Electrocaloric Cooling Materials and Devices for Zero-Global-Warming-Potential, High-Efficiency Refrigeration
Source abstract
Abstract
Summary Electrocaloric cooling technologies, enabled by the discovery of the giant electrocaloric effect in dielectrics more than a decade ago, represents a zero-global-warming-potential, environment-benign cooling alternative. Benefited from its nature as an electricity-driven capacitor, the electrocaloric working body renders the great advantages in the energy efficiency and the device integration. The decade-long efforts on advancing the technology revealed many promising material candidates with matured manufacturing protocols, as well as intriguing device prototypes for applications beyond the traditional vapor compression based cooling. This article presents the recent advances in electrocaloric cooling technologies, from material improvements to device demonstrations. The environmental impact and the energy efficiency of the technology were evaluated by the total effective warming impact and the material COP, respectively. In addition to the current progresses achieved by the decade-long research effort, the existing challenges and potential opportunities brought by the electrocaloric refrigeration will be discussed.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Ferroelectric and Piezoelectric Materials · Thermal Expansion and Ionic Conductivity
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. The large contribution of projected HFC emissions to future climate forcing10.1073/pnas.0902817106 ↗
2. Nihar Shah · 2015
3. Recent investigations in HFCs substitution with lower GWP synthetic alternatives: focus on energetic performance and environmental impact10.1016/j.ijrefrig.2017.06.026 ↗
4. Organic thermoelectric materials for energy harvesting and temperature control10.1038/natrevmats.2016.50 ↗
5. Magnetocaloric effect: from materials research to refrigeration devices10.1016/j.pmatsci.2017.10.005 ↗
6. Giant electrocaloric effect in thin-film PbZr0.95Ti0.05O310.1126/science.1123811 ↗
7. Large electrocaloric effect in ferroelectric polymers near room temperature10.1126/science.1159655 ↗
8. A regenerative elastocaloric heat pump10.1038/nenergy.2016.134 ↗
9. Progress and expectation of atmospheric water harvesting10.1016/j.joule.2018.07.015 ↗
10. Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling10.1126/science.aai7899 ↗
11. Caloric materials near ferroic phase transitions10.1038/nmat3951 ↗
12. Dielectric properties of Rochelle salt crystal
13. Principles and applications of ferroelectrics and related materials
14. Pyroelectric and electrocaloric materials10.1039/C2TC00283C ↗
15. Influence of the critical point on the electrocaloric response of relaxor ferroelectrics10.1063/1.3641975 ↗
16. Upper bounds on the electrocaloric effect in polar solids10.1063/1.3543628 ↗
17. Effect of inactive volume on thermocouple measurements of electrocaloric temperature change in multilayer capacitors of 0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO310.1088/1361-6463/aa87a5 ↗
18. Tunable temperature dependence of electrocaloric effect in ferroelectric relaxor poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene terpolymer
19. Giant electrocaloric effect in ferroelectric poly(vinylidenefluoride-trifluoroethylene) copolymers near a first-order ferroelectric transition
20. Giant electrocaloric response over a broad temperature range in modified BaTiO3Ceramics10.1002/adfm.201302386 ↗
21. Giant electrocaloric effect in BaZr0.2Ti0.8O3 thick film10.1063/1.4898599 ↗
22. Characterization of the electrocaloric effect and hysteresis loss in relaxor ferroelectric thin films under alternating current bias fields10.1063/1.4885715 ↗
23. High electrocaloric cooling power of relaxor ferroelectric BaZrxTi1-xO3 ceramics within broad temperature range10.1016/j.scib.2018.02.016 ↗
24. Direct measurements of the giant electrocaloric effect in soft and solid ferroelectric materials10.1080/00150193.2010.482884 ↗
25. Organic and inorganic relaxor ferroelectrics with giant electrocaloric effect10.1063/1.3501975 ↗
26. Direct measurement of pyroelectric and electrocaloric effects in thin films10.1103/PhysRevApplied.7.034025 ↗
27. Direct electrocaloric measurements of a multilayer capacitor using scanning thermal microscopy and infra-red imaging10.1063/1.4788924 ↗
