journal article·2021-04-03Open access

Synthesis of Bi6O6(OH)3(NO3)3·1.5H2O/ZnO composite material with excellent photocatalytic hydrogen production performance

Lingyi Wang, Shichang Sun, Ziqing Zhong, Qingguang Gong, Xingpeng Jiang, Weiming Zhou, Liwei Wang, Ming Lin, Zhanhui Yuan

Abstract

The heterojunction effect can effectively improve the separation efficiency of the photocatalyst’s photo-generated electron and hole pairs, thereby greatly improving the photocatalytic hydrogen production performance of the photocatalyst. In this paper, Bi6O6(OH)3(NO3)3 · 1.5H2O (BBN) and ZnO are used to construct and synthesize Bi6O6(OH)3(NO3)3 · 1.5H2O/ZnO (BBN/ZnO) heterojunction photocatalyst. Under UV-vis light irradiation, the BBN/ZnO composite could generate H2 with a rate of 28.66 μmol·g−1·h−1, which is higher than pure BBN (0.92 μmol·g−1·h−1) and ZnO (6.54 μmol·h−1·g−1) at around 31.1 and 4.4 times, respectively. Moreover, the experimental results found that the composite still exhibits excellent photocatalytic activity and maintains a high and stable activity in the 12-hour experiment with 3 cycles. The possible mechanism to enhance the photocatalytic behavior is attributed to the expanded light absorption range, reduced surface migration resistance, and inhibited recombination of photo-generated electron and hole pairs.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Perovskite Materials and Applications · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou, China

Ocean College, Minjiang University, Fuzho, China

Funding

Natural Science Foundation of Fujian Province · Fujian Engineering Research Center of New Chinese lacquer Material · Fujian Agriculture and Forestry University · Education Research Program for Young and Middle-aged Teachers of Fujian Education Department · Key Laboratory of New Functional Textile Fiber and Material of Fujian Province

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