Towards Woven Fabrics with Integrated Stainless Steel-Nickel-Carbon Thermopile for Sensing and Cooling Applications

Thermocouples can be combined into thermopiles to sense heat differences or achieve localized heating and cooling. However, integrating them into textiles using yarns is not straightforward, and chemical methods face challenges like complex processing, poor scalability, and voltage non-uniformity. This study employs conventional weaving to fabricate textile-based thermocouples and thermopiles for wearable sensing and potential cooling applications, with a focus on protective clothing. Using stainless steel and nickel-coated carbon yarns, we demonstrate a more stable thermocouple than those made with chemical or welded methods, with minimal fabric damage. Four conductive yarns, stainless steel, carbon fiber (CF), and nickel-coated carbon fiber (NiFC), were woven and laser-cut to form thermocouples using three different binding types to connect them. Inox1–NiFC was the most efficient thermocouple, achieving the highest Seebeck coefficient of 21.87 µV/K with Binding 3. Binding 3 also reduced contact resistance by 66% across all configurations. Slightly lower but comparable performance was seen with Inox1–NiFC/Binding 2 (21.83 µV/K) and Inox2–NiFC/Binding 1 (15.79 µV/K). In contrast, FC-based thermocouples showed significantly lower Seebeck values: 5.67 µV/K (Inox2–FC/Binding 2), 5.43 µV/K (Inox1–FC/Binding 3), and 5.06 µV/K (Inox2–FC/Binding 1). A woven thermopile with three junctions made with the optimal binding and thermocouple combination generated an average of 55.54 µV/K and about 500 µV at small temperature differences (4–5 °C), with a linear voltage response suitable for sensing. While thermal sensing proved effective, Peltier cooling needs further optimization. This method offers a stable, low-cost, and scalable platform for textile-integrated thermoelectric systems, with strong potential for use in uniforms and other protective garments.