28. Tailoring electrically induced properties by stretching relaxor polymer films10.1063/1.4704364 ↗
29. Tuning the electrocaloric effect by varying Sr concentration in ferroelectric Ba1−xSrxTiO310.1103/PhysRevMaterials.2.055402 ↗
30. Sintering aids modified electrocaloric response in BaZr0.2Ti0.8O3 bilayer films10.1016/j.jallcom.2017.07.019 ↗
31. Giant electrocaloric strength in single-crystal BaTiO310.1002/adma.201203823 ↗
32. Enhanced electrocaloric effect in composition gradient bilayer thick films10.1063/1.4944409 ↗
33. Dielectric and electrocaloric responses of Ba(Zr0.2Ti0.8)O3 bulk ceramics and thick films with sintering aids10.1109/TDEI.2015.7116344 ↗
34. Electrocaloric effects in multilayer capacitors for cooling applications10.1557/mrs.2018.68 ↗
35. Progress on electrocaloric multilayer ceramic capacitor development10.1063/1.4950796 ↗
36. Complex strain evolution of polar and magnetic order in multiferroic BiFeO3 thin films10.1038/s41467-018-06190-5 ↗
37. PST thin films for electrocaloric coolers10.1088/0022-3727/44/16/165407 ↗
38. Huge electrocaloric effect in Langmuir-Blodgett ferroelectric polymer thin films
39. Electrocaloric effect of PMN-PT thin films near morphotropic phase boundary10.1007/s12034-009-0039-3 ↗
40. A polymer blend approach to tailor the ferroelectric responses in P(VDF–TrFE) based copolymers10.1016/j.polymer.2013.02.041 ↗
41. A nanocomposite approach to tailor electrocaloric effect in ferroelectric polymer10.1016/j.polymer.2013.07.052 ↗
42. Enhanced electrocaloric effect in poly(vinylidene fluoride-trifluoroethylene)-based terpolymer/copolymer blends10.1063/1.4722932 ↗
43. Ferroelectric polymer nanocomposites with complementary nanostructured fillers for electrocaloric cooling with high power density and great efficiency10.1021/acsaem.8b00052 ↗
44. Internal biasing in relaxor ferroelectric polymer to enhance the electrocaloric effect10.1002/adfm.201501840 ↗
45. Graphene enabled percolative nanocomposites with large electrocaloric efficient under low electric fields over a broad temperature range10.1016/j.nanoen.2016.02.026 ↗
46. Interfacial coupling boosts giant electrocaloric effects in relaxor polymer nanocomposites: in situ characterization and phase-field simulation
47. Giant electrocaloric response in the prototypical Pb(Mg,Nb)O3 relaxor ferroelectric from atomistic simulations10.1103/PhysRevB.97.104110 ↗
48. Impact of critical point on piezoelectric and electrocaloric response in barium titanate10.1103/PhysRevB.87.104102 ↗
49. Maximizing the number of coexisting phases near invariant critical points for giant electrocaloric and electromechanical responses in ferroelectrics
50. The giant electromechanical response in ferroelectric relaxors as a critical phenomenon10.1038/nature04854 ↗
51. Negative electrocaloric effect in antiferroelectric PbZrO310.1209/0295-5075/107/17002 ↗
52. Anomalous negative electrocaloric effect in a relaxor/normal ferroelectric polymer blend with controlled nano- and meso-dipolar couplings10.1063/1.4944776 ↗
53. Electrocaloric refrigeration: An innovative, emerging, eco-friendly refrigeration technique
54. Yin, J.M., Pettersen, J., McEnaney, R., and Beaver, A. (1999). TEWI comparison of R744 and R134a systems for mobile air conditioning. In International Congress and Exposition, 1999-1901-0582.10.4271/1999-01-0582 ↗
55. Design and modeling of a fluid-based micro-scale electrocaloric refrigeration system10.1016/j.ijheatmasstransfer.2014.01.043 ↗
56. Simulation of chip-size electrocaloric refrigerator with high cooling-power density10.1063/1.4796184 ↗
57. Enhanced electrocaloric efficiency via energy recovery10.1038/s41467-018-04027-9 ↗
58. Efficient charge recovery method for driving piezoelectric actuators with quasi-square waves10.1109/TUFFC.2003.1193617 ↗
59. The electrocaloric efficiency of ceramic and polymer films10.1002/adma.201300606 ↗
60. An electrocaloric refrigerator without external regenerator10.1063/1.4898812 ↗
61. Large electrocaloric effect in a dielectric liquid possessing a large dielectric anisotropy near the isotropic–nematic transition10.1002/adfm.201202686 ↗
62. Not-in-kind cooling technologies: a quantitative comparison of refrigerants and system performance10.1016/j.ijrefrig.2015.10.019 ↗
63. Pecharsky
64. Annapragada
65. Experimental testing of electrocaloric cooling with transparent ferroelectric ceramic as a working body10.1080/00150199208223433 ↗
