journal article·2012-01-01

Oligomer Distribution at the Gel Point of Tannin-resorcinol-formaldehyde Cold-Set Wood Adhesives

A. Pizzi, H. Pasch, A. Celzard, A. Szczurek

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Abstract

Tannin-resorcinol-formaldehyde cold-set adhesives for wood laminating and fingerjointing were examined by Matrix Assisted Laser Desorption/Ionisation Time of Flight (MALDI-TOF) mass spectrometry. The analysis revealed that the adhesive was composed at the gel point of resorcinol-formaldehyde oligomers, unreacted flavonoids, and resorcinol-formaldehyde oligomers coreacted with flavonoid units of the tannin. The last ones constitute a high proportion of the adhesive resin. Furthermore, their proportion is highest at the minimum phenolic reactivity around pH 4.
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Research context

OpenAlex topics: Forensic Fingerprint Detection Methods · Mass Spectrometry Techniques and Applications · Cultural Heritage Materials Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

a ENSTIB-LERMAB, University Henri Poincaré — Nancy 1, 27 rue Philippe Seguin, BP 1041, 88051 Epinal, France;, Email: antonio.pizzi@enstib.uhp-nancy.fr

b Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, 7602 Matieland, South Africa

c ENSTIB-Institut Jean Lamour, University Henri Poincaré — Nancy 1, 27 rue Philippe Seguin, BP 1041, 88051 Epinal, France

d ENSTIB-Institut Jean Lamour, University Henri Poincaré — Nancy 1, 27 rue Philippe Seguin, BP 1041, 88051 Epinal, France

References (11)

Show source-provided references
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