journal article·2021-10Open access

NUV-pumped luminescence of thermally stable samarium-activated alkali metal borophosphate phosphor

Zhenyu Fang, Dan Yang, Youkui Zheng, Jialiang Song, Tongsheng Yang, Ruitong Song, Yuefei Xiang, Jing Zhu

Journal of Advanced Ceramics· Volume 10· Issue 5

Abstract

Abstract Exploring outstanding rare-earth activated inorganic phosphors with good thermostability has always been a research focus for high-power white light-emitting diodes (LEDs). In this study, we report a Sm3+-activated KNa4B2P3O13 (KNBP) powder phase. Its particle morphology, photoluminescence properties, concentration quenching mechanism, thermal quenching mechanism, and chromatic properties are demonstrated. Upon the near-ultraviolet (NUV) irradiation of 402 nm, the powder phase exhibits orange-red visible luminescence performance, originating from typical 4G5/2→6HJ/2 (J = 5, 7, 9) transitions of Sm3+. Importantly, the photoluminescence performance has good thermostability, low correlated color temperature (CCT), and high color purity (CP), indicating its promising application in the NUV-pumped warm white LEDs.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Luminescence and Fluorescent Materials · Radiation Detection and Scintillator Technologies

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References (30)

Show source-provided references
1. Fang MH, Leaño JL Jr, Liu RS. Control of narrow-band emission in phosphor materials for application in light-emitting diodes. ACS Energy Lett 2018, 3: 2573–2586.10.1021/acsenergylett.8b01408 ↗
2. Qin X, Liu XW, Huang W, et al. Lanthanide-activated phosphors based on 4f-5d optical transitions: Theoretical and experimental aspects. Chem Rev 2017, 117: 4488–4527.10.1021/acs.chemrev.6b00691 ↗
3. Xia ZG, Liu QL. Progress in discovery and structural design of color conversion phosphors for LEDs. Prog Mater Sci 2016, 84: 59–117.10.1016/j.pmatsci.2016.09.007 ↗
4. Qiao JW, Zhao J, Liu QL, et al. Recent advances in solidstate LED phosphors with thermally stable luminescence. J Rare Earths 2019, 37: 565–572.10.1016/j.jre.2018.11.001 ↗
5. Sahoo S. Enhanced time response and temperature sensing behavior of thermistor using Zn-doped CaTiO3 nanoparticles. J Adv Ceram 2018, 7: 99–108.10.1007/s40145-018-0261-9 ↗
6. Zhu Q, Wang XJ, Li JG. Recent progress in layered rare-earth hydroxide (LRH) and its application in luminescence. J Adv Ceram 2017, 6: 177–186.10.1007/s40145-017-0238-0 ↗
7. Ofelt GS. Intensities of crystal spectra of rare-earth ions. J Chem Phys 1962, 37: 511–520.10.1063/1.1701366 ↗
8. Yang Y, Pan H, Guan L, et al. Electronic structure and luminescent properties of Sr3Al2O6:Sm3+ orange phosphor prepared by hydrothermal method. J Mater Res Technol 2020, 9: 3847–3855.10.1016/j.jmrt.2020.02.011 ↗
9. Puchalska M, Zych E. The effect of charge compensation through alkali metal co-doping on the luminescence behaviour of SrAl4O7:Sm3+ phosphor. J Lumin 2018, 197: 211–218.10.1016/j.jlumin.2018.01.047 ↗
10. Xin SY, Zhou FG, Wang C, et al. Thermal stable red phosphor Sm3+ doped Na3MgZr(PO4)3: The synthesis, site occupation and photoluminescence property investigation. J Mater Sci: Mater Electron 2017, 28: 19134–19138.
11. Fan J, Zhang WT, Dai SY, et al. Effect of charge compensators A+ (A = Li, Na and K) on luminescence enhancement of Ca3Sr3(PO4)4:Sm3+ orange-red phosphors. Ceram Int 2018, 44: 20028–20033.10.1016/j.ceramint.2018.07.276 ↗
12. Li T, Wang ZJ, Li PL, et al. A novel red emitting phosphor LiBaB9O15:Sm2+/Sm3+, Li+ with broad excitation band for white LEDs. Luminescence 2018, 33: 438–442.10.1002/bio.3432 ↗
