journal article·2026-04-21Open access

Porosity and Pore-Network Controls on Elastic Properties and Permeability in Porous Ignimbrites

Hugo Sereno, Antonio Pola

Applied Sciences· Volume 16· Issue 8

Abstract

In porous ignimbrites, porosity defines the first-order control on elastic trend, but rocks with similar porosity can still behave differently because their pore networks are arranged differently. We analyzed 50 specimens from seven ignimbrite units in Mexico using density and porosity measurements, permeability tests, mercury intrusion porosimetry, image-based pore descriptors, and ultrasonic P- and S-wave velocities. At the unit scale averages, total porosity ranges from 31.4% in Tl to 42.9%, but elastic properties and permeability vary widely, showing that porosity alone does not define a unique physical state. Two end-member pore-network tendencies can be recognized: crack-linked, throat-restricted systems and more equant or intergranular systems. At similar porosity, crack-dominated networks are generally less stiff and less permeable, whereas more equant networks show higher permeability and stiffer behavior under dry conditions. Effective-medium models indicate that most samples are consistent with KT aspect ratios of 0.15–0.20 and a critical-porosity range of 40–60%. Overall, porosity defines the first-order elastic trend, whereas pore-network architecture explains much of the remaining hydraulic variability and part of the residual elastic spread.
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Research context

OpenAlex topics: earthquake and tectonic studies · Geological and Geochemical Analysis · High-pressure geophysics and materials

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Affiliations

Posgrado en Ciencias de la Tierra, Escuela Nacional de Estudios Superiores—Unidad Morelia, Universidad Nacional Autónoma de México, 04510 Morelia, Michoacán, Mexico

Escuela Nacional de Estudios Superiores—Unidad Morelia, Universidad Nacional Autónoma de México, 04510 Morelia, Michoacán, Mexico

References (81)

