ↗
61. Sacarescu L, Capmare E, Ardeleanu R, et al. Hyperbranched polycyclocarbosiloxane. Eur Polym J 2002, 38: 983–987.10.1016/S0014-3057(01)00273-7 ↗
62. Hu J, Carver PI, Meier DJ, et al. Hyperbranched polycarbosiloxanes and polycarbosilanes via bimolecular non-linear hydrosilylation polymerization. Polymer 2012, 53: 5459–5468.10.1016/j.polymer.2012.09.052 ↗
63. Gao Y, Mera G, Nguyen H, et al. Processing route dramatically influencing the nanostructure of carbon-rich SiCN and SiBCN polymer-derived ceramics. Part I: Low temperature thermal transformation. J Eur Ceram Soc 2012, 32: 1857–1866.10.1016/j.jeurceramsoc.2011.09.012 ↗
64. Widgeon S, Mera G, Gao Y, et al. Effect of precursor on speciation and nanostructure of SiBCN polymer-derived ceramics. J Am Ceram Soc 2013, 96: 1651–1659.10.1111/jace.12192 ↗
65. Zhang ZB, Zeng F, Han JJ, et al. Synthesis and characterization of a new liquid polymer precursor for Si–B–C–N ceramics. J Mater Sci 2011, 46: 5940–5947.10.1007/s10853-011-5549-x ↗
66. Whittell GR, Manners I. Metallopolymers: New multifunctional materials. Adv Mater 2007, 19: 3439–3468.10.1002/adma.200702876 ↗
67. Whittell GR, Hager MD, Schubert US, et al. Functional soft materials from metallopolymers and metallosupramolecular polymers. Nat Mater 2011, 10: 176–188.10.1038/nmat2966 ↗
68. Cai T, Qiu WF, Liu D, et al. Synthesis of soluble poly-yne polymers containing zirconium and silicon and corresponding conversion to nanosized ZrC/SiC composite ceramics. Dalton Trans 2013, 42: 4285–4290.10.1039/c2dt32428h ↗
69. Yu ZJ, Yang L, Min H, et al. Single-source-precursor synthesis of high temperature stable SiC/C/Fe nanocomposites from a processable hyperbranched polyferrocenylcarbosilane with high ceramic yield. J Mater Chem C 2014, 2: 1057–1067.10.1039/C3TC32088J ↗
70. Gou Y, Tong X, Zhang Q, et al. The preparation and characterization of polymer-derived Fe/Si/C magnetoceramics. Ceram Int 2016, 42: 681–689.10.1016/j.ceramint.2015.08.165 ↗
71. Balan C, Riedel R. Rheological investigations of a polymeric precursor for ceramic materials: Experiments and theoretical modeling. J Optoelectro Adv Mater 2006, 8: 561–567.
72. Harshe R, Balan C, Riedel R. Amorphous Si(Al)OC ceramic from polysiloxanes: Bulk ceramic processing, crystallization behavior and applications. J Eur Ceram Soc 2004, 24: 3471–3482.10.1016/j.jeurceramsoc.2003.10.016 ↗
73. Bernardo E, Colombo P, Dainese E, et al. Novel 3D wollastonite-based scaffolds from preceramic polymers containing micro- and nano-sized reactive particles. Adv Eng Mater 2012, 14: 269–274.10.1002/adem.201100241 ↗
74. Bernardo E, Parcianello G, Colombo P, et al. Wollastonite foams from an extruded preceramic polymer mixed with CaCO3 microparticles assisted by supercritical carbon dioxide. Adv Eng Mater 2013, 15: 60–65.10.1002/adem.201200202 ↗
75. Zhang JH, Zhao SC, Zhu M, et al. 3D-printed magnetic Fe3O4/MBG/PCL composite scaffolds with multifunctionality of bone regeneration, local anticancer drug delivery and hyperthermia. J Mater Chem B 2014, 2: 7583–7595.10.1039/C4TB01063A ↗
76. Pei P, Wei DX, Zhu M, et al. The effect of calcium sulfate incorporation on physiochemical and biological properties of 3D-printed mesoporous calcium silicate cement scaffolds. Microporous Mesoporous Mater 2017, 241: 11–20.10.1016/j.micromeso.2016.11.031 ↗
77. Du XY, Yu B, Pei P, et al. 3D printing of pearl/CaSO4 composite scaffolds for bone regeneration. J Mater Chem B 2018, 6: 499–509.10.1039/C7TB02667F ↗
78. Pei P, Qi X, Du XY, et al. Three-dimensional printing of tricalcium silicate/mesoporous bioactive glass cement scaffolds for bone regeneration. J Mater Chem B 2016, 4: 7452–7463.10.1039/C6TB02055K ↗
79. Zhang JH, Zhao SC, Zhu YF, et al. Three-dimensional printing of strontium-containing mesoporous bioactive glass scaffolds for bone regeneration. Acta Biomater 2014, 10: 2269–2281.10.1016/j.actbio.2014.01.001 ↗
80. Zhang JH, Zhu YF. Synthesis and characterization of CeO2-incorporated mesoporous calcium-silicate materials. Microporous Mesoporous Mater 2014, 197: 244–251.10.1016/j.micromeso.2014.06.018 ↗
