journal article·2018-10-02

Experimental and computational investigations of 2-amino-6-bromobenzothiazole as a corrosion inhibitor for copper in sulfuric acid

Jie Chen, Yujie Qiang, Shini Peng, Zhili Gong, Shengtao Zhang, Lanzhou Gao, Bochuan Tan, Shijin Chen, Lei Guo

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Abstract

2-amino-6-bromobenzothiazole (ABBT) as an inhibitor of copper corrosion in 0.5 M H2SO4 solution was researched in this study using with electrochemical measurement, scanning electron microscope, atomic force microscope, and theoretical calculation. Polarization curves manifest that ABBT acts as a modest cathodic-type inhibitor with a maximum achievable inhibition efficiency of 94.6% at 1 mM. EIS test indicates that ABBT adsorb on the copper surface and form an adsorption film, which obeys Langmuir adsorption model. Furthermore, DFT calculation and molecular dynamics simulation were utilized to explore the mechanism of inhibition of ABBT.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Hydrogen embrittlement and corrosion behaviors in metals

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Urban Construction and Environmental Engineering, Chongqing University, Chongqing, China

School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, China

Bomin Electronics Ltd., Meizhou, China

School of Material and Chemical Engieering, Tongren University, Tongren, China

Funding

National Natural Science Foundation of China · the Science and Technology Program of Guizhou Province · the Guizhou Provincial Department of Education Foundation · Sail Plan of Guangdong, China · Graduate Research and Innovation Foundation of Chongqing, China · Science and Technology Program of Guizhou Province · Guizhou Provincial Department of Education Foundation

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