journal article·2017-12

Experimental and analytical investigation of water diffusion process in nano-carbon/alumina/silica filled epoxy nanocomposites

M. A. Agwa, I. Taha, M. Megahed

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Abstract

This study discusses the water absorption behavior of three different types of nanocomposites. Silica, carbon and alumina nanoparticles are used as fillers incorporated in epoxy resin with different contents of 0.5, 1.5, and 3 wt%. A new nonlinear least-squares regression approach in conjunction with a gradient optimization was developed using symbolic manipulator MAPLE software to find the best fit. The equilibrium moisture content of the nanocomposites is measured as a function of time and the analytical modelling is successfully conducted. Results indicate that the addition of nanoparticles generally lower moisture content in contrast to neat epoxy. Compositions of 1.5 and 3 wt% alumina as well as silica nanocomposites however show a different behaviour. Diffusion coefficients for different types of nanocomposites were computed using Fickian and Langmuir models of diffusion. The least and highest diffusion coefficients correspond to the addition of silica 0.5 wt% and alumina 3 wt%, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Epoxy Resin Curing Processes · Polymer Nanocomposites and Properties · Asphalt Pavement Performance Evaluation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Alhuthali, A., Low, I.M.: Multi-scale hybrid eco-nanocomposites: synthesis and characterization of nano-SiC-reinforced vinyl-ester eco-composites. J. Mater. Sci. 48, 3097 (2013)10.1007/s10853-012-7084-9 ↗
2. Chapra, S.C., Canale, R.P.: Numerical Methods for Engineers, 6th edn. Mc Graw-Hill, New York (2010)
3. Chisholm, N., Mahfuz, H., Rangari, V., Ashfaq, A., Jeelani, Sh: Fabrication and mechanical characterization of carbon/SiC–epoxy nanocomposites. Compos. Struct. 67, 115 (2005)10.1016/j.compstruct.2004.01.010 ↗
4. Gouanve, F., Marais, S., Bessadok, A., Langevin, D., Tayer, M.: Kinetics of water sorption in flax and PET fibers. Eur. Polym. J. 43, 586 (2007)10.1016/j.eurpolymj.2006.10.023 ↗
5. Guadagno, L., Vertuccio, L., Sorrentino, A., Raimondo, M., Naddeo, C., Vittoriaa, V., Iannuzzo, G., Calvi, E., Russo, S.: Mechanical and barrier properties of epoxy resin filled with multi-walled carbon nanotubes. Carbon 47, 2419 (2009)10.1016/j.carbon.2009.04.035 ↗
6. Gurtin, M.E., Yatomi, C.: On a model for two phase diffusion in composite materials. J. Compos. Mater. 13, 126 (1979)10.1177/002199837901300204 ↗
7. Hongxia, Zh, Robert, K.Y.: Effect of water absorption on the mechanical and dielectric properties of nano-alumina filled epoxy nanocomposites. Compos. A 39, 602 (2008)10.1016/j.compositesa.2007.07.006 ↗
8. Jost, W.: Diffusion in Solids, Liquids, Gases. Academic Press, New York (1960)
9. Kim, J., Hu, Ch., Woo, R.S., Sham, M.: Moisture barrier characteristics of organoclay–epoxy nanocomposites. Compos. Sci. Technol. 65, 805 (2005)10.1016/j.compscitech.2004.10.014 ↗
10. Ladhari, A., Daly, H.B., Belhadjsalah, H., Cole, K.C., Denault, J.: Investigation of water absorption in clay-reinforced polypropylene nanocomposites. Polym. Degrad. Stab. 95, 429 (2010)10.1016/j.polymdegradstab.2009.12.001 ↗
11. Lin, Y.C., Chen, X.: Moisture sorption–desorption–resorption characteristics and its effect on the mechanical behavior of the epoxy system. Polymer 46, 11994 (2005)10.1016/j.polymer.2005.10.002 ↗
12. Liu, W., Hoa, S.V., Pugh, M.: Water uptake of epoxy–clay nanocomposites: model development. Compos. Sci. Technol. 67, 3308 (2007)10.1016/j.compscitech.2007.03.041 ↗
13. Liu, W., Hoa, S.V., Pugh, M.: Water uptake of epoxy–clay nanocomposites: experiments and model validation. Compos. Sci. Technol. 68, 2066 (2008)10.1016/j.compscitech.2007.07.024 ↗
14. MAPLE. Waterloo Maple Inc. http://www.maplesoft.com/ (2001)
15. Masclauxa, C., Gouanvea, F., Espuche, E.: Experimental and modelling studies of transport in starch nanocomposite films as affected by relative humidity. J. Membr. Sci. 363, 221 (2010)10.1016/j.memsci.2010.07.032 ↗
16. Mohan, T.P., Kanny, K.: Water barrier properties of nanoclay filled sisal fibre reinforced epoxy composites. Compos. A 42, 385 (2011)10.1016/j.compositesa.2010.12.010 ↗
17. Prolongo, S.G., Gude, M.R., Urena, A.: Water uptake of epoxy composites reinforced with carbon nanofillers. Compos. A 43, 2169 (2012)10.1016/j.compositesa.2012.07.014 ↗
18. Springer, G.S. (ed.): Environmental effects on composite materials. vol. 1, Technomic Publishing Co., Westport (1981)
19. Starkova, O., Buschhorn, S.T., Mannov, E., Schulte, K., Aniskevich, A.: Water transport in epoxy/MWCNT composites. Eur. Polym. J. 49, 2138 (2013)10.1016/j.eurpolymj.2013.05.010 ↗
20. Yang, B., Huang, W., Li, C., Chor, H.: Effects of moisture on the glass transition temperature of polyurethane shape memory polymer filled with nano-carbon powder. Eur. Polym. J. 41, 1123 (2005)10.1016/j.eurpolymj.2004.11.029 ↗
21. Zhuravlev, L.: The surface chemistry of amorphous silica. Zhuravlev model. Physicochem. Eng. Asp. 173, 1 (2000)10.1016/S0927-7757(00)00556-2 ↗