journal article·2024-09-09Open access

Exploring the Cutting Process of Coaxial Phase Change Fibers under Optical Characterization Tests

Nathalia Hammes, José Monteiro, Claver Pinheiro, Helena P. Felgueiras, Graça M. B. Soares, Iran Rocha Segundo, Manuel F. M. Costa, Joaquim Carneiro

Applied Sciences· Volume 14· Issue 17

Abstract

Urban heat islands (UHI) are a growing issue due to urbanization, causing citizens to suffer from the inadequate thermal properties of building materials. Therefore, the need for climate-resistant infrastructure is crucial for quality of life. Phase change materials (PCMs) offer a solution by being incorporated into construction materials for thermoregulation. PCMs store and release heat as latent heat, adjusting temperatures through phase changes. Polymeric phase change fibers (PCFs) are an innovative technology for encapsulating PCMs and preventing leaks. This study produced PCFs via wet-spinning, using commercial cellulose acetate (CA, Mn 50,000) as the sheath and polyethylene glycol (PEG 2000) as the core. The PCFs were cut using a hot-cutting method at three different temperatures and washed with distilled water. Morphological analysis was conducted with a bright-field microscope, and chemical analysis was performed using Fourier transform infrared spectroscopy (FTIR) before and after controlled washing. Additionally, the washing baths were analyzed by UV-visible spectroscopy to detect PEG. The PCFs displayed a well-defined core-shell structure. Although some PEG 2000 leakage occurred in unsuccessful cuts, cuts at 50 °C showed sealed ends and less material in the baths, making it viable for civil engineering materials.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Phase-change materials and chalcogenides · Phase Change Materials Research · Textile materials and evaluations

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centre of Physics of Minho and Porto Universities (CF-UM-UP), University of Minho, Av. da Universidade, 4800-058 Guimarães, Portugal

Earth Sciences Department of the University of Minho, Gualtar Campus, University of Minho, R. da Universidade, 4710-057 Braga, Portugal

ARISE, Department of Civil Engineering (ISISE-UMinho), University of Minho, Av. da Universidade, 4800-058 Guimarães, Portugal

Centre for Textile Science and Technology (2C2T-UMinho), University of Minho, Av. da Universidade, 4800-058 Guimarães, Portugal

Centre of Physics of Minho and Porto Universities (CF-UM-UP), Gualtar Campus, University of Minho, R. da Universidade, 4710-057 Braga, Portugal

Funding

Foundation for Science and Technology FCT/MCTES through national funds (PIDDAC) · Associated Laboratory for Advanced Manufacturing and Intelligent Systems ARISE · FCT

References (33)