Show source-provided references
1. Ranking welding intensity in pyroclastic deposits10.1007/s00445-004-0367-5 ↗
2. Pyroclastic density currents: State of the art and perspectives10.1016/j.jvolgeores.2014.06.014 ↗
3. Classification of ignimbrites and their eruptions10.1016/j.earscirev.2021.103697 ↗
4. The impact of hydrothermal alteration on the physiochemical characteristics of reservoir rocks: The case of the Los Humeros geothermal field (Mexico)10.1186/s40517-022-00231-5 ↗
5. Estimation of engineering properties of selected tuffs by using grain/matrix ratio10.1016/j.jafrearsci.2016.05.008 ↗
6. Tuff as rock and soil: Review of the literature on tuff geotechnical, chemical, and mineralogical properties around the world and in Indonesia10.1063/1.5112466 ↗
7. A review on challenges in the assessment of geomechanical rock performance for deep geothermal reservoir development10.1016/j.rser.2017.10.076 ↗
8. Hyperspectral mapping of density, porosity, stiffness, and strength in hydrothermally altered volcanic rocks10.5194/se-16-1249-2025 ↗
9. Mavko, G., Mukerji, T., and Dvorkin, J. (2009). The Rock Physics Handbook: Tools for Seismic Analysis of Porous Media, Cambridge University Press. [2nd ed.].10.1017/CBO9780511626753 ↗
10. Ultrasonic velocity measurements in volcanic rocks: Correlation with microtexture10.1046/j.0956-540x.2001.01580.x ↗
11. Omovie, S.J., Myers, M., and Castagna, J.P. (2022). Acoustic dispersion in low permeability unconventional reservoir rocks and shales at in situ stress conditions. Minerals, 12.10.3390/min12101180 ↗
12. Sandstone reservoir rock physics modeling and time-lapse seismic analysis10.1016/j.jappgeo.2024.105318 ↗
13. The permeability and elastic moduli of tuff from Campi Flegrei, Italy: Implications for ground deformation modelling10.5194/se-5-25-2014 ↗
14. Mineral alteration and fracture influence on the elastic properties of volcaniclastic rocks10.1029/2018JB016617 ↗
15. Exploring microstructure and petrophysical properties of microporous volcanic rocks through 3D multiscale and super-resolution imaging10.1038/s41598-023-33687-x ↗
16. Facies variations and permeability of ignimbrites in active geothermal systems: Case study of the Xáltipan ignimbrite at Los Humeros Volcanic Complex10.1016/j.jsames.2020.102810 ↗
17. Welding degree assessment of the Escalera Ignimbrite in Central Mexico: Insights from physical and mechanical properties10.1016/j.jvolgeores.2025.108473 ↗
18. Microstructural controls on the geomechanical of ignimbrite10.1016/0013-7952(93)90067-M ↗
19. Novel approach for simulating the elastic properties of porous rocks including the critical porosity phenomena10.1190/geo2012-0260.1 ↗
20. Wave-velocity dispersion and rock microstructure10.1016/j.petrol.2019.106466 ↗
21. Petrophysical properties of hydrothermally-altered pyroclastic deposits from Deception Island (Bransfield Strait, Antarctica)10.1016/j.jvolgeores.2025.108399 ↗
22. The influence of fluid type on elastic wave velocity and attenuation in volcanic rocks10.1016/j.jvolgeores.2020.107004 ↗
23. Use of porosity to estimate hydraulic properties of volcanic tuffs10.1016/S0309-1708(02)00182-3 ↗
24. The role of microporosity on the permeability of volcanic-hosted geothermal reservoirs: A case study from Los Humeros, Mexico10.1016/j.geothermics.2020.102020 ↗
25. Crack propagation characteristics in shale under cyclic in situ methane detonation impact fracturing10.1021/acs.energyfuels.5c06341 ↗
26. A multi-method approach in the physical and mechanical assessment of lava rocks with distinct microstructure10.1016/j.enggeo.2025.107907 ↗
27. Variations in pore structure in subaerial lava flows at Nishinoshima, Japan, inferred from physical properties10.1016/j.jvolgeores.2024.108262 ↗
28. A variational approach to the theory of the elastic behaviour of multiphase materials10.1016/0022-5096(63)90060-7 ↗
29. Velocity and attenuation of seismic waves in two-phase media: Part I, Theoretical formulations10.1190/1.1440450 ↗
30. Velocity and attenuation of seismic waves in two-phase media: Part II. Experimental results10.1190/1.1440451 ↗
31. Long-wavelength propagation in composite elastic media I. Spherical inclusions10.1121/1.385171 ↗
32. Evaluating bounds and estimators for constants of random polycrystals composed of orthotropic elastic materials
33. Nur, A., Mavko, G., Dvorkin, J., and Gal, D. (1995, January 1). Critical porosity: The key to relating physical properties to porosity in rocks. Proceedings of the 1995 SEG Annual Meeting, Houston, TX, USA.10.1190/1.1887540 ↗
34. Comparison of the Krief and critical porosity models for prediction of porosity and VP/VS10.1190/1.1444403 ↗
35. Critical porosity and elastic properties of microporous mixed carbonate-siliciclastic rocks10.1190/1.3043727 ↗
36. Pressure effects in Nur’s critical porosity model estimates for carbonate rocks10.1016/j.jappgeo.2021.104498 ↗
37. Rock physics modelling of the carbonate reservoirs: A log-based algorithm to determine the pore aspect ratio10.1016/j.jappgeo.2019.103930 ↗
38. Queiroz, L.E., Grana, D., Fernandes, C.P., Mukerji, T., de Figueiredo, L.P., and Mantovani, I.F. (2025). Estimation of equivalent pore aspect ratio in rock physics models and validation using digital rocks. Geosciences, 15.10.3390/geosciences15020067 ↗
39. Geomechanical characterization of the Miocene Cuitzeo ignimbrites, Michoacán, Central Mexico10.1016/j.enggeo.2016.10.003 ↗
40. Building stones used in the architectural heritage of Morelia (México): Quarries location, rock durability and stone compatibility in the monument10.1007/s12665-018-7340-7 ↗
