Potential of combating transmission of COVID-19 using novel self-cleaning superhydrophobic surfaces: part II—thermal, chemical, and mechanical durability
Source abstract
Abstract
In part I, we identified encapsulation, contamination suppression, and virus elimination as our three governing strategies for developing surfaces to combat the transmission and spread of COVID-19. We showed that our recent superhydrophobic nanocomposites has the potential of encapsulating and suppressing the virus so as to limit its transmission and spread. In this study, we examine the durability of the newly developed surfaces when subjected to elevated temperature, chemical attack and mechanical damage in the form of abrasion and compressive load. Extensive tests were conducted to reveal the effect of these parameters on the surface performance. Three aspects of the work were accordingly examined. The first was concerned with controlled thermal stability tests in which the surfaces were subjected to elevated temperatures approaching 350 °C for silicone-based nanocomposites and 150 °C for epoxy-based nanocomposites. The second was concerned with subjecting the surfaces to alkaline and acidic solutions with pH concentrations ranging between 1 and 13. Finally, the third involved surface damage by abrasion tests. Our results show clearly that the newly developed superhydrophobic surfaces are capable of resisting the adverse effects of thermal and chemical attacks as well as mechanical abrasion owing to the excellent structural stability and mechanical properties of the constituents of the nanocomposite. Moreover, our superhydrophobic monolith demonstrated exceptional regenerative capabilities even after being subjected to damaging compressive stresses of up to 10 MPa.
Source: europepmc · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Surface Modification and Superhydrophobicity · Infection Control and Ventilation
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (21)
Show source-provided references
1. BaratiDarband, G., Aliofkhazraei, M., Khorsand, S., Sokhanvar, S., Kaboli, A.: Science and engineering of superhydrophobic surfaces: review of corrosion resistance—chemical and mechanical stability. Arab. J. Chem. 13, 1763–1802 (2020). https://doi.org/10.1016/j.arabjc.2018.01.01310.1016/j.arabjc.2018.01.013 ↗
2. Cha, S.C., Her, E.K., Ko, T.J., Kim, S.J., Roh, H., Lee, K.R., Oh, K.H., Moon, M.W.: Thermal stability of superhydrophobic, nanostructured surfaces. J. Colloid Interface Sci. 391, 152–157 (2013). https://doi.org/10.1016/j.jcis.2012.09.05210.1016/j.jcis.2012.09.052 ↗
3. Cui, X., Lin, X., Liu, C., Yang, R., Zheng, X., Gong, M.: Fabrication and corrosion resistance of a hydrophobic micro-arc oxidation coating on AZ31 Mg alloy. Corros. Sci. 90, 402–412 (2015). https://doi.org/10.1016/j.corsci.2014.10.04110.1016/j.corsci.2014.10.041 ↗
4. Ellinas, K., Tserepi, A., Gogolides, E.: Durable superhydrophobic and superamphiphobic polymeric surfaces and their applications: a review. Adv. Colloid Interface Sci. 250, 132–157 (2017). https://doi.org/10.1016/j.cis.2017.09.00310.1016/j.cis.2017.09.003 ↗
5. Elzaabalawy, A., Verberne, P., Meguid, S.A.: Multifunctional silica—silicone nanocomposite with regenerative superhydrophobic capabilities. ACS Appl. Mater. Interfaces. 11, 42827–42837 (2019). https://doi.org/10.1021/acsami.9b1544510.1021/acsami.9b15445 ↗
6. Falde, E.J., Yohe, S.T., Colson, Y.L., Grinstaff, M.W.: Superhydrophobic materials for biomedical applications. Biomaterials 104, 87–103 (2016). https://doi.org/10.1016/j.biomaterials.2016.06.05010.1016/j.biomaterials.2016.06.050 ↗
7. Gralinski, L.E., Menachery, V.D.: Return of the coronavirus: 2019-nCoV. Viruses 12, 1–8 (2020). https://doi.org/10.3390/v1202013510.3390/v12020135 ↗