13. Devi LL, Jayasankar CK. Novel reddish-orange color emitting Ca2SiO4:Sm3+ phosphors for white LED applications prepared by using agricultural waste. J Lumin 2020, 221: 116996.10.1016/j.jlumin.2019.116996 ↗
14. Han B, Dai YZ, Zhang J, et al. Photoluminescence properties of a double perovskite tungstate based red-emitting phosphor NaLaMgWO6:Sm3+. Ceram Int 2018, 44: 3734–3740.10.1016/j.ceramint.2017.11.154 ↗
15. Du P, Hua YB, Yu JS. Energy transfer from VO43- group to Sm3+ ions in Ba3(VO4)2:3xSm3+ microparticles: A bifunctional platform for simultaneous optical thermometer and safety sign. Chem Eng J 2018, 352: 352–359.10.1016/j.cej.2018.07.019 ↗
16. Xie JH, Zhang XY, Cheng LQ, et al. Photoluminescence properties of novel K2Mg2(MoO4)3:Sm3+ orange-red emitting phosphors for white light emitting diodes. Opt Mater 2020, 107: 110008.10.1016/j.optmat.2020.110008 ↗
17. Li M, Verena-Mudring A. New developments in the synthesis, structure, and applications of borophosphates and metalloborophosphates. Cryst Growth Des 2016, 16: 2441–2458.10.1021/acs.cgd.5b01035 ↗
18. Yang Y, Gong PF, Huang Q, et al. KNa4B2P3O13: A deep-ultraviolet transparent borophosphate exhibiting second-harmonic generation response. Inorg Chem 2019, 58: 8918–8921.10.1021/acs.inorgchem.9b01198 ↗
19. Shannon RD. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr Sect A 1976, 32: 751–767.10.1107/S0567739476001551 ↗
20. Zhu J, Yang MH, Che Y, et al. Europium (III) doped LiNa2B5P2O14 phosphor: Surface analysis, DFT calculations and luminescent properties. J Alloys Compd 2020, 822: 153606.10.1016/j.jallcom.2019.153606 ↗
21. Zhou Y, Ge XC, Zhang ZH, et al. Understanding the downconversion photoluminescence of NaLaP4O12:Er3+ phosphor. Ceram Int 2019, 45: 20988–20993.10.1016/j.ceramint.2019.06.268 ↗
22. Zhang ZJ, Hu GQ, Wang H, et al. Investigations of Ba3BP3O12:Eu2+ single crystal as a scintillator. Mater Res Bull 2014, 52: 70–73.10.1016/j.materresbull.2014.01.004 ↗
23. Xiang JY, Yang MH, Che Y, et al. Photoluminescence investigation of novel reddish-orange phosphor Li2NaBP2O8:Sm3+ with high CP and low CCT. Ceram Int 2019, 45: 7018–7024.10.1016/j.ceramint.2018.12.203 ↗
24. Zhao D, Shi LY, Zhang RJ, et al. Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa2Sm2(BO3)(PO4)2. Acta Crystallogr Sect C 2020, 76: 1068–1075.10.1107/S2053229620014576 ↗
25. Hooda A, Khatkar SP, Khatkar A, et al. Reddish-orange light emission via combustion synthesized Ba3Y4O9:Sm3+ nanocrystalline phosphor upon near ultraviolet excitation. J Lumin 2020, 217: 116806.10.1016/j.jlumin.2019.116806 ↗
26. Li JH, Liang QY, Cao YF, et al. Layered structure produced nonconcentration quenching in a novel Eu3+-doped phosphor. ACS Appl Mater Interfaces 2018, 10: 41479–41486.10.1021/acsami.8b13759 ↗
27. Zhong YF, Deng B, Gao X, et al. High thermally Sm3+-activated SrBi2Ta2O9 orange-red phosphor: Preparation, characterization, and optical properties. J Lumin 2019, 215: 116648.10.1016/j.jlumin.2019.116648 ↗
28. Zhu G, Ci ZP, Shi YR, et al. Synthesis and photoluminescence properties of Ca19Mg2(PO4)14:Sm3+ red phosphor for white light emitting diodes. Mater Res Bull 2014, 55: 146–149.10.1016/j.materresbull.2014.04.030 ↗
29. Guo QF, Zhao CL, Liao LB, et al. Luminescence investigations of novel orange-red fluorapatite KLaSr3(PO4)3F:Sm3+ phosphors with high thermal stability. J Am Ceram Soc 2017, 100: 2221–2231.10.1111/jace.14751 ↗
30. Huang L, Zhu YW, Zhang XJ, et al. HF-free hydrothermal route for synthesis of highly efficient narrow-band red emitting phosphor K2Si1−xF6:xMn4+ for warm white light-emitting diodes. Chem Mater 2016, 28: 1495–1502.10.1021/acs.chemmater.5b04989 ↗