journal article·2022-01-01Open access

Microwave Synthesis, Characterization and Perspectives of Wood Pencil-Derived Carbon

Nikolaos Chalmpes, Georgios Asimakopoulos, Maria Baikousi, Constantinos E. Salmas, Dimitrios Moschovas, Apostolos Avgeropoulos, Athanasios B. Bourlinos, Iosif Tantis, Aristides Bakandritsos, Dimitrios Gournis, Michael A. Karakassides

Applied Sciences· Volume 12· Issue 1

Abstract

More than 14 billion pencils are manufactured and used globally every year. On average, a pencil is discarded after 60% of its original length has been depleted. In the present work we propose a simple and affordable way of converting this non-neglectable amount of waste into added value carbon product. In particular, we demonstrate the microwave synthesis of carbon from the wood pencil with and without chemical activation. This could be a process stage before the final recycling of the expensive graphite core. In the latter case, irradiation of the wood pencil in a domestic microwave oven heats up the pencil’s graphite core, thus inducing carbonization of its wood casing. The carbonized product consists of amorphous carbon nanosheets having relatively low surface area. However, if the wood pencil is soaked in 50% KOH aqueous solution prior to microwave irradiation, a significantly higher surface area of carbon is obtained, consisting of irregular-shaped porous particles. Consequently, the obtained carbon can easily decolorize a methylene blue aqueous solution, can be used to make pocket warmers or gunpowder, and lastly, serves as an excellent adsorbent towards Cr(VI) removal from water, showing a maximum adsorption capacity of 70–75 mg/g within 24 h at 23 °C, pH = 3.
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Research context

OpenAlex topics: Nanomaterials for catalytic reactions · Adsorption and biosorption for pollutant removal · Environmental remediation with nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science & Engineering, University of Ioannina, 45110 Ioannina, Greece

Physics Department, University of Ioannina, 45110 Ioannina, Greece

Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacký University, Křížkovského 511/8, 77900 Olomouc, Czech Republic

Nanotechnology Centre, Centre of Energy and Environmental Technologies, VŠB-Technical University of Ostrava, 70800 Ostrava, Czech Republic

Funding

European Regional Development Fund · State Scholarships Foundation (IKY) Greece · Ministry of Education, Youth and Sports of the Czech Republic · Czech Science Foundation

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