Structure and Stability of Gas Adsorption Complexes in Periodic Porous Solids as Studied by VTIR Spectroscopy: An Overview
Source abstract
Abstract
Variable-temperature infrared (VTIR) spectroscopy is an instrumental technique that enables structural characterization of gas-solid adsorption complexes by analysis of meaningful vibrational modes, and simultaneous determination of the standard enthalpy change (ΔH0) involved in the gas adsorption process, which allows one to quantify the stability of the corresponding complex. This is achieved by a van’t Hoff analysis of a set of IR spectra recorded over a sufficiently large temperature range. Herein, the use of this versatile spectroscopic technique is demonstrated by reviewing its application to the study of carbon monoxide, carbon dioxide and dinitrogen adsorption on several (alkaline) zeolites, which can be regarded as the archetype of periodic porous solids.
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Research context
OpenAlex topics: Catalytic Processes in Materials Science · Carbon Dioxide Capture Technologies · Metal-Organic Frameworks: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, University of the Balearic Islands, 07122 Palma, Spain
References (100+)
Show source-provided references
1. Oxygen separation from air by PSA: Modelling and experimental results10.1016/S1383-5866(00)00227-6 ↗
2. Oxygen Separation from Air by Four-Bed Pressure Swing Adsorption10.1021/ie801805k ↗
3. Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process10.1016/j.energy.2009.12.033 ↗
4. Oxygen separation from air using zeolite type 5A
5. Adsorption separation of carbon dioxide, methane and nitrogen on H and Na-exchanged-zeolite10.1016/S1003-9953(09)60015-3 ↗
6. CO2 separation and landfill biogas upgrading: A comparison of 4A and 13X zeolite adsorbents10.1016/j.energy.2010.10.038 ↗
7. Regenerability of zeolites as adsorbents for natural gas sweetening: A case-study10.1016/j.fuel.2011.08.051 ↗
8. Adsorption isotherms and ideal selectivities of hydrogen sulfide and carbon dioxide over methane for the Si-CHA zeolite: Comparison of carbon dioxide and methane adsorption with the all-silica DD3R zeolite10.1007/s10450-013-9528-1 ↗
9. Metal−Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture10.1021/ja111411q ↗
10. Multicomponent adsorption of H2, CH4, CO and CO2 in zeolites NaX, CaX and MgX. Evaluation of performance in PSA cycles for hydrogen purification10.1016/j.micromeso.2019.05.021 ↗
11. Poly-metal-benzimidazol nano-composite membrane for hydrogen purification10.1039/c1ee01324f ↗
12. Carbon Dioxide Capture: Prospects for New Materials10.1002/anie.201000431 ↗
13. Carbon capture by physical adsorption: Materials, experimental investigations and numerical modeling and simulations—A review10.1016/j.apenergy.2015.10.011 ↗
14. Combined DFT/CC and IR spectroscopic studies on carbon dioxide adsorption in the zeolite H-FER10.1039/b911253g ↗
15. Adsorption of CO2 in FAU zeolites: Effect of zeolite composition10.1016/j.cattod.2013.10.036 ↗
16. Removal of VOCs from indoor environment by ozonation over different porous materials10.1016/j.atmosenv.2007.12.030 ↗
17. Experimental and computational investigation of adsorption performance of TC-5A and PSA-5A for manned spacecraft10.1016/j.cja.2015.08.003 ↗
18. Multiobjective optical method for carbon dioxide removal assembly in manned spacecraft
19. Energy efficient indoor VOC air cleaning with activated carbon fiber (ACF) filters10.1016/j.buildenv.2011.07.002 ↗
20. Porous Adsorbents for Vehicular Natural Gas Storage: A Review10.1023/A:1009673830619 ↗
21. Methane storage in advanced porous materials10.1039/c2cs35251f ↗
22. Role of microporosity in hydrogen adsorption on templated nanoporous carbons10.1016/j.micromeso.2007.10.017 ↗
23. High pressure adsorption of hydrogen, nitrogen, carbon dioxide and methane on the metal-organic framework HKUST-110.1016/j.micromeso.2010.09.013 ↗
24. Synthesis and characterization of porous HKUST-1 metal organic frameworks for hydrogen storage10.1016/j.ijhydene.2012.04.105 ↗
25. Preparation, characterization, and hydrogen storage capacity of MIL-53 metal-organic frameworks10.1166/jnn.2013.7372 ↗
26. Hydrogen Adsorption Characteristics for Zeolite-Y Templated Carbon10.22146/ijc.38978 ↗
27. Materials for hydrogen storage: Current research trends and perspectives10.1039/B712576N ↗
28. Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites10.1002/anie.200801163 ↗
29. Hydrogen fuel tanks for subsonic transport aircraft10.1016/j.ijhydene.2010.06.060 ↗
30. Greenhouse gas emissions assessment of hydrogen and kerosene-fueled aircraft propulsion10.1016/j.ijhydene.2008.11.017 ↗
