journal article·2024-10-16Open access

Energy-Saving Extractive Distillation Process for Isopropanol Dehydration with Propylene Glycol as Novel Extractive Solvent

Marilena Nicolae, Mihaela Neagu, Diana Luciana Cursaru

Applied Sciences· Volume 14· Issue 20

Abstract

The extractive distillation process using propylene glycol (IUPAC name: 1,2 propanediol) as an extractive agent for the separation of the isopropanol–water system was investigated in this work. A systematic procedure was set out to obtain the optimal design and process conditions for extractive distillation and solvent recovery columns using the PRO/II process simulator. Four thermally integrated flowsheets were proposed, implying the recovery of the sensible heat and latent heat from the hot streams in the process. To establish the economic feasibility of the proposed process, we calculated the total annual cost for all the simulated versions, and the proposed fully thermally integrated flowsheets could save up to 43.13% in terms of the utility costs and up to 15.57% in terms of the TAC compared to the conventional design. Thus, propylene glycol (PG) is found to be suitable as a new solvent for isopropanol dehydration, being comparable with other classical solvents used for the dehydration of alcohols.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Process Optimization and Integration · Advanced Control Systems Optimization · Extraction and Separation Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Petroleum Refining and Environmental Engineering, Petroleum-Gas University of Ploiesti, 39. Bucuresti Blvd, 100680 Ploiesti, Romania

Funding

Petroleum-Gas University of Ploiesti, Romania

References (32)

Show source-provided references
1. Dehydration of IPA-H2O mixture: Review of fundamentals and proposal of novel energy-efficient separation schemes10.1016/j.ces.2023.118672 ↗
2. Performance comparison of falling film distillation process configurations for energy-saving ethanol-water separation10.1016/j.jiec.2024.01.059 ↗
3. Energy-saving improvement of heat integration for separating dilute azeotropic components in extractive distillation10.1016/j.energy.2022.125821 ↗
4. Conceptual design of sustainable extractive distillation processes combining preconcentration and extractive distillation functions for separating ternary multi-azeotropic mixture10.1016/j.ces.2022.118088 ↗
5. Investigation of energy-efficient heat pump assisted heterogeneous azeotropic distillation for separating of acetonitrile/ethyl acetate/n-hexane mixture10.1016/j.cjche.2022.04.015 ↗
6. Energy-saving reactive pressure-swing distillation process for separation of methanol—Dimethyl carbonate azeotrope via reacting with propylene oxide10.1016/j.seppur.2022.120889 ↗
7. Improving the economy and energy efficiency of separating n-propanol/water/tetrahydrofuran via triple-column pressure-swing distillation and azeotropic combining pressure-swing distillation10.1016/j.seppur.2022.123023 ↗
8. Membranes for the dehydration of solvents by pervaporation10.1016/j.memsci.2008.02.061 ↗
9. Dehydration of isopropanol by PVA–APTEOS/TEOS nanocomposite membranes10.1016/j.cherd.2010.06.004 ↗
10. Development of novel grafted hybrid PVA membranes using glycidyltrimethylammonium chloride for pervaporation separation of water–isopropanol mixtures10.1016/j.jiec.2012.08.032 ↗
11. Methodology for design of vapor permeation membrane-assisted distillation processes for aqueous azeotrope dehydration10.1016/j.memsci.2019.03.009 ↗
12. Efficient separation method for tert -butanol dehydration via extractive distillation10.1016/j.jtice.2016.07.040 ↗
13. Design and Control of an Isopropyl Alcohol Dehydration Process via Extractive Distillation Using Dimethyl Sulfoxide as an Entrainer10.1021/ie070996n ↗
14. A case study on separation of IPA-water mixture by extractive distillation using aspen plus10.19101/IJATEE.2016.324004 ↗
15. Isopropyl Alcohol Purification through Extractive Distillation using Glycerol as an Entrainer: Technical Performances Simulation and Design10.15294/jbat.v8i2.23477 ↗
16. Energy-saving thermally coupled ternary extractive distillation process by combining with mixed entrainer for separating ternary mixture containing bioethanol10.1016/j.energy.2018.01.161 ↗
17. Thermal integration of homogeneous azeotropic distillation sequences10.1002/aic.690360702 ↗
18. Novel Heat-Pump-Assisted Extractive Distillation for Bioethanol Purification10.1021/ie504459c ↗
19. Enhanced bioethanol dehydration by extractive and azeotropic distillation in dividing-wall columns10.1016/j.seppur.2011.10.022 ↗
20. Energy-Efficient Extractive Distillation Process by Combining Preconcentration Column and Entrainer Recovery Column10.1021/ie5002372 ↗
21. A systematic process synthesis method towards sustainable extractive distillation processes with pre-concentration for separating the binary minimum azeotropes10.1016/j.ces.2020.115932 ↗
22. New Operation Strategy for Separation of Ethanol–Water by Extractive Distillation10.1021/ie2026579 ↗
23. Optimization and control of energy saving side-stream extractive distillation with heat integration for separating ethyl acetate-ethanol azeotrope10.1016/j.ces.2019.115373 ↗
24. Energy efficient design through structural variations of complex heat-integrated azeotropic distillation of acetone-chloroform-water system10.1016/j.jiec.2022.02.012 ↗
25. Pressure Swing Batch Distillation for Homogeneous Azeotropic Separation10.1205/cherd06092 ↗
26. A new entrainer for separation of tetrahydrofuran–water azeotropic mixture by extractive distillation10.1016/j.cep.2006.02.001 ↗
27. (2024, September 10). Dow Chemical, Safety Data Sheet, Product name: Propylene Glycol USP/EP. Available online: https://www.dow.com/en-us/doc-viewer-blank.html?docType=SDS&contentType=SDS&product=59518z&tradeProduct=000000059518&selectedCountry=RO&selectedLanguage=EN&recordNumber=47749347&useRequestPath=true.
28. Separation of Tetrahydrofuran–Water Azeotropic Mixture by Batch Extractive Distillation Process10.1205/cherd05050 ↗
29. Prausnitz, J.M., Lichtenthaler, R.N., and de Azevedo, E.G. (1999). Molecular Thermodynamics of Fluid-Phase Equilibria, Prentice Hall PTR. [3rd ed.].
30. Plantwide control of an isopropyl alcohol dehydration process10.1002/aic.10807 ↗
31. Design and Optimization of Hybrid Separation Processes for the Dehydration of 2-Propanol and Other Organics10.1021/ie034194d ↗
32. Optimal design and synthesis of homogeneous azeotropic distillation sequences10.1021/ie00089a011 ↗