Time-Dependent, Two-Photon Rabi Frequency Shift Observed in Multi-Frequency Raman Spectra
Source abstract
Abstract
It has been observed that when the multi-frequency Raman scattering process is pumped by two frequency chirped pulses in the transient regime, the anti-Stokes orders are spectrally broadened on the lower-frequency side, causing each of the orders to have a broader spectrum with double-peak pattern. In this article, we employ frequency-resolved optical gating to study the spectral shift of the first anti-Stokes Raman order. A double-pulse model is introduced to determine the electric field of the anti-Stokes orders from the experimental FROG spectrogram. With the help from the double-pulse model, we demonstrate that the double-peaked spectrum comes from linear Raman scattering between manifolds in the two-photon dressed states.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Laser-Matter Interactions and Applications · Spectroscopy and Quantum Chemical Studies · Spectroscopy Techniques in Biomedical and Chemical Research
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Affiliations
Department of Physics and Astronomy, University of Waterloo, Waterloo, ON N2L 3G1, Canada
Funding
Natural Sciences and Engineering Research Council of Canada
References (18)
Show source-provided references
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