journal article·2025-04-05Open access

Analysis of Tribological Properties of Expanded Graphite—Alloy Steel Pair Under High Loads in Dry and Humid Conditions

Aleksandra Rewolińska, Kamil Leksycki, Łukasz Wojciechowski, Karolina Perz

Applied Sciences· Volume 15· Issue 7

Abstract

Expanded graphite significantly improves the tribological properties of materials in friction pairs, but there is a lack of research in the literature on its cooperation with metals and the effect of water on friction and wear mechanisms. It is particularly important to understand the phenomenon of graphite layer formation on the steel surface and its effect on tribological properties. The aim of this study is to evaluate the tribological properties of an expanded graphite–alloy steel combination operating under selected loads in both dry and humid conditions. The tests were carried out on a block-on-ring tribological tester (where the blocks were made of expanded graphite and the rings were made of AISI 4130 steel) at a rotational speed of 150 rpm, with loads of 200 and 650 N. The frictional behavior was analyzed on the basis of the measured values of the friction torque and the coefficient of friction (COF) calculated from it (and the applied load). In dry conditions, the friction torque was stable, while in humid conditions it showed cyclical changes. An increase in load from 200 to 650 N caused an increase in the average friction torque by 235% in dry conditions and by 209% in humid conditions. The presence of water reduced the friction pair temperature by 12% at 200 N and by 18% at 650 N; however, it simultaneously increased graphite consumption–by 1179% at 200 N and by 100% at 650 N. The amount of graphite deposited on the steel surface depended on the load–in humid conditions, it increased by 114% at 200 N, while it decreased by 250% at 650 N. The conducted research expanded the understanding of the influence of operating conditions on the tribological properties of the expanded graphite–alloy steel pair. It also provided new data on the friction and wear mechanisms of this material combination in humid conditions, which may have significant engineering applications.
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Research context

OpenAlex topics: Tribology and Wear Analysis · Lubricants and Their Additives · Metal Alloys Wear and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Civil and Transport Engineering, Poznan University of Technology, Piotrowo Street, 60-965 Poznan, Poland

Institute of Mechanical Engineering, University of Zielona Gora, 4 Prof. Z. Szafrana Street, 65-516 Zielona Gora, Poland

References (50)

