journal article·2024-11-18Open access

Features of the Influence of the Arrangement of Parts in the Chamber of Installation During Vacuum Arc Deposition on the Properties of Coatings

Catherine Sotova, Marina Volosova, Alexey Vereschaka, Yuri Bublikov, Filipp Milovich, Anton Seleznev, Ilya Shmakov, Sergey Grigoriev

Applied Sciences· Volume 14· Issue 22

Abstract

The effect of the spatial arrangement in the physical vapor deposition (PVD) chamber on the composition and properties of coatings is considered using the example of the deposition of the (Ti,Al)N coating. The proposed method is one of the ways (along with varying the arc current of the cathodes and the bias voltage, as well as using alloy cathodes) to change the ratio of elements in the coating, and achieves this across a wide range of values. The three samples were located, respectively, opposite the evaporator with a titanium cathode, opposite the evaporator with an aluminum cathode and in an intermediate position between the two evaporators. The coating was deposited without rotating the turntable. The aluminum content in the coatings decreases from 94.2 at.% for the sample located directly opposite the evaporator with an Al cathode to 10.3 at.% for the sample located opposite the evaporator with a Ti cathode. In the coating deposited on the sample located opposite the aluminum cathode, the formation of a nitrided layer with a thickness of about 250 nm was observed in the substrate. The maximum hardness (32.3 ± 1.7 GPa) belongs to a coating on the sample occupying an intermediate position. The coating on the sample located opposite the aluminum cathode has a hardness of 16.7 ± 0.8 GPa. The coating hardness on the sample located opposite the titanium cathode is 28.5 ± 1.1 GPa. The best fracture strength in the scratch test was observed for the coating on the sample occupying an intermediate position. The nature of the coating fracture in the scratch test was studied. A sufficiently high-quality coating can be obtained without rotating the turntable, and the coating composition can be controlled by changing the position of the sample relative to the evaporators.
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Research context

OpenAlex topics: Metal and Thin Film Mechanics · Advanced materials and composites · Vacuum and Plasma Arcs

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of High-Efficiency Machining Technologies, Moscow State University of Technology “STANKIN”, Vadkovsky Lane 3a, 127055 Moscow, Russia

Institute of Design and Technological Informatics of the Russian Academy of Sciences (IDTI RAS), Vadkovsky Lane 18a, 127055 Moscow, Russia

Materials Science and Metallurgy Shared Use Research and Development Center, National University of Science and Technology “MISiS”, Leninsky Prospect 4, 119049 Moscow, Russia

Department of Materials Science, Moscow Polytechnic University, Bolshaya Semyonovskaya Street, 38, 107023 Moscow, Russia

Department of Digital and Additive Technologies, Federal State Budget Educational Institution of Higher Education «MIREA—Russian Technological University», Vernadsky Avenue, 78, 119454 Moscow, Russia

Funding

Ministry of Science and Higher Education of the Russian Federation

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