Show source-provided references
1. Review and Analysis of Advances in Functionalized, Smart, and Multifunctional Asphalt Mixtures10.1016/j.rser.2021.111552 ↗
2. Classification, Mitigations and Methods to Detect UHI: A Review
3. Matos, A.M., Delgado, J.M.P.Q., and Guimarães, A.S. (2022). Linking Energy Poverty with Thermal Building Regulations and Energy Efficiency Policies in Portugal. Energies, 15.10.3390/en15010329 ↗
4. Pinheiro, C., Landi, S., Lima, O., Ribas, L., Hammes, N., Segundo, I.R., Homem, N.C., Castelo Branco, V., Freitas, E., and Costa, M.F. (2023). Advancements in Phase Change Materials in Asphalt Pavements for Mitigation of Urban Heat Island Effect: Bibliometric Analysis and Systematic Review. Sensors, 23.10.3390/s23187741 ↗
5. Performance Enhancement of Shell and Tube Latent Thermal Storage System Using Copper Foam10.24237/djes.2022.15304 ↗
6. Sharma, R., Jang, J.G., and Hu, J.W. (2022). Phase-Change Materials in Concrete: Opportunities and Challenges for Sustainable Construction and Building Materials. Materials, 15.10.3390/ma15010335 ↗
7. Phase Change Materials for Pavement Applications: A Review10.1016/j.conbuildmat.2020.118553 ↗
8. Incorporation of Phase Change Materials into Building Envelope for Thermal Comfort and Energy Saving: A Comprehensive Analysis10.1016/j.jobe.2020.102122 ↗
9. Wang, Z., Xie, Y., Mu, M., Feng, L., Xie, N., and Cui, N. (2022). Materials to Mitigate the Urban Heat Island Effect for Cool Pavement: A Brief Review. Buildings, 12.10.3390/buildings12081221 ↗
10. Review on Application of Phase Change Materials in Asphalt Pavement
11. Asadi, I., Jacobsen, S., Baghban, M.H., Maghfouri, M., and Hashemi, M. (2023). Reviewing the Potential of Phase Change Materials in Concrete Pavements for Anti-Freezing Capabilities and Urban Heat Island Mitigation. Buildings, 13.10.3390/buildings13123072 ↗
12. Hammes, N., Pinheiro, C., Segundo, I.R., Homem, N.C., Silva, M.M., Felgueiras, H.P., Soares, G.M.B., Freitas, E., Costa, M.F.M., and Carneiro, J.A.O. (2024). Coaxial Fibres Incorporated with Phase Change Materials for Thermoregulation Applications. Appl. Sci., 14.10.20944/preprints202402.1278.v1 ↗
13. A Perspective on the Wet Spinning Process and Its Advancements in Biomedical Sciences10.1016/j.eurpolymj.2022.111681 ↗
14. Homem, N.C., Tavares, T.D., Miranda, C.S., Antunes, J.C., Amorim, M.T.P., and Felgueiras, H.P. (2021). Functionalization of Crosslinked Sodium Alginate/Gelatin Wet-Spun Porous Fibers with Nisin z for the Inhibition of Staphylococcus Aureus-Induced Infections. Int. J. Mol. Sci., 22.10.3390/ijms22041930 ↗
15. Core-Sheath Phase Change Fibers via Coaxial Wet Spinning for Solar Energy Active Storage10.1016/j.compositesb.2022.110346 ↗
16. Theoretical Aspects of Fibre Laser Cutting10.1088/0022-3727/42/17/175507 ↗
17. Polymer Optical Fiber Sensors—A Review10.1088/0964-1726/20/1/013002 ↗
18. Cleaving of Microstructured Polymer Optical Fibres10.1016/j.optcom.2005.08.011 ↗
19. Chiang, J.S. (2018). Analysis of Leaky Modes in Photonic Crystal Fibers Using the Surface Integral Equation Method. Crystals, 8.10.3390/cryst8040177 ↗
20. Electrospun Cellulose Acetate Fibers for the Photodecolorization of Methylene Blue Solutions under Natural Sunlight10.1007/s00289-020-03324-y ↗
21. Phase-Change Materials for Controlled Release and Related Applications10.1002/adma.202000660 ↗
22. Comparison by Fourier Transform Infrared (FTIR) Spectroscopy of Different Ageing Techniques: Application to Road Bitumens10.1016/S0016-2361(00)00121-6 ↗
23. Liang, X., Kong, Y., Sun, H., Zhao, R., Jiao, L., Zhang, W., and Liu, B. (2023). Study on the Interaction Mechanism of Methoxy Polyethylene Glycol Maleimide with Sweet Potato β-Amylase. Molecules, 28.10.3390/molecules28052188 ↗
24. Morphology, Mechanical, and Physical Properties of Wet-Spun Cellulose Acetate Fiber in Different Solvent-Coagulant Systems and in-Situ Crosslinked Environment10.1002/app.50358 ↗
25. Zhuang, J., Li, M., Pu, Y., Ragauskas, A.J., and Yoo, C.G. (2020). Observation of Potential Contaminants in Processed Biomass Using Fourier Transform Infrared Spectroscopy. Appl. Sci., 10.10.3390/app10124345 ↗
26. Natural Cellulose Fibers: Heterogeneous Acetylation Kinetics and Biodegradation Behavior10.1021/bm0056409 ↗
27. Vibrational Spectp in the C-H Stretching Region and the Structure of the Polymethylene Chain10.1016/0584-8539(78)80167-6 ↗
28. A Bio-Inspired CO2-Philic Network Membrane for Enhanced Sustainable Gas Separation10.1039/C5TA03232F ↗
29. Segundo, I.R., Landi, S., Margaritis, A., Pipintakos, G., Freitas, E., Vuye, C., Blom, J., Tytgat, T., Denys, S., and Carneiro, J. (2020). Physicochemical and Rheological Properties of a Transparent Asphalt Binder Modified with Nano-TiO2. Nanomaterials, 10.10.3390/nano10112152 ↗
30. Cellulose Nanofibrils Endow Phase-Change Polyethylene Glycol with Form Control and Solid-to-Gel Transition for Thermal Energy Storage10.1021/acsami.0c18623 ↗
31. Culica, M.E., Chibac-Scutaru, A.L., Melinte, V., and Coseri, S. (2020). Cellulose Acetate Incorporating Organically Functionalized CeO2 NPs: Efficient Materials for UV Filtering Applications. Materials, 13.10.3390/ma13132955 ↗
32. Photodissociation Dynamics of N,N-Dimethylformamide at 225 Nm and 245 Nm10.1039/D2CP02662G ↗
33. Investigation of Polyethylene Glycol with Embedded Gold Nanoparticles Membranes