66. Solid-state refrigeration based on the electrocaloric effect for electronics cooling10.1115/1.4002896 ↗
67. A solid-state refrigerator based on the electrocaloric effect10.1063/1.4729038 ↗
68. Bulk relaxor ferroelectric ceramics as a working body for an electrocaloric cooling device10.1063/1.4907258 ↗
69. A chip scale electrocaloric effect based cooling device10.1063/1.4799283 ↗
70. A review of magnetic refrigerator and heat pump prototypes built before the year 201010.1016/j.ijrefrig.2010.04.002 ↗
71. An electrocaloric refrigerator with direct solid to solid regeneration10.1063/1.4986508 ↗
72. Highly efficient electrocaloric cooling with electrostatic actuation10.1126/science.aan5980 ↗
73. Coupling of the electrocaloric and electromechanical effects for solid-state refrigeration10.1063/1.4964124 ↗
74. Electrocaloric devices based on thin-film heat switches10.1063/1.3190559 ↗
75. Modeling of a smart heat pump made of laminated thermoelectric and electrocaloric materials10.1115/1.4034751 ↗
76. High-throughput phase-field design of high-energy-density polymer nanocomposites
77. First-principles-based calculation of the electrocaloric effect in BaTiO3: A comparison of direct and indirect methods10.1103/PhysRevB.93.054110 ↗
78. Modeling hybrid perovskites by molecular dynamics10.1088/1361-648X/29/4/043001 ↗
79. Ferroelectric polymer nanocomposites for room-temperature electrocaloric refrigeration10.1002/adma.201404591 ↗
80. Relaxor ferroelectric-based electrocaloric polymer nanocomposites with a broad operating temperature range and high cooling energy10.1002/adma.201405495 ↗
81. Ultrahigh piezoelectricity in ferroelectric ceramics by design10.1038/s41563-018-0034-4 ↗
82. The giant electrocaloric effect and high effective cooling power near room temperature for BaTiO3 thick film10.1063/1.3658251 ↗
83. A giant electrocaloric effect in nanoscale antiferroelectric and ferroelectric phases coexisting in a relaxor Pb0.8Ba0.2ZrO3 thin film at room temperature10.1002/adfm.201202525 ↗
84. Colossal negative electrocaloric effects in lead-free bismuth ferrite-based bulk ferroelectric perovskite for solid-state refrigeration10.1039/C8TC04125C ↗
85. Ultrafast electric field pulse control of giant temperature change in ferroelectrics10.1103/PhysRevLett.120.055901 ↗
86. Diisopropylammonium bromide is a high-temperature molecular ferroelectric crystal10.1126/science.1229675 ↗
87. Metal-free three-dimensional perovskite ferroelectrics10.1126/science.aas9330 ↗
88. Thermal strain induced large electrocaloric effect of relaxor thin film on LaNiO3 /Pt composite electrode with the coexistence of nanoscale antiferroelectric and ferroelectric phases in a broad temperature range10.1016/j.nanoen.2018.03.003 ↗
89. Phase coexistence and electric-field control of toroidal order in oxide superlattices10.1038/nmat4951 ↗
90. Atomic-resolution transmission electron microscopy of electron beam–sensitive crystalline materials10.1126/science.aao0865 ↗
91. Strong electrocaloric effect in lead-free 0.65Ba(Zr 0.2 Ti 0.8 )O 3 -0.35(Ba 0.7 Ca 0.3 )TiO 3 ceramics obtained by direct measurements10.1063/1.4907774 ↗
92. Comparison of directly and indirectly measured electrocaloric effect in relaxor ferroelectric polymers10.1063/1.3514255 ↗
93. Electrocaloric characterization of a poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) terpolymer by infrared imaging10.1063/1.4890676 ↗
94. Toward wearable cooling devices: Highly flexible electrocaloric Ba0.67Sr0.33TiO3 nanowire arrays10.1002/adma.201506118 ↗
95. Enhancing the electrocaloric effect in a relaxor polymer by including minor normal ferroelectric phase10.1063/1.5054114 ↗
96. Towards electrocaloric heat pump—a relaxor ferroelectric polymer exhibiting large electrocaloric response at low electric field10.1063/1.5048599 ↗
97. Enhanced electrocaloric effect in ferroelectric poly(vinylidene-fluoride/trifluoroethylene) 55/45 mol % copolymer at ferroelectric-paraelectric transition10.1063/1.3569953 ↗
98. Colossal room-temperature electrocaloric effect in ferroelectric polymer nanocomposites using nanostructured barium strontium titanates10.1021/acsnano.5b03371 ↗
99. Electrocaloric effect in polycrystalline barium titanate
100. Direct measurement of giant electrocaloric effect in BaTiO3 multilayer thick film structure beyond theoretical prediction10.1063/1.3430045 ↗