journal article·2024-07-30Open access

Iron Removal from Low-Grade Pyrophyllite Ore by Microwave Irradiation and Dry Magnetic Separation

Hussin A. M. Ahmed, Nesren Khairy, Maaz A. Ali

Applied Sciences· Volume 14· Issue 15

Abstract

Owing to its unique properties, pyrophyllite is an economical alternative to many minerals in different applications. The presence of iron-bearing minerals in Saudi pyrophyllite hampers its industrial uses. The aim of this study was to examine the removal of iron from Saudi low-grade pyrophyllite ore using two approaches. The first approach involves dry high-intensity magnetic separation, whereas the second approach involves microwave pretreatment of the ore before dry magnetic separation. For the first approach, the studied operating parameters were roll speed; feed rate, field intensity, and feed particle size. For the alternative approach, microwave treatment followed by dry magnetic separation, the microwave irradiation time and the magnetic field intensity were studied. The results show that the combined microwave treatment and dry separation method could provide high-purity pyrophyllite for filler industries. Microwave irradiation for 30 min was optimal to change impurity phases (i.e., pyrite, hematite) into ferromagnetic phases in microwave-treated pyrophyllite samples. At a magnetic field intensity of 2000 Gauss, the 30 min microwave-irradiated pyrophyllite sample achieved an iron recovery of 11.2% in non-magnetic fractions, with a removal efficiency of 89% with an alumina recovery of 91.31%.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Minerals Flotation and Separation Techniques · Metal Extraction and Bioleaching · Bauxite Residue and Utilization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Mining Engineering Department, King Abdulaziz University, Jeddah P.O. Box 80204, Saudi Arabia

Environmental Studies Department, National Authority of Remote Sensing and Space Sciences, El-Nozha El-Gedida, Cairo P.O. Box 1564, Egypt

Saudi Mining Polytechnic, Arar P.O. Box 215, Saudi Arabia

Geological Research Authority of Sudan, Ministry of Minerals, Khartoum P.O. Box 410, Sudan

Funding

Deanship of Scientific Research (DSR), King Abdulaziz University

References (36)

Show source-provided references
1. Physicochemical studies of pyrophyllite of the Nikol’sk deposit10.1007/s11148-010-9244-2 ↗
2. Evaluating the feasibility of pyrophyllite-based ceramic membranes for treating domestic wastewater in anaerobic ceramic membrane bioreactors10.1016/j.cej.2017.07.080 ↗
3. Kogel, J.E., Trivedi, N.C., Barker, J.M., and Krukowski, S.T. (2006). Industrial Minerals & Rocks: Commodities, Markets, and Uses, SME.
4. “A Review of Low-Grade Pyrophyllite ore Upgrading Techniques” Researchers: Abstract
5. XRD and HRTEM characterization of pyrophyllite from Morocco and its possible applications10.1016/S0169-1317(03)00066-8 ↗
6. Ali, M.A., Ahmed, H.A.M., Ahmed, H.M., and Hefni, M. (2021). Pyrophyllite: An Economic Mineral for Different Industrial Applications. Appl. Sci., 11.10.3390/app112311357 ↗
7. Thermal behaviour of sericite clays as precursors of mullite materials10.1007/s10973-018-7046-9 ↗
8. Solid-state 27Al and 29Si NMR and 1H CRAMPS studies of the thermal transformations of the 2:1 phyllosilicate pyrophyllite10.1021/jp961499f ↗
9. Interfacial characteristics between mineral fillers and phenolic resin in friction materials10.1166/mex.2020.1596 ↗
10. Song, S., Wu, Z., and Nie, J. (2020). Paper fillers innovations: From design of particles to preparing filler composites. BioResources, 15.10.15376/biores.15.2.2117-2118 ↗
11. Kutz, M. (2017). Functional Fillers for Plastics. Applied Plastics Engineering Handbook: Processing, Materials, and Applications, Elsevier Inc.
12. Ciullo, P.A. (1996). Industrial Minerals and Their Uses: A Handbook and Formulary, Noyes Publications. [1st ed.].10.1016/B978-081551408-4.50003-X ↗
13. Adsorption capacity of nitrate from artificial fertilizers and soil on pyrophyllite10.1007/s13762-021-03135-2 ↗
14. Qin, X., Zhao, J., Wang, J., and He, M. (2020). Atomic structure, electronic, and mechanical properties of pyrophyllite under pressure: A first-principles study. Minerals, 10.10.3390/min10090778 ↗
15. Refractory Composites Based on Pyrophyllite Raw Materials10.1007/s11148-018-0214-4 ↗
16. Industrial clays in the 21st century: A perspective of exploration, technology and utilization10.1016/S0169-1317(96)00028-2 ↗
17. Decleer, J.G.M. (1996). Introduction to Industrial Minerals, Chapman & Hall. [1st ed.].10.1016/0169-1317(95)00043-7 ↗
18. Production of Nano Amorphous SiO2 from Malatya Pyrophyllite10.1088/1755-1315/44/5/052004 ↗
19. Use of natural pyrophyllite as cement substitution in ultra performance polypropylene fiber concrete10.4028/www.scientific.net/JERA.56.123 ↗
20. Effect of organic acids on ferric iron removal from iron-stained kaolinite10.1016/S0169-1317(99)00038-1 ↗
21. Sequential microwave roasting and magnetic separation for removal of Fe and Ti impurities in low-grade pyrophyllite ore from Wando mine, South Korea10.1016/j.mineng.2019.105881 ↗
22. Removal of hematite from silica sand ore by reverse flotation technique10.1016/j.seppur.2007.08.023 ↗
23. Pyrophyllite as raw material for ceramic applications in the perspective of its pyro-chemical properties10.1016/j.ceramint.2009.10.026 ↗
24. Chatterjee, K.K. (2009). Uses of Industrial Minerals, Rocks and Freshwater, Nova Science Publishers.
25. Non-traditional domestic refractory materials for aluminum metallurgy10.1007/s11148-008-9090-7 ↗
26. Characterization and removal of iron from pyrophyllite ore for industrial applications
27. Kim, B.J., Cho, K.H., Lee, S.G., Park, C.Y., Choi, N.C., and Lee, S. (2018). Effective gold recovery from near-surface oxide zone using reductive microwave roasting and magnetic separation. Metals, 8.10.3390/met8110957 ↗
28. Iron role on mechanical properties of ceramics with clays from Ivory Coast10.1016/j.ceramint.2008.01.007 ↗
29. Ferreira, D.P. (2017). Structural Iron Removal from Clays Used in Ceramic Industries. [Master’s Thesis, University of Coimbra].
30. The Mineralogical and Chemical Characteristics of Fe Impurities and the Efficiency of their Removal Using Microwave Heating and Magnetic Separation in the Pyrophyllite Ore10.9727/jmsk.2016.29.2.47 ↗
31. Effect of microwave pre-treatment on the magnetic properties of iron ore and its implications on magnetic separation10.1016/j.seppur.2014.09.011 ↗
32. Effect of dry grinding and leaching on polytypic structure of pyrophyllite10.1016/0169-1317(93)90008-O ↗
33. Metamorphic-hosted pyrophyllite and dickite occurrences from the hydrous Al-silicate deposits of the Malatya-Pütürge region, central eastern Anatolia, Turkey10.1346/CCMN.2007.0550409 ↗
34. Changes of pyrite and pyrrhotite in coal upon microwave treatment10.1088/1742-6596/217/1/012051 ↗
35. Recent developments in microwave processing of minerals10.1179/174328006X79472 ↗
36. Chemical and Mineralogical Characterization of Saudi-Pyrophyllite ore and its potential applications