journal article·2021-05-14Open access

Feasibility of Probing the Filler Restructuring in Magnetoactive Elastomers by Ultra-Small-Angle Neutron Scattering

Inna A. Belyaeva, Jürgen Klepp, Hartmut Lemmel, Mikhail Shamonin

Applied Sciences· Volume 11· Issue 10

Abstract

Ultra-small-angle neutron scattering (USANS) experiments are reported on isotropic magnetoactive elastomer (MAE) samples with different concentrations of micrometer-sized iron particles in the presence of an in-plane magnetic field up to 350 mT. The effect of the magnetic field on the scattering curves is observed in the scattering vector range between 2.5 × 10−5 and 1.85 × 10−4 Å−1. It is found that the neutron scattering depends on the magnetization history (hysteresis). The relation of the observed changes to the magnetic-field-induced restructuring of the filler particles is discussed. The perspectives of employing USANS for investigations of the internal microstructure and its changes in magnetic field are considered.
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Research context

OpenAlex topics: Vibration Control and Rheological Fluids · Characterization and Applications of Magnetic Nanoparticles · Fluid Dynamics and Vibration Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

East Bavarian Centre for Intelligent Materials (EBACIM), Ostbayerische Technische Hochschule (OTH) Regensburg, Prüfeninger Str. 58, 93049 Regensburg, Germany

Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna, Austria

Atominstitut, Technische Universität Wien, 1020 Vienna, Austria

Institut Laue-Langevin, 38042 Grenoble, France

Funding

State Conference of Women and Equality Officers at Bavarian Universities

References (37)

Show source-provided references
1. Gong, B., Sanford, A.R., and Ferguson, J.S. (2007). Magnetic Field-Responsive Smart Polymer Composites. Oligomers–Polymer Composites-Molecular Imprinting, Springer. Advances in Polymer Science.
2. A State-of-the-Art Review on Magnetorheological Elastomer Devices10.1088/0964-1726/23/12/123001 ↗
3. Recent Progress on Magnetorheological Solids: Materials, Fabrication, Testing, and Applications10.1002/adem.201400258 ↗
4. Tuned, Driven, and Active Soft Matter10.1016/j.physrep.2014.10.001 ↗
5. Microstructure and Rheology of Magnetic Hybrid Materials10.1007/s00419-015-1092-6 ↗
6. Mechanics of Magnetopolymer Composites: A Review10.1166/jon.2016.1233 ↗
7. Polymer Architecture of Magnetic Gels: A Review10.1088/1361-648X/aaa344 ↗
8. Domracheva, N., Caporali, M., and Rentschler, E. (2018). Chapter 7–Highly Responsive Magnetoactive Elastomers. Novel Magnetic Nanostructures, Elsevier. Advanced Nanomaterials.
9. Recent Progress of Magnetorheological Elastomers: A Review10.1088/1361-665X/abbc77 ↗
10. Modeling of Magneto-Mechanical Response of Magnetorheological Elastomers (MRE) and MRE-Based Systems: A Review10.1088/1361-665X/aa549c ↗
11. Novel Highly Elastic Magnetic Materials for Dampers and Seals: Part I. Preparation and Characterization of the Elastic Materials10.1002/pat.924 ↗
12. Borbáth, T., Günther, S., Borin, D., Gundermann, T., and Odenbach, S. (2012). XμCT Analysis of Magnetic Field-Induced Phase Transitions in Magnetorheological Elastomers. Smart Mater. Struct., 21.10.1088/0964-1726/21/10/105018 ↗
13. Direct Observation of Particle Rearrangement during Cyclic Stress Hardening of Magnetorheological Gels10.1039/c2sm26587g ↗
14. In-Situ Observation of the Particle Microstructure of Magnetorheological Elastomers in Presence of Mechanical Strain and Magnetic Fields10.1016/j.jmmm.2017.05.024 ↗
15. Statistical Analysis of Magnetically Soft Particles in Magnetorheological Elastomers10.1088/1361-665X/aa5f96 ↗
16. Small-Angle Neutron Scattering in Structure Research of Magnetic Fluids10.3367/UFNe.0180.201010a.1009 ↗
17. Evidence for Diffusion-Induced Convection in Ferrofluids from Small-Angle Neutron Scattering10.1007/BF01313857 ↗
18. SANS Study of Concentration Effect in Magnetite/Oleic Acid/Benzene Ferrofluid10.1007/s003390201674 ↗
19. The Microstructure of Ferrofluids and Their Rheological Properties10.1002/aoc.755 ↗
20. Balasoiu, M., Craus, M.L., Plestil, J., Haramus, V., Erhan, R., Lozovan, M., Kuklin, A.I., and Bica, I. (2021, May 12). Microstructure of Magnetite Doped Elastomers Investigated by SAXS and SANS. 2008, 11. Available online: https://www.researchgate.net/publication/242829586_Microstructure_of_magnetite_doped_elastomers_investigated_by_SAXS_and_SANS.
21. Microstructure of Stomaflex Based Magnetic Elastomers10.1134/S1063783410050070 ↗
22. SANS Investigation of a Ferrofluid Based Silicone Elastomer Microstructure10.1088/1742-6596/351/1/012014 ↗
23. The Implicit Effect of Texturizing Field on the Elastic Properties of Magnetic Elastomers Revealed by SANS10.1016/j.jmmm.2016.09.109 ↗
24. Scattering Properties and Internal Structure of Magnetic Filament Brushes10.1039/C6SM02606K ↗
25. Characterization of a Magnetic Fluid Exposed to a Shear Flow and External Magnetic Field Using Small Angle Laser Scattering10.1016/j.jmmm.2019.165959 ↗
26. In Situ Magnetorheological SANS Setup at Institut Laue-Langevin10.1007/s00396-020-04713-5 ↗
27. Magnetorheological Response of Highly Filled Magnetoactive Elastomers from Perspective of Mechanical Energy Density: Fractal Aggregates above the Nanometer Scale?10.1103/PhysRevE.95.062501 ↗
28. Magnetodielectric Effect in Magnetoactive Elastomers: Transient Response and Hysteresis10.1016/j.polymer.2017.08.056 ↗
29. The New High Resolution Ultra Small-Angle Neutron Scattering Instrument at the High Flux Reactor in Grenoble10.1107/S0021889899013394 ↗
30. Zubarev, A., Chirikov, D., Borin, D., and Stepanov, G. (2016). Hysteresis of the Magnetic Properties of Soft Magnetic Gels. Soft Matter, 12.10.1039/C6SM01257D ↗
31. Chain Formation in a Magnetic Fluid under the Influence of Strong External Magnetic Fields Studied by Small Angle Neutron Scattering10.1039/c1sm05104k ↗
32. Elongated Micro-Structures in Magneto-Sensitive Elastomers: A Dipolar Mean Field Model10.1039/C6SM01798C ↗
33. Theoretical Method for Calculation of Effective Properties of Composite Materials with Reconfigurable Microstructure: Electric and Magnetic Phenomena10.1016/j.physa.2019.122467 ↗
34. Induced anisotropy in composite materials with reconfigurable microstructure: Effective medium model with movable percolation threshold10.1016/j.physa.2020.125170 ↗
35. Pipich, V. Magnetic-Field-Induced Structural Changes in Compliant Magnetorheological Elastomers. Private Communication,.
36. Motion of Ferroparticles Inside the Polymeric Matrix in Magnetoactive Elastomers10.1088/0953-8984/20/20/204121 ↗
37. Magnetic Anisotropy in Magnetoactive Elastomers, Enabled by Matrix Elasticity10.1016/j.polymer.2018.12.027 ↗