journal article·2015-03-01Open access

On atom–atom `short contact' bonding interactions in crystals

Claude Lecomte, Enrique Espinosa, Cherif F. Matta

IUCrJ· Volume 2· Issue 2

Abstract

Professor Dunitz questions the usefulness of ascribing crystalline structural stability to individual atom–atom intermolecular interactions viewed as bonding (hence stabilizing) whenever linked by a bond path. An alternative view is expressed in the present essay that articulates the validity and usefulness of the bond path concept in a crystallographic and crystal engineering context.
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Research context

OpenAlex topics: Crystallography and molecular interactions · Chemical Thermodynamics and Molecular Structure · High-pressure geophysics and materials

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