journal article·2025-05-09Open access

Modelling Leaching Using C-S-H Solid Solutions

Niall Holmes, Mark Tyrer

Applied Sciences· Volume 15· Issue 10

Abstract

Leaching from cement can lead to a loss in performance and durability and can also have an environmental impact. Therefore, it is an important aspect to consider when new cements are being developed and where concrete is to be placed that could lead to the contamination of groundwater. Calibrated thermodynamic models can provide very useful predictions in a matter of seconds for any cement-based material. However, such models need to include accurate representations of the solid-solution nature of the C-S-H gels that are included for the incongruent dissolution of calcium and silica. This study presents the calibration of a thermodynamic model employing the pH-REdox-Equilibrium geochemical software 3.8.7, written in C (PHREEQC 3.8.7), to model the change in the pH and the leaching of calcium (Ca) and silica (Si) from cement against the Ca/Si ratio and over time. The predicted concentrations of Ca and Si and the pH in the leachate were calculated using three solid-solution C-S-H gel models that were taken from the cemdata18 database, namely, CSHQ, CSH3T, and tobermorite–jennite, which have not been analysed before and show good agreement. The calibrated model was used to predict leaching from a CEM II/A-L cement and a blended CEM I + fly-ash with a cement replacement level of 35%. The effect of a sulphate environment (Na2SO4) was also analysed.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Groundwater flow and contamination studies · Groundwater and Isotope Geochemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Transport & Civil Engineering, Technological University Dublin (TU Dublin), D01 K822 Dublin, Ireland

Institute of Advanced Study, Collegium Basilea, 4053 Basel, Switzerland

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