journal article·2024-10-01Open access

Electrochemical Performance of Ti Gr. 2 as Electrodes in Contact with Saline Suspension of Clays during the Electroflotation Process

Alvaro Soliz, Felipe M. Galleguillos-Madrid, José Ángel Cobos-Murcia, Sebastian Angulo, Sebastian Salazar-Avalos, Bernabé Alonso-Fariñas, Alexis Guzmán

Applied Sciences· Volume 14· Issue 19

Abstract

The presence of clays in copper minerals has a significant negative impact during their processing, leading to low recoveries during the flotation process. In saline environments, the presence of these clays promotes operational problems associated with salinity, leading to decreases in the copper concentrate grade, alterations in the rheology of the mineral pulp, reduction in the selectivity of copper during the flotation process, declines in the quality of clarified water, and excessive corrosion of metallic components. This study explores the electroflotation of kaolinite and montmorillonite clays in NaCl solutions using a modified Hallimond tube coupled with Ti Gr. 2 electrodes for bubble generation via water electrolysis and the corrosion analysis of these electrodes applying the superposition model. The electroflotation results show recovery of clays close to 72.68% for kaolinite, 88.44% for montmorillonite, and 67.36% for a mixture of both clays. The presence of clays helps reduce the corrosive effects of Ti Gr. 2 from 0.069 A/m2 in NaCl to 0.0073 A/m2 in NaCl with montmorillonite clay.
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Research context

OpenAlex topics: Iron oxide chemistry and applications · Radioactive element chemistry and processing · Minerals Flotation and Separation Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departamento de Ingeniería en Metalurgia, Universidad de Atacama, Av. Copayapu 485, Copiapó 1530000, Chile

Centro de Desarrollo Energético Antofagasta, Universidad de Antofagasta, Antofagasta 1240000, Chile

Instituto de Ciencias Básicas e Ingeniería, Universidad Autónoma del Estado de Hidalgo, Carr. Pachuca-Tulancingo km. 4.5, Mineral de la Reforma 42184, Hidalgo, Mexico

Departamento de Ingeniería Química y Ambiental, Escuela Técnica Superior de Ingeniería, Universidad de Sevilla, Camino de los Descubrimientos s/n, 41092 Sevilla, Spain

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