journal article·2025-12-12Open access

Statistical Evaluation of Long-Term Monitoring of Petroleum Hydrocarbon Pollution in Groundwater at 45 Railway Sites Across Slovakia

Juraj Macek, Veronika Špirová, Ľubomír Jurkovič

Applied Sciences· Volume 15· Issue 24

Abstract

Railway sites are characterized by the frequent occurrence of soil and groundwater pollution by oil. The primary reason for pollution is usually the handling of large volumes of fuels and lubricants and, to a lesser extent, other hazardous substances, which represent an increased likelihood of potential spills due to inattention and accidents. The second factor is spills due to inadequate (aged) process equipment. In the Slovak Republic, a network of locomotive depots, strategically located throughout the country, has been operated in the past. In 2008, a pilot project was implemented to survey groundwater quality at 45 sites, followed by monitoring of the quality status until 2014. The levels of petroleum hydrocarbons in groundwater were determined by spectrophotometric methods (NEC-IR and NEC-UV). The NEC-IR parameter documented very-high pollution at 14 sites, while the NEC-UV parameter documented the same very-high pollution degree at 23 sites. Statistical evaluation using Kruskal–Wallis test followed by Dunn’s post hoc test revealed a significant effect of the size of the site as well as activity status on the presence and intensity of pollution. The presence of light non-aqueous phase liquids (LNAPLs) was observed at almost half of the sites. Based on the evaluated data, railway sites represent a specific type of site with frequent occurrence of severe oil pollution, posing a significant environmental and health risk.
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Research context

OpenAlex topics: Oil Spill Detection and Mitigation · Lubricants and Their Additives · Environmental Chemistry and Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Geochemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Ilkovičova 6, 842 15 Bratislava, Slovakia

The Centre of Environmental Services, Ltd., Kutlíkova 17, 852 50 Bratislava, Slovakia

References (52)

