journal article·2025-08-28Open access

Molecular Dynamics Simulation of Methane Adsorption and Diffusion in Limestone Pores in the Taiyuan Formation of the Ordos Basin, China: Effects of Pore Shapes, Apertures, and Formation Water

Tielian Shi, Cunbao Deng, Xiaoyang Guo, Lemei Zhang, Yu Zhang, Yue Bai, Dengke Liang, Yuanjing Li

Applied Sciences· Volume 15· Issue 17

Abstract

The Taiyuan Formation limestone in the Ordos Basin of China holds significant gas-bearing potential, making it a key target for unconventional natural gas exploration. Clarifying the microscopic occurrence mechanism of gas in limestone is necessary. The effects of pore morphology, aperture, and formation water were systematically studied in this paper through MD and GCMC. The results indicate that specific surface area, pore volume, tortuosity, and interaction synergistically influence methane adsorption and diffusion. Pore shape is intricately linked to these factors, and variations in pore width impact pore volume and interaction, with a slit pore being most conducive to gas diffusion. Formation water mainly forms water films and clusters in organic–inorganic pores. Water molecules preferentially form a water film, while increasing moisture content, expanding aperture, and introducing ions promote cluster formation. Formation water can enhance surface diffusion, reduce the adsorbed phase proportion, and decrease interaction, but it also occupies flow space and forms clusters that hinder gas diffusion. At low moisture content, gas diffusion is promoted in 2 nm and 4 nm pores, while high moisture content inhibits it. In contrast, 6 nm pores consistently curb diffusion.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Hydrocarbon exploration and reservoir analysis · Methane Hydrates and Related Phenomena · Atmospheric and Environmental Gas Dynamics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Safety and Emergency Management Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Shanxi Laboratory of Intelligent Mine, Taiyuan 030024, China

Postdoctoral Research Station, Huayang New Material Technology Group Co., Ltd., Yangquan 045000, China

Funding

National Natural Science Foundation of China

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