Show source-provided references
1. Shah, R., Chen, R., and Woydt, M. (2021). The Effects of Energy Efficiency and Resource Consumption on Environmental Sustainability. Lubricants, 9.10.3390/lubricants9120117 ↗
2. Influence of tribology on global energy consumption, costs and emissions10.1007/s40544-017-0183-5 ↗
3. Application and impact of tribology in energy-an overview10.1051/e3sconf/202339101081 ↗
4. Effects of carbon nanotubes functionalization on mechanical and tribological properties of nitrile rubber nanocomposites: Molecular dynamics simulations10.1016/j.commatsci.2021.110556 ↗
5. Tribological characteristics of graphite epoxy composites using adhesive wear experiments10.1016/j.jmrt.2020.09.106 ↗
6. Graphene oxide/polyethyleneimine/hydroxyapatite nanowire composite paper: Unexpected mechanical robustness after fire attacking and fire alarm application10.1016/j.compositesa.2022.107061 ↗
7. Investigations on the mechanics and tribology of multilayer graphene nanosheet in TiAl aviation composites10.1177/16878140211040714 ↗
8. Preparation and characterization of nanodiamond reinforced aluminum matrix composites by hot-press sintering10.1016/j.diamond.2021.108664 ↗
9. Hajdukiewicz, G., Komarov, A.I., Orda, D.V., and Panasiuk, K. (2025). Analysis of the Impact of Graphite Addition on the Tribological Properties of Composites with Polyester–Glass Recyclate. Materials, 18.10.3390/ma18020376 ↗
10. Improved lubricating and corrosion resistance of MAO coatings on ZK61 Mg alloy by co-doping with graphite and nano-zirconia10.1016/j.jmrt.2024.09.232 ↗
11. Peculiar high temperature tribological behaviour of plasma sprayed graphene nanoplatelets reinforced cerium oxide coatings10.1016/j.ceramint.2021.03.096 ↗
12. Micromechanical properties of hydroxyapatite nanocomposites reinforced with CNTs and ZrO210.1016/j.ceramint.2022.10.218 ↗
13. Tribological behaviour of spark plasma sintered and laser ablated SiC-graphene nanoplatelets composite10.1016/j.ceramint.2023.01.062 ↗
14. The performances of expanded graphite on the phase change materials composites for thermal energy storage10.1016/j.polymer.2020.123128 ↗
15. Multifunctional flexible composite membrane based on nanocellulose-modified expanded graphite/electrostatically spun fiber network structure for solar thermal energy conversion10.1016/j.egyr.2024.04.048 ↗
16. Preparation and properties of copper-plated expanded graphite/copper composites10.1016/j.triboint.2021.107094 ↗
17. Comparative tribological behavior of friction composites containing natural graphite and expanded graphite10.1007/s40544-019-0293-3 ↗
18. Mechanical, tribological and thermal properties of injection molded short carbon fiber/expanded graphite/polyetherimide composites10.1016/j.compscitech.2020.108498 ↗
19. Vande Ryse, R., Van Osta, M., Gruyaert, M., Oosterlinck, M., Kalácska, Á., Edeleva, M., Pille, F., D’hooge, D.R., Cardon, L., and De Baets, P. (2024). Playing with Low Amounts of Expanded Graphite for Melt-Processed Polyamide and Copolyester Nanocomposites to Achieve Control of Mechanical, Tribological, Thermal and Dielectric Properties. Nanomaterials, 14.10.3390/nano14070606 ↗
20. Experimental Investigation on the Tribo-Thermal Properties of Brake Friction Materials Containing Various Forms of Graphite: A Comparative Study10.1007/s13369-018-3590-7 ↗
21. Study on the mechanism of expanded graphite to improve the fading resistance of the non-asbestos organic composite braking materials10.1016/j.triboint.2023.108278 ↗
22. Thermomechanical and tribological properties of polyimide and polyethersulfone blends reinforced with expanded graphite particles at various elevated temperatures10.1002/app.52512 ↗
23. Effects of nanoscale expanded graphite on the wear and frictional behaviors of polyimide-based composites10.1016/j.wear.2015.06.019 ↗
24. Triboengineering properties of polytetrafluoroethylene modified by thermally expanded graphite10.3103/S1068366608050097 ↗
25. Effect of expanded graphite (EG) dispersion on the mechanical and tribological properties of nitrile rubber/EG composites10.1016/j.wear.2011.12.009 ↗
26. Graphene oxide versus graphite and chemically expanded graphite as solid lubricant in ultrahigh molecular weight polyethylene composites10.1016/j.triboint.2023.108643 ↗
27. Effect of Expanded Graphite on Mechanical and TribologicalProperties of Polyamide 6/Glass Fibre Composites
28. Facile fabrication and tribological properties of self-lubricating polyurethane based on expanded graphite/paraffin for water lubricated bearings10.1016/j.jmrt.2024.12.032 ↗
29. Tribological performance of epoxy composites reinforced by 3D expanded graphite skeleton containing oil microcapsules10.1016/j.triboint.2024.109814 ↗
30. Feng, W., Liang, B., Li, H., Chen, J., Gao, X., Yao, D., Lu, C., and Pang, X. (2024). Interconnected expanded graphite/stearic acid networks for self-lubricating PA6 composites with excellent heat dissipation performance. Polym. Compos., 1–13.10.1002/pc.29346 ↗
31. Tribological properties of low-temperature time-dependent pretreated graphite for mechanical seal pairs in high-speed turbopump10.1007/s40544-023-0759-1 ↗
32. Zhao, J., Liu, Y., Liu, D., Gu, Y., Zheng, R., Ma, R., Li, S., Wang, Y., and Shi, Y. (2022). The Tribological Performance of Metal-/Resin-Impregnated Graphite under Harsh Condition. Lubricants, 10.10.3390/lubricants10010002 ↗
33. Marine propeller shaft bearings under low-speed conditions: Water vs. oil lubrication
34. Experimental study on scale-down pads for nuclear main pump thrust bearing10.1016/j.anucene.2023.110297 ↗
35. A gasket design suitable for helium circuits of generation IV Gas-Cooled reactors10.1016/j.anucene.2024.110383 ↗
36. Płaza, S., Margielewski, L., and Celichowski, G. (2005). Introduction to Tribology and Tribochemistry, WUŁ.
37. Friction and wear properties of bronze graphite composite under water lubrication10.1016/j.triboint.2003.12.013 ↗
38. Formation of transfer layer and its effect on friction and wear of carbon–graphite face seal under dry, water and steam environments10.1016/j.wear.2009.03.018 ↗
39. Monitoring water and oxygen splitting at graphene edges and folds: Insights into the lubricity of graphitic materials10.1016/j.carbon.2019.09.040 ↗
40. Carbon-based films: A review on mechanical and tribology properties10.1016/j.matchemphys.2024.129716 ↗
41. Oxidation behavior of diamond-like carbon films10.1016/S0257-8972(99)00350-3 ↗
42. Solid lubricants: A review10.1007/s10853-012-7038-2 ↗
43. Influence of humidity on the tribological performance of graphite reinforced aluminium anodic oxide coating10.1016/j.triboint.2024.109752 ↗
44. Role of humidity in reducing sliding friction of multilayered graphene10.1016/j.carbon.2015.01.053 ↗
45. Role of humidity in reducing the friction of graphene layers on textured surfaces10.1016/j.apsusc.2017.01.226 ↗
46. Microstructure and high temperature tribological properties of copper-based graphite composite coatings reinforced with in-situ Fe3C10.1016/j.triboint.2024.110452 ↗
47. Chen, Z., He, X., Xiao, C., and Kim, S.H. (2018). Effect of Humidity on Friction and Wear—A Critical Review. Lubricants, 6.10.3390/lubricants6030074 ↗
48. The influence of atmospheric humidity and grain size on the friction and wear of AISI 304 austenitic stainless steel10.1016/S0167-577X(03)00351-3 ↗
49. Experimental study by means of thin layer activation of the humidity influence on the fretting wear of steel surfaces10.1016/S0043-1648(97)00189-0 ↗
50. Effect of surface texture on transfer layer formation and tribological behaviour of copper–graphite composite10.1016/j.wear.2010.10.062 ↗