Show source-provided references
1. Kubáček, J., Doubek, M., Školník, M., Klubal, M., Kattoš, M., Szojka, L., Pravda, P., Kinček, J., Farkaš, G., and Menger, J. (1999). Dejiny Železníc na Území Slovenska, Železnice SR.
2. História, súčasnosť a budúcnosť elektrifikácie železničných tratí na Slovensku
3. Light Non-Aqueous Phase Liquids Distribution and Weathering in Former Railyard; SE Danube Basin, Slovakia
4. Railway Transportation as a Serious Source of Organic and Inorganic Pollution10.1007/s11270-010-0645-0 ↗
5. Railway Tracks-Habitat Conditions, Contamination, Floristic Settlement—A Review
6. Jovanovic, L., Aleksic, G., Radosavljevic, M., and Onjia, A. (2015). Soil Pollution in the Railway Junction Niš (Serbia) and Possibility of Bioremediation of Hydrocarbon-Contaminated Soil, European Geosciences Union.
7. Výskyt a Stanovenie Ropných Látok v Povrchových Vodách
8. Forrester, S., Janik, L., and McLaughlin, M. (2010, January 1–6). An Infrared Spectroscopic Test for Total Petroleum Hydrocarbon (TPH) Contamination in Soils. Proceedings of the 19th World Congress of Soil Science: Soil Solutions for a Changing World, Brisbane, Australia.
9. Rapid Assessment of Petroleum-Contaminated Soils with Infrared Spectroscopy10.1016/j.geoderma.2016.11.030 ↗
10. The Application of Rapid Handheld FTIR Petroleum Hydrocarbon-Contaminant Measurement with Transport Models for Site Assessment: A Case Study10.1016/j.geoderma.2019.114017 ↗
11. Wang, L., Cheng, Y., Naidu, R., and Bowman, M. (2021). The Key Factors for the Fate and Transport of Petroleum Hydrocarbons in Soil With Related In/Ex Situ Measurement Methods: An Overview. Front. Environ. Sci., 9.10.3389/fenvs.2021.756404 ↗
12. Investigation of Oil and Grease in Surface Soils of Gas Station, Automobile Repair Workshop, Urban, Recreational Area, and Rural Sites Using FT-IR
13. Optimization and Validation of FTIR Method with Tetrachloroethylene for Determination of Oils and Grease in Water Matrices
14. Analysis of Total Content of Petroleum Products in Water by Using FTIR Spectroscopy10.1051/matecconf/202237300063 ↗
15. Crompton, T.R. (2019). Chapter 1—Hydrocarbons in Nonsaline Waters. Determination of Toxic Organic Chemicals in Natural Waters, Sediments and Soils, Academic Press.10.1016/B978-0-12-815856-2.00001-1 ↗
16. Zemo, D.A. (2016). White Paper: Analytical Methods for Total Petroleum Hydrocarbons (TPH), Zemo & Associates, Inc.
17. Determination of Total Petroleum Hydrocarbon (TPH) and Polycyclic Aromatic Hydrocarbon (PAH) in Soils: A Review of Spectroscopic and Nonspectroscopic Techniques10.1080/05704928.2012.736048 ↗
18. Thomas, O., and Burgess, C. (2022). Chapter 12—Industrial Wastewater. UV-Visible Spectrophotometry of Waters and Soils, Elsevier. [3rd ed.].10.1016/B978-0-323-90994-5.00013-7 ↗
19. Vrana, K., Fatulová, E., and Naštický, J. (2008). Vypracovanie Programov Opatrení v Rámci Prípravy Plánov Manažmentu Oblastí Povodí v Súlade s Požiadavkami Vodného Zákona a Rámcovej Smernice o Vode Pre Prevádzky ZSSK CARGO a.s.–I. Etapa Prác a Lokalitu Čierna nad Tisou–Prekladisko, Life and Waste, s.r.o., HYDEKO-KV.
20. Vrana, K., Fatulová, E., Naštický, J., and Kovács, T. (2008). Vypracovanie Programov Opatrení v Rámci Prípravy Plánov Manažmentu Oblastí Povodí v Súlade s Požiadavkami Vodného Zákona a Rámcovej Smernice o Vode Pre Prevádzky ZSSK CARGO a.s.-II. Etapa Prác a Lokalitu Čierna nad Tisou-Prekladisko, Centrum environmentálnych služieb, s.r.o.
21. Auxt, A., and Hronec, B. (2010). Monitoring Podzemných vôd v Prevádzkach ZSSK Cargo Slovakia a.s. za rok 2009, Centrum Environmentálnych Služieb, s.r.o.
22. Auxt, A., and Hronec, B. (2011). Monitoring Podzemných vôd v Prevádzkach ZSSK Cargo Slovakia a.s. za rok 2010, Centrum Environmentálnych Služieb, s.r.o.
23. Auxt, A., and Hronec, B. (2012). Monitoring Podzemných vôd v Prevádzkach ZSSK Cargo Slovakia a.s. za rok 2011, Centrum Environmentálnych Služieb, s.r.o.
24. Auxt, A., Hronec, B., and Fecková, B. (2013). Monitoring Podzemných vôd v Prevádzkach ZSSK Cargo Slovakia a.s. za rok 2012, Centrum Environmentálnych Služieb, s.r.o.
25. Auxt, A., Hronec, B., and Polčan, I. (2014). Monitoring Podzemných vôd v Prevádzkach ZSSK Cargo Slovakia a.s. za rok 2013, Centrum Environmentálnych Služieb, s.r.o.
