journal article·2005-01

The effect of organo-functional silanes on the adhesion of epoxide resins to ITO glass

Tzu Hsuan Chiang, T.-E. Hsieh

Publisher page

Abstract

Abstract In this study we investigated five different types of organo-functional silanes containing vinyl, epoxy, amino, methacrylic and acrylic groups in the cationic polymerization of epoxide resin and studied their effects on epoxide adhesion strength to indium tin oxide (ITO) substrate via a pull test. The adhesion strength of epoxide resins was found to be in the order vinyl > methacrylic > acrylic > epoxy > amino. The silane containing vinyl group enhanced the adhesion strength, since it was able to promote free-radical polymerization. As to the silane containing amino group, it retarded the photo-polymerization of cationic photoinitiator in the resin and thus the lowest adhesion strength was observed. It was found that the resin sample containing 1 wt% of vinyl group silane possessed the highest adhesion strength of 91.42 kg/cm2 to ITO glass. An excessive amount of silane added in the resin generated too much H2O that diluted the concentration of resin and deteriorated the adhesion strength. Keywords: ADHESION STRENGTHITO GLASSSILANE FUNCTIONAL GROUPEPOXIDE RESINS
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Photopolymerization techniques and applications · Dental materials and restorations · Advanced Polymer Synthesis and Characterization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Park N. G. · Jpn. J. Appl. Phys. · 2002 · 41 · 152310.1143/JJAP.41.1523 ↗
2. Lee J. · J. Mater. Chem. · 2002 · 12 · 349410.1039/B206939C ↗
3. Adamovich V. · New J. Chem. · 2002 · 26 · 117110.1039/b204301g ↗
4. Plueddemann, E. P. 1992.Silanes and Other Coupling AgentsEdited by: Mittal, K. L. 3–19. VSP, Utrecht
5. Mathias L. J. · Polym. Composit. · 1997 · 18 · 33210.1002/pc.10286 ↗
6. Pape P. G. · J. Adhesion Sci. Technol. · 1991 · 5 · 83110.1163/156856191X00242 ↗
7. Harding P. H. · J. Appl. Polym. Sci. · 1998 · 67 · 102510.1002/(SICI)1097-4628(19980207)67:6<1025::AID-APP9>3.0.CO;2-K ↗
8. Gu X. H. · Appl. Surf. Sci. · 1997 · 115 · 6610.1016/S0169-4332(96)00857-4 ↗
9. Chen Y. J. · Langmuir · 2001 · 17 · 742510.1021/la010866y ↗
10. Medda S. K. · J. Non-Cryst. Solids. · 2003 · 318 · 14910.1016/S0022-3093(02)01862-8 ↗
11. Mohsen N. M. · J. Oral Rehabil. · 2000 · 27 · 25010.1046/j.1365-2842.2000.00491.x ↗
12. Zhao S. · Composites Sci. Technol. · 2003 · 63 · 100910.1016/S0266-3538(02)00317-2 ↗
13. Viengkhou V. · J. Appl. Polym. Sci. · 1996 · 61 · 236110.1002/(SICI)1097-4628(19960926)61:13<2361::AID-APP15>3.0.CO;2-7 ↗
14. Madsen N. B. · 1999
15. Wu S. · 1982
16. Kobayashi T. · J. Appl. Polym. Sci. · 1993 · 49 · 41710.1002/app.1993.070490306 ↗
17. 10.1163/156856195X0003110.1163/156856195X00031 ↗
18. Fang A. · Langmuir · 2000 · 16 · 522110.1021/la991574o ↗
19. Kim C. O. · J. Colloid Interf. Sci. · 2004 · 277 · 49910.1016/j.jcis.2004.04.064 ↗
20. Bruner E. L. · Langmuir · 2001 · 17 · 569610.1021/la010495l ↗
21. Priola B. · J. Photochem. Photobiol., A Chem. · 2001 · 141 · 8510.1016/S1010-6030(01)00424-5 ↗
22. Wake, W. C. 1976.Adhesion and the Formulation of Adhesives, 269–312. London: Applied Science Publishers.
23. Decker C. · J. Polym. Sci., A, Polym. Chem. · 1996 · 34 · 177110.1002/(SICI)1099-0518(19960715)34:9<1771::AID-POLA15>3.0.CO;2-3 ↗
24. McMurry, J. 1986.Fundamentals of Organic Chemistry, 144–145. New York, NY: Plenum Press.
25. Allen N. S. · J. Oil Colour Chem. Assoc. · 1990 · 73 · 438
26. Huber C. · Polymer · 1996 · 37 · 331910.1016/0032-3861(96)88478-3 ↗
27. Randell, D. R. 1987.Radiation Curing of Polymers, 116–127. London: Plenum Press.
28. Plueddemann, E. P. 1991.Silane Coupling Agents, 2nd edn, 158New York, NY: Plenum Press.10.1007/978-1-4899-2070-6 ↗
29. Chiniwalla P. · J. Appl. Polym. Sci. · 2003 · 89 · 56810.1002/app.12234 ↗
30. Crivello J. V. · J. Polym. Sci., A, Polym. Chem. · 2001 · 39 · 357810.1002/pola.10015 ↗
31. Choi D. H. · Eur. Polym. J. · 2001 · 37 · 195110.1016/S0014-3057(01)00102-1 ↗
32. He J. H. · J. Polym. Sci., A, Polym. Chem. · 1996 · 34 · 280910.1002/(SICI)1099-0518(19960930)34:13<2809::AID-POLA27>3.0.CO;2-F ↗
33. Nishiyama N. · Composites · 1995 · 26 · 30910.1016/0010-4361(95)93674-9 ↗
34. Loudon G. M. · 1995
35. Oldring, P. K. T. 1991.Chemistry & Technology of UV&EB Formulation for Coatings, Inks & Paints IV, 37–39. New York, NY: Plenum Press.
36. Fouassier, J. P. and Rabek, J. F. 1993.Radiation Curing in Polymer Science and Technology, Vol. IV. Practical Aspects and Applications, 196–232. New York, NY: Plenum Press.10.1007/978-94-011-1876-7 ↗
37. Zhu D. · Prog. Organic Coatings · 2004 · 49 · 4210.1016/j.porgcoat.2003.08.009 ↗
38. Palanivel V. · Prog. Organic Coatings · 2003 · 47 · 38410.1016/j.porgcoat.2003.08.015 ↗