8. Ishizaki, T., Hieda, J., Saito, N., Saito, N., Takai, O.: Corrosion resistance and chemical stability of super-hydrophobic film deposited on magnesium alloy AZ31 by microwave plasma-enhanced chemical vapor deposition. Electrochim. Acta 55, 7094–7101 (2010). https://doi.org/10.1016/j.electacta.2010.06.06410.1016/j.electacta.2010.06.064 ↗
9. Jaggessar, A., Shahali, H., Mathew, A., Yarlagadda, P.K.D.V.: Bio-mimicking nano and micro-structured surface fabrication for antibacterial properties in medical implants. J. Nanobiotechnol. 15, 1–20 (2017). https://doi.org/10.1186/s12951-017-0306-110.1186/s12951-017-0306-1 ↗
10. Jeevahan, J., Chandrasekaran, M., BrittoJoseph, G., Durairaj, R.B.: Mageshwaran G (2018) Superhydrophobic surfaces: a review on fundamentals, applications, and challenges. J. Coat. Technol. Res. 15, 231–250 (2018). https://doi.org/10.1007/s11998-017-0011-x10.1007/s11998-017-0011-x ↗
11. Katoh, I., Tanabe, F., Kasai, H., Moriishi, K., Shimasaki, N., Shinohara, K., Uchida, Y., Koshiba, T., Arakawa, S., Morimoto, M.: Potential risk of virus carryover by fabrics of personal protective gowns. Front. Public Heal. 7, 3–8 (2019). https://doi.org/10.3389/fpubh.2019.0012110.3389/fpubh.2019.00121 ↗
12. Milionis, A., Loth, E., Bayer, I.S.: Recent advances in the mechanical durability of superhydrophobic materials. Adv. Colloid Interface Sci. 229, 57–79 (2016). https://doi.org/10.1016/j.cis.2015.12.00710.1016/j.cis.2015.12.007 ↗
13. Mortazavi, V., Khonsari, M.M.: On the degradation of superhydrophobic surfaces: a review. Wear 372–373, 145–157 (2017). https://doi.org/10.1016/j.wear.2016.11.00910.1016/j.wear.2016.11.009 ↗
14. Saleema, N., Farzaneh, M.: Thermal effect on superhydrophobic performance of stearic acid modified ZnO nanotowers. Appl. Surf. Sci. 254, 2690–2695 (2008). https://doi.org/10.1016/j.apsusc.2007.10.00410.1016/j.apsusc.2007.10.004 ↗
15. Shin, S., Seo, J., Han, H., Kang, S., Kim, H., Lee, T.: Bio-inspired extreme wetting surfaces for biomedical applications. Materials (Basel) (2016). https://doi.org/10.3390/ma902011610.3390/ma9020116 ↗
16. Tomšič, B., Simončič, B., Orel, B., Černe, L., Tavčer, P.F., Zorko, M., Jerman, I., Vilčnik, A., Kovač, J.: Sol-gel coating of cellulose fibres with antimicrobial and repellent properties. J. Sol-Gel. Sci. Technol. 47, 44–57 (2008). https://doi.org/10.1007/s10971-008-1732-110.1007/s10971-008-1732-1 ↗
17. Van Doremalen, N., Bushmaker, T., Morris, D., Holbrook, M., Gamble, A., Williamson, B., Tamin, A., Harcourt, J., Thornburg, N., Gerber, S., Lloyd-Smith, J.: Aerosol and surface stability of SARS-CoV-2 as compared with SARS-CoV-1. N. Engl. J. Med. 382(16), 1564–1567 (2020)10.1056/NEJMc2004973 ↗
18. Yang, P., Wang, X.: COVID-19: a new challenge for human beings. Cell. Mol. Immunol. (2020). https://doi.org/10.1038/s41423-020-0407-x10.1038/s41423-020-0407-x ↗
19. Yeerken, T., Wang, G., Li, H., Liu, H., Yu, W.: Chemical stable, superhydrophobic and self-cleaning fabrics prepared by two-step coating of a polytetrafluoroethylene membrane and silica nanoparticles. Text. Res. J. 89, 4827–4841 (2019). https://doi.org/10.1177/004051751984279510.1177/0040517519842795 ↗
20. Zhang, X., Wang, L., Levänen, E.: Superhydrophobic surfaces for the reduction of bacterial adhesion. RSC Adv. 3, 12003–12020 (2013). https://doi.org/10.1039/c3ra40497h10.1039/c3ra40497h ↗
21. Zhao, L., Hong, C., Lin, L., Wu, H., Su, Y., Zhang, X., Liu, A.: Controllable nanoscale engineering of vertically aligned MoS2 ultrathin nanosheets by nitrogen doping of 3D graphene hydrogel for improved electrocatalytic hydrogen evolution. Carbon N. Y. 116, 223–231 (2017). https://doi.org/10.1016/j.carbon.2017.02.01010.1016/j.carbon.2017.02.010 ↗