26. Polčan, I. (2014). Hodnotiaca Správa z Priebehu Vývoja Znečistenia Za Obdobie Jún 2009–Marec 2014. Rušňové Depo Čadca, Čierna Nad Tisou, Haniska, Jablonica, Komárno, Leopoldov, Maťovce, Plešivec, Prešov, Púchov, Spišská Nová Ves, Štúrovo, Trenšianska Teplá a Čierna Nad Tisou–VSP, Centrum Environmentálnych Služieb, s.r.o.
27. ITRC (2010). Use and Measurement of Mass Flux and Mass Discharge, ITRC.
28. LNAPL Thickness in Monitoring Wells Considering Hysteresis and Entrapment10.1111/j.1745-6584.1996.tb02021.x ↗
29. Urban, O., Chovanec, J., Keklák, V., Gregor, T., Kolářová, J., Vybíral, V., Škarvan, A., Čopan, J., Drábik, A., and Macek, J. (2021). Sanácia Environmentálnej Záťaže NZ (029)/Štúrovo-Rušňové Depo, Cargo a.s. (SK/EZ/NZ/601), DEKONTA Slovensko, spol. s r. o., DEKONTA, a. s.
30. Urban, O., Chovanec, J., Keklák, V., Gregor, T., Kolářová, J., Vybíral, V., Škarvan, A., Čopan, J., Drábik, A., and Macek, J. (2023). Sanácia Environmentálnej Záťaže NZ (029)/Štúrovo-Rušňové Depo, Cargo a.s. (SK/EZ/NZ/601), DEKONTA Slovensko, spol. s r. o., DEKONTA, a. s.
31. Pennington, A., Coughlin, J., Thomas, L., and Gabardi, D. (2018, January 8). LNAPL Recovery and Remedy Transitions: A Case Study at a Railyard Fueling Facility. Proceedings of the Chlorinated Conference Proceedings, Palm Springs, CA, USA.
32. Mitton, M.J., and Pimblett, B. (2005). In-Situ Biological Percolating System for the Treatment of Hydrocarbon Impacted Groundwater, Environmental Services Association of Alberta.
33. INTERA (2017). Additional Groundwater Characterization Report. City of Albuquerque Rail Yards, INTERA.
34. Investigation of Soil and Groundwater Contaminated by Gasoline and Lubricants Around a Railroad Station in S City, Korea
35. US EPA (2024). Sixth Five-Year Review Report for Conrail Rail Yard (Elkhart) Superfund Site, US EPA.
36. Exposure of Soil and Groundwater to Spills of Hazardous Materials Transported by Rail: A Geographic Information System Analysis10.1177/0361198106194300102 ↗
37. Kordík, J., Slaninka, I., Bačová, N., Bahnová, N., Benková, K., Bodiš, D., Bottlik, F., Dananaj, I., Demko, R., and Dénes, D. (2020). Udržateľnosť Projektu “Monitorovanie Environmentálnych Záťaží Na Vybraných Lokalitách Slovenskej Republiky”, Štátny Geologický Ústav Dionýza Štúra.
38. WVDEP (2023). West Virginia Voluntary Remediation Program, West Virginia Department of Environmental Protection.
39. TGCP (2024). Joint Groundwater Monitoring and Contamination Report-2023, Texas Groundwater Protection Committee.
40. Review of Groundwater Contaminant Mass Flux Measurement10.4491/eer.2007.12.4.176 ↗
41. CRC CARE (2016). Flux-Based Groundwater Assessment and Management, CRC for Contamination Assessment and Remediation of the Environment.
42. Xia, Y., Wang, B., Yang, Y., Du, X., and Yang, M. (2023). Quantitative Assessment of Organic Mass Fluxes and Natural Attenuation Processes in a Petroleum-Contaminated Subsurface Environment. Appl. Sci., 13.10.3390/app132312782 ↗
43. A Field Comparison of BTEX Mass Flow Rates Based on Integral Pumping Tests and Point Scale Measurements10.1016/j.jconhyd.2010.10.001 ↗
44. Mass Fluxes per Capita of Organic Contaminants from On-Site Sewage Treatment Facilities10.1016/j.chemosphere.2018.03.058 ↗
45. Weiner, E.R. (2012). Applications of Environmental Aquatic Chemistry: A Practical Guide, CRC Press. [3rd ed.].10.1201/b12963 ↗
46. Rice, D.W., Grose, R.D., Michaelsen, J.C., MacQueen, D.H., Cullen, S.J., Kastenberg, W.E., Everett, L.G., and Marino, M.A. (1995). California Leaking Underground Fuel Tank (LUFT) Historical Case Analyses, Lawrence Livermore National Laboratory, Environmental Protection Department, Environmental Restoration Division.
47. BTEX: A Serious Ground-Water Contaminant10.3923/rjes.2011.394.398 ↗
48. Newell, C., and Connor, J. (1998). Characteristics of Dissolved Petroleum Hydrocarbon Plumes, American Petroleum Institute.
49. Biodegradability of Commercial and Weathered Diesel Oils10.1590/S1517-83822008000100028 ↗
50. Overview of Natural Source Zone Depletion: Processes, Controlling Factors, and Composition Change10.1111/gwmr.12219 ↗
51. Natural Source Zone Depletion of LNAPL: A Critical Review Supporting Modelling Approaches10.1016/j.watres.2019.04.001 ↗
52. Tupý, P., Schwarz, J., Antal, J., Masiar, R., Filo, J., Jasovský, Z., Moravčík, D., Fickuliaková, M., Drábik, A., and Macek, J. (2022). Sanácia Environmentálnej Záťaže HC (1844)/Leopoldov-Rušňové Depo, Cargo a.s. (SK/EZ/HC/1844), EBA, s.r.o., ODOS, s.r.o., ENVIGEO, a.s.