journal article·2020-10-17Open access

Sub-Picosecond Micromachining of Monocrystalline Silicon for Solar Cell Manufacturing

Katarzyna Garasz, Marek Kocik

Applied Sciences· Volume 10· Issue 20

Abstract

In this study a prototype sub-picosecond laser was investigated for cutting and scribing of silicon wafers. The Yb:KYW laser used for this investigation, unlike ultrashort systems used previously, generates pulses of 650 fs, i.e., between the pico and femtosecond range. The laser was placed in a micromachining setup, involving a galvo scanner and a telecentric lens. A study of the influence of the processing parameters on the crater width, depth, and quality of machining was carried out. The optimal parameters were found to be 343 nm, 200 kHz, 7 mm/s, and 15 pattern repetitions. The experiments were performed using samples of a silicon wafer of 210-µm thickness. The experimental results show that the sub-picosecond laser can be a promising and competitive tool for solar cell micromachining. In comparison to the commercially available ultrashort pulse laser systems, we find the sub-picosecond laser to be a more cost efficient and reliable source, than a femtosecond one. In addition, the prototype Yb:KYW design offers some unique parameters, such as repetition rate in the range of 100–400 kHz, UV wavelength or obtainable laser fluence close to the silicon ablation thresholds.
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Research context

OpenAlex topics: Laser Material Processing Techniques · Ocular and Laser Science Research · Advanced Surface Polishing Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centre for Plasma and Laser Engineering, Institute of Fluid Flow Machinery, Polish Academy of Sciences, Fiszera 14, 80-231 Gdańsk, Poland

References (30)

Show source-provided references
1. Ultrafast laser processing of silicon for photovoltaics10.1080/09506608.2017.1389547 ↗
2. Laser processing of solar cells
3. Laser Processing in Industrial Solar Module Manufacturing10.2961/jlmn.2010.03.0001 ↗
4. Comparison of structure and properties of femtosecond and nanosecond laser-structured silicon10.1063/1.1667004 ↗
5. Femtosecond laser-induced formation of submicrometer spikes on silicon in water10.1063/1.1828575 ↗
6. Visible and near-infrared responsivity of femtosecond-laser microstructured silicon photodiodes10.1364/OL.30.001773 ↗
7. Microstructured silicon photodetector10.1063/1.2227629 ↗
8. Infrared absorption by conical silicon microstructures made in a variety of background gases using femtosecond-laser pulses10.1063/1.1545159 ↗
9. Silicon Surface Morphologies after Femtosecond Laser Irradiation10.1557/mrs2006.160 ↗
10. Rear emitter n-type passivated emitter, rear totally diffused silicon solar cell Structure10.1063/1.2213927 ↗
11. Femtosecond laser for black silicon and photovoltaic cells
12. Dunsky, C. (2020, September 05). Laser Processes in PV Manufacturing: An Update. Industrial Laser Soultions for Manufacturing. Available online: http://www.industrial-lasers.com.
13. (2020, October 08). Available online: https://www.directindustry.com/.
14. Bovatsek, J.M., and Patel, R.S. (2010, January 26–28). Highest-speed dicing of thin silicon wafers with nanosecond-pulse 355nm q-switched laser source using line-focus fluence optimization technique. Proceedings of the SPIE LASE, San Francisco, CA, USA.10.1117/12.845298 ↗
15. Neuenschwander, B., Bucher, G.F., Hennig, G., Nussbaum, C., Joss, B., Muralt, M., Zehnder, S., Hunziker, U.W., and Schütz, P. (2010, January 26–30). Processing of dielectric materials and metals with PS laserpulses. Proceedings of the International Congress on Applications of Lasers & Electro-Optics, Anaheim, CA, USA.10.2351/1.5062103 ↗
16. Laser ablation and micromachining with ultrashort laser pulses10.1109/3.631270 ↗
17. Timescales in the response of materials to femtosecond laser excitation10.1007/s00339-004-2805-9 ↗
18. Ablation dynamics–from absorption to heat accumulation/ultra-fast laser matter interaction10.1515/aot-2018-0010 ↗
19. Experimental investigations on ultrashort laser ablation for micro and nanomachining of materials10.1088/1742-6596/1186/1/012028 ↗
20. Photovoltaics Report (2019). Fraunhofer Institute for Solar Energy Systems, FHG-SK: ISE-PUBLIC.
21. The absorption factor of crystalline silicon PV cells: A numerical and experimental study10.1016/j.solmat.2007.10.005 ↗
22. Femtosecond laser ablation behavior of gold, crystalline silicon, and fused silica: A comparative study10.1088/1054-660X/24/10/106102 ↗
23. Mechanical strength and fracture toughness of brittle monocrystalline and ceramic materials
24. Zeng, X., Mao, X., Greif, R., and Russo, R. (2004, January 20). Ultraviolet femtosecond and nanosecond laser ablation of silicon: Ablation efficiency and laser-induced plasma expansion. Proceedings of the SPIE, Taos, NM, USA.10.2172/836676 ↗
25. Lim, G., Tuan, A., Low, D., and Chen, Q. (2002, January 14–17). High quality laser microcutting of difficult-to-cut materials–copperand silicon wafer. Proceedings of the ICALEO, Scottsdale, AZ, USA.10.2351/1.5065764 ↗
26. Corboline, T., and Hoult, A.P. (2002, January 14–17). Laser machining of silicon using diode-pumped solid state & CO2 lasers. Proceedings of the the ICALEO, Scottsdale, AZ, USA.10.2351/1.5065750 ↗
27. Femtosecond laser ablation of silicon –modificationthresholds and morphology10.1007/s003390100893 ↗
28. Modelling ultrafast laser ablation10.1088/1361-6463/50/19/193001 ↗
29. Laser damage in silicon: Energy absorption, relaxation, and transport10.1063/1.4891633 ↗
30. Clark, D. (2009). Lasers in solar cell production. Photonics Spectra, Available online: https://www.photonics.com/Articles/Lasers_in_solar_cell_production/a40098.