Quantitative Analysis of the Complex Time Evolution of a Camphor Boat
Source abstract
Abstract
The motion of a camphor boat on the water’s surface is a long-studied example of the direct transformation of chemical energy into a mechanical one. Recent experimental papers have reported a complex character of boat motion depending on the location of the camphor source. If the source is close to the stern, the boat moves at a constant speed. When it is shifted towards the boat center, oscillations of speed are observed. When the source is close to the boat center, pulses of speed followed by oscillations appear. Here, we focus on numerical simulations of camphor boat motion. We discuss approximations that allow us to reduce the numerical complexity of the problem and formulate a model in which the equation for boat velocity is coupled with a one-dimensional reaction–diffusion equation for camphor surface concentration. We scanned the phase space of model parameters and found the values that give qualitative agreement with the experiments. The model predicts all types of boat motion (continuous, oscillating, and pulsating) observed in experiments. Moreover, the model with selected parameter values shows that for specific locations of the camphor source, a spike in speed is followed by transient oscillations, which are an inherent part of speed relaxation.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Spectroscopy and Quantum Chemical Studies · Advanced Thermodynamics and Statistical Mechanics · Micro and Nano Robotics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
Department of Physics, Graduate School of Science, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522, Japan
Graduate School of Human Development and Environment, Kobe University, 3-11 Tsurukabuto, Nada-ku, Kobe 657-0011, Japan
Funding
PAN-JSPS
References (25)
Show source-provided references
1. Thermodynamics of chemical Marangoni driven engines10.1039/C7SM00840F ↗
2. Evolution of Self-Propelled Objects: From the Viewpoint of Nonlinear Science10.1002/chem.201705171 ↗
3. Self-rotation of a camphor scraping on water: New insight into the old problem10.1021/la970196p ↗
4. Pen-drawn Marangoni swimmer10.1038/s41467-023-39186-x ↗
5. On the motions of camphor on the surface of water10.1098/rspl.1860.0124 ↗
6. Measurements of the amount of oil necessary in order to check the motions of camphor upon water
7. Quantitative Estimation of the Parameters for Self-Motion Driven by Difference in Surface Tension10.1021/la501628d ↗
8. A camphor grain oscillates while breaking symmetry10.1021/jp004505n ↗
9. Intermittent motion of a camphor float10.1016/S0927-7757(03)00248-6 ↗
10. A theoretical and experimental study on the unidirectional motion of a camphor disk10.1016/j.physd.2004.02.003 ↗
11. Intermittent motion of a camphor float depending on the nature of the float surface on water10.1016/j.colsurfa.2009.07.054 ↗
12. Period of oscillatory motion of a camphor boat determined by the dissolution and diffusion of camphor molecules10.1021/acs.jpcb.7b11903 ↗
13. Synchronized self-motion of two camphor boats10.1021/la010388r ↗
14. Mode-switching of the self-motion of a camphor boat depending on the diffusion distance of camphor molecules10.1021/jp101838h ↗
15. New types of complex motion of a simple camphor boat10.1039/D2CP05707G ↗
16. Löffler, R. (Centre for Star and Planet Formation, University of Copenhagen, Copenhagen, Danemark). Private information, 2023.
17. Dynamic self-assembly in ensembles of camphor boats10.1021/jp7111457 ↗
18. Swarming in shallow waters10.1021/jz200180z ↗
19. Spreading dynamics of reactive surfactants driven by Marangoni convection10.1039/C8SM02641F ↗
20. Finite Volume Methods
21. Time-resolved measurements of interfacial tension and flow speed of the inclined water surface around a self-propelled camphor boat by the quasi-elastic laser scattering method10.1021/acs.jpcb.3c00466 ↗
22. Löffler, R.J.G. (2021). New Materials for Studies on Nanostructures and Spatio-Temporal Patterns Self-Organized by Surface Phenomena. Chapter IV.2. [Ph.D. Thesis, Institute of Physical Chemistry, Polish Academy of Sciences]. Available online: https://ichf.edu.pl/files/tytuly/loffler-phd-thesis.pdf.
23. Otani, S. (Department of Physics, Chiba University, Inage Ward, Chiba). Private information, 2023.
24. Dynamics of a camphoric acid boat at the air—Water interface10.1016/j.physleta.2018.02.026 ↗
25. Instability of vehicle systems moving along an infinite beam on a viscoelastic foundation10.1016/j.euromechsol.2017.12.007 ↗