81. Qi X, Pei P, Zhu M, et al. Three dimensional printing of calcium sulfate and mesoporous bioactive glass scaffolds for improving bone regeneration in vitro and in vivo. Sci Rep 2017, 7: 42556.10.1038/srep42556 ↗
82. Yu B, Pei P, Yu BQ, et al. Enhance the bioactivity and osseointegration of the polyethylene-terephthalate-based artificial ligament via poly(dopamine) coating with mesoporous bioactive glass. Adv Eng Mater 2017, 19: 1600708.10.1002/adem.201600708 ↗
83. Li S, Duan WY, Zhao T, et al. The fabrication of SiBCN ceramic components from preceramic polymers by digital light processing (DLP) 3D printing technology. J Eur Ceram Soc 2018, 38: 4597–4603.10.1016/j.jeurceramsoc.2018.06.046 ↗
84. Zanchetta E, Cattaldo M, Franchin G, et al. Stereolithography of SiOC ceramic microcomponents. Adv Mater 2016, 28: 370–376.10.1002/adma.201503470 ↗
85. Fu YL, Xu G, Chen ZW, et al. Multiple metals doped polymer-derived SiOC ceramics for 3D printing. Ceram Int 2018, 44: 11030–11038.10.1016/j.ceramint.2018.03.075 ↗
86. De Hazan Y, Penner D. SiC and SiOC ceramic articles produced by stereolithography of acrylate modified polycarbosilane systems. J Eur Ceram Soc 2017, 37: 5205–5212.10.1016/j.jeurceramsoc.2017.03.021 ↗
87. Zocca A, Gomes CM, Staude A, et al. SiOC ceramics with ordered porosity by 3D-printing of a preceramic polymer. J Mater Res 2013, 28: 2243–2252.10.1557/jmr.2013.129 ↗
88. Chen HH, Wang XF, Xue FD, et al. 3D printing of SiC ceramic: Direct ink writing with a solution of preceramic polymers. J Eur Ceram Soc 2018, 38: 5294–5300.10.1016/j.jeurceramsoc.2018.08.009 ↗
89. Pierin G, Grotta C, Colombo P, et al. Direct Ink Writing of micrometric SiOC ceramic structures using a preceramic polymer. J Eur Ceram Soc 2016, 36: 1589–1594.10.1016/j.jeurceramsoc.2016.01.047 ↗
90. Zocca A, Franchin G, Elsayed H, et al. Direct ink writing of a preceramic polymer and fillers to produce hardystonite (Ca2ZnSi2O7) bioceramic scaffolds. J Am Ceram Soc 2016, 99: 1960–1967.10.1111/jace.14213 ↗
91. Elsayed H, Sinico M, Secco M, et al. B-doped hardystonite bioceramics from preceramic polymers and fillers: Synthesis and application to foams and 3D-printed scaffolds. J Eur Ceram Soc 2017, 37: 1757–1767.10.1016/j.jeurceramsoc.2016.12.002 ↗
92. Fiocco L, Elsayed H, Badocco D, et al. Direct ink writing of silica-bonded calcite scaffolds from preceramic polymers and fillers. Biofabrication 2017, 9: 025012.10.1088/1758-5090/aa6c37 ↗
93. Elsayed H, Colombo P, Bernardo E. Direct ink writing of wollastonite-diopside glass-ceramic scaffolds from a silicone resin and engineered fillers. J Eur Ceram Soc 2017, 37: 4187–4195.10.1016/j.jeurceramsoc.2017.05.021 ↗
94. Zocca A, Elsayed H, Bernardo E, et al. 3D-printed silicate porous bioceramics using a non-sacrificial preceramic polymer binder. Biofabrication 2015, 7: 025008.10.1088/1758-5090/7/2/025008 ↗
95. Mishra MK, Kumar S, Ranjan A, et al. Processing, properties and microstructure of SiC foam derived from epoxy-modified polycarbosilane. Ceram Int 2018, 44: 1859–1867.10.1016/j.ceramint.2017.10.123 ↗
96. Ma Y, Wang S, Chen ZH. Effects of high-temperature annealing on the microstructures and mechanical properties of Cf/SiC composites using polycarbosilane. Mat Sci Eng A 2011, 528: 3069–3072.10.1016/j.msea.2010.12.095 ↗
97. Liu J, Qiao YL, Zhang P, et al. Synthesis of SiC ceramics from polysilazane by laser pyrolysis. Surf Coat Technol 2017, 321: 491–495.10.1016/j.surfcoat.2017.05.021 ↗
98. Yan J, Wang AJ, Kim DP. Preparation of ordered mesoporous SiC from preceramic polymer templated by nanoporous silica. J Phys Chem B 2006, 110: 5429–5433.10.1021/jp057378+ ↗
99. Eick BM, Youngblood JP. SiC nanofibers by pyrolysis of electrospun preceramic polymers. J Mater Sci 2009, 44: 160–165.10.1007/s10853-008-3102-3 ↗
100. Boakye EE, Mogilevsky P, Parthasarathy TA, et al. Monazite coatings on SiC fibers I: Fiber strength and thermal stability. J Am Ceram Soc 2006, 89: 3475–3480.10.1111/j.1551-2916.2006.01288.x ↗