41. Geology of La Reforma caldera complex, Baja California, Mexico10.1080/17445647.2019.1612287 ↗
42. Volcanic and marine stratigraphy along the El Álamo Canyon, Santa Rosalía Basin, Baja California Sur
43. Estratigrafía volcánica de la porción suroeste del Lago de Cuitzeo y su relación con la formación de la caldera tipo graben de Chucándiro10.22201/cgeo.20072902e.2022.1.1689 ↗
44. (2019). Standard Practices for Preparing Rock Core Specimens and Determining Dimensional and Shape Tolerances (Standard No. ASTM D4543-19).
45. Thermal Analysis and Thermal Reactions of Smectites: A Review of Methodology, Mechanisms, and Kinetics10.1007/s42860-023-00222-y ↗
46. Thermal dehydroxylation of kaolinite under isothermal conditions10.1016/j.clay.2013.07.017 ↗
47. Permeability of volcanic rocks to gas and water10.1016/j.jvolgeores.2018.02.002 ↗
48. Generalized log-normal distribution of pore sizes in hydrated cement paste10.1016/0021-9797(72)90239-1 ↗
49. Pore facies analysis: Incorporation of rock properties into pore geometry based classes in a Permo-Triassic carbonate reservoir in the Persian Gulf10.1088/1742-2132/11/3/035008 ↗
50. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)10.1515/pac-2014-1117 ↗
51. Mercury porosimetry: A general (practical) overview10.1002/ppsc.200601009 ↗
52. (2014). Standard Test Method for Specific Gravity of Soil Solids by Gas Pycnometer (Standard No. ASTM D5550-14).
53. (2021). Standard Test Methods for Laboratory Determination of Density (Unit Weight) of Soil Specimens (Standard No. ASTM D7263-21).
54. Ulusay, R., and Hudson, J.A. (2007). The Complete ISRM Suggested Methods for Rock Characterization, Testing and Monitoring, ISRM.
55. (2018). Standard Test Method for Permeability of Rocks by Flowing Air (Standard No. ASTM D4525-13).
56. Putz, H., and Brandenburg, K. (2003). Match!: Phase Analysis Using Powder Diffraction, Crystal Impact. Available online: https://www.crystalimpact.de/match.
57. Ahrens, T.J. (1995). Mixture theories for rock properties. Rock Physics and Phase Relations: A Handbook of Physical Constants, American Geophysical Union.10.1029/RF003 ↗
58. The differential Kuster-Toksöz rock physics model for predicting S-wave velocity10.1088/1742-2132/12/5/839 ↗
59. Weathering mechanisms and their effects on the landsliding of ignimbrite subject to vapor-phase crystallization in the Shirakawa pyroclastic flow, northern Japan10.1016/S0013-7952(02)00035-2 ↗
60. Strategies for helium pycnometry density measurements of welded ignimbritic rocks10.1016/j.measurement.2020.108640 ↗
61. Mechanical and physical properties of hydrothermally altered rocks, Taupo Volcanic Zone, New Zealand10.1016/j.jvolgeores.2014.10.008 ↗
62. Quantifying the role of hydrothermal alteration in creating geothermal and epithermal mineral resources: The Ohakuri ignimbrite (Taupō Volcanic Zone, New Zealand)10.1016/j.jvolgeores.2019.106703 ↗
63. Porosity and permeability in volcanic rocks: A case study on the Serie Tobífera, South Patagonia, Argentina10.1016/S0377-0273(03)00419-0 ↗
64. Bär, K., Reinsch, T., and Bott, J. (2026, April 17). P3: PetroPhysical Property Database [Data Set]. GFZ Data Services. Available online: https://dataservices.gfz-potsdam.de/panmetaworks/showshort.php?id=escidoc:2263895.
65. Acoustics and petrophysical investigations on upper cretaceous carbonate rocks from northern Lebanon10.1016/j.jafrearsci.2020.103955 ↗
66. Estimating permeability of carbonate rocks from porosity and Vp/Vs10.1190/1.2756081 ↗
67. Experimental insights into factors influencing Vp/Vs ratios at the Nevado del Ruiz Volcano, Colombia10.30909/vol.06.02.283299 ↗
68. Pore space topology controls ultrasonic waveforms in dry volcanic rocks10.1029/2022GL100310 ↗
69. Pore structure of volcanic clasts: Measurements of permeability and electrical conductivity10.1016/j.epsl.2009.01.023 ↗
70. Mercury cyclic porosimetry: Measuring pore-size distributions corrected for both pore-space accessivity and contact-angle hysteresis10.1016/j.jcis.2021.04.038 ↗
71. Hydrothermal alteration and physical and mechanical properties of rocks in a volcanic environment: A review10.1016/j.earscirev.2024.104754 ↗
72. Hydraulic properties of ignimbrites: Matrix and fracture permeabilities in two pyroclastic flow deposits from Cimino-Vico volcanoes (Italy)10.1007/s10064-022-02712-0 ↗
73. The influence of alteration and fractures on gas permeability and mechanical properties of the sedimentary and volcanic rocks of the Acoculco Caldera Complex (México)10.1007/s10064-023-03522-8 ↗
74. Characteristics and factors controlling reservoir space in the Cretaceous volcanic rocks of the Hailar Basin, NE China10.1016/j.marpetgeo.2018.01.038 ↗
75. Aligholi, S., and Khandelwal, M. (2022). Computing elastic moduli of igneous rocks using modal composition and effective medium theory. Geosciences, 12.10.3390/geosciences12110413 ↗
76. The equivalent pore aspect ratio as a tool for pore type prediction in carbonate reservoirs
77. The power-law relation between inclusion aspect ratio and porosity: Implications for electrical and elastic modeling10.1029/2019JB019187 ↗
78. Rock physics modelling of porous rocks with multiple pore types: A multiple-porosity variable critical porosity model10.1111/1365-2478.12898 ↗
79. Empirical determination of the effective solid modulus in organic-rich shales10.1038/s41598-023-45393-9 ↗
80. Integrative rock physics and computer vision analysis of elastic properties and pore aspect ratios in Brazilian pre-salt carbonates10.1038/s41598-025-11646-y ↗
81. Effective moduli of rocks predicted by the Kuster-Toksöz and Mori-Tanaka models10.1093/jge/gxab034 ↗