31. Analysis of the control strategies for fuel saving in the hydrogen fuel cell vehicles10.1016/j.ijhydene.2017.12.150 ↗
32. Issues related to fuel cells application to small drones propulsion10.1088/1757-899X/421/4/042014 ↗
33. Long range transport aircraft using hydrogen fuel10.1016/j.ijhydene.2013.09.021 ↗
34. Hydrogen powered aircraft: The future of air transport10.1016/j.paerosci.2012.12.002 ↗
35. Modelling the potential of adsorbed hydrogen for use in aviation10.1016/j.micromeso.2014.08.038 ↗
36. A fuel cell powered unmanned aerial vehicle for low altitude surveillance missions10.1016/j.ijhydene.2017.01.137 ↗
37. Variable-temperature infrared spectroscopy and access to adsorption thermodynamics of weakly interacting systems10.1039/B209299A ↗
38. Variable temperature infrared spectroscopy: A convenient tool for studying the thermodynamics of weak solid-gas interactions10.1039/b407049f ↗
39. Probing Bronsted acidity of protonic zeolites with variable-temperature infrared spectroscopy10.15407/ujpe63.6.538 ↗
40. Synthesis of chloropropylamine grafted mesoporous MCM-41, MCM-48 and SBA-15 from rice husk ash: Their application to CO2 chemisorption10.1007/s10934-009-9310-7 ↗
41. CO2 Adsorption by Amine-Functionalized MCM-41: A Comparison between Impregnation and Grafting Modification Methods10.1021/acs.energyfuels.7b02906 ↗
42. Gas Storage in Nanoporous Materials10.1002/anie.200703934 ↗
43. Development and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture10.1002/anie.201101891 ↗
44. The new age of MOFs and of their porous-related solids10.1039/C7CS90049J ↗
45. Hybrid porous solids: Past, present, future10.1039/B618320B ↗
46. Pettinari, C., and Tombesi, A. (2020). Metal-organic frameworks for carbon dioxide capture. MRS Energy & Sustainability, Cambridge University Press.10.1557/mre.2020.30 ↗
47. Synthesis and characterization of ordered porous carbons with potential applications as hydrogen storage media10.1016/j.micromeso.2007.01.049 ↗
48. High-Pressure Hydrogen Storage in Zeolite-Templated Carbon10.1021/jp808890x ↗
49. Effects of synthesis parameters on zeolite templated carbon for hydrogen storage application10.1016/j.micromeso.2013.03.014 ↗
50. High pressure carbon dioxide adsorption on nanoporous carbons prepared by Zeolite Y templating10.1016/j.matlet.2011.03.039 ↗
51. Post-synthesis modifications of SBA-15 carbon replicas: Improving hydrogen storage by increasing microporous volume10.1016/j.cattod.2008.05.002 ↗
52. Two Coordination Modes of CO in Zeolites: A Temperature-Dependent Equilibrium10.1002/(SICI)1521-3773(19981204)37:22<3161::AID-ANIE3161>3.0.CO;2-B ↗
53. Variable-temperature IR spectroscopic studies of CO adsorbed on Na-ZSM-5 and Na-Y zeolites10.1023/A:1019089309446 ↗
54. Quantum Chemical Calculations and Experimental Evidence for O-Bonding of Carbon Monoxide to Alkali Metal Cations in Zeolites10.1021/jp982078w ↗
55. Formation of several types of coordination complexes upon CO adsorption on the zeolite Li-ZSM-510.1039/b105669g ↗
56. Barrer, R.M. (1978). Zeolites and Clay Minerals as Sorbents and Molecular Sieves, Academic Press.
57. Szostak, R. (1989). Molecular Sieves: Principles of Synthesis and Identification, Van Nostrand Reinhold.10.1007/978-94-010-9529-7 ↗
58. Meier, W., and Olson, D.H. (1992). Altas of Zeolite Structure Types, Butterworth-Heinemann.
59. Zeolites and Intrazeolite Chemistry: Insights from Infrared Spectroscopy10.1080/02603590008050871 ↗
60. Molar Entropy and Enthalpy of CO Adsorbed in Zeolites as Derived from VTIR Data: Role of Intermolecular Modes10.1002/open.202000019 ↗
61. Compensation Phenomena in Heterogeneous Catalysis: General Principles and a Possible Explanation10.1081/CR-100100264 ↗
62. Infrared spectroscopic studies on the binding isomerism of adsorbed molecules10.1023/B:KICA.0000038081.43384.56 ↗
63. Thermodynamic and vibrational characterization of CO adsorption on variously pretreated anatase
64. Direct Calorimetric Measurement of Enthalpy of Adsorption of Carbon Dioxide on CD-MOF-2, a Green Metal−Organic Framework10.1021/ja402315d ↗
65. The nature of cationic adsorption sites in alkaline zeolites- single, dual and multiple cation sites10.1039/C2CP23237E ↗
66. Ab-initio molecular dynamics simulation of the liquid-metal amorphous-semiconductor transition in germanium10.1103/PhysRevB.49.14251 ↗
67. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set10.1016/0927-0256(96)00008-0 ↗
68. Generalized Gradient Approximation Made Simple10.1103/PhysRevLett.77.3865 ↗
69. From ultrasoft pseudopotentials to the projector augmented-wave method10.1103/PhysRevB.59.1758 ↗
70. Projector augmented-wave method10.1103/PhysRevB.50.17953 ↗
71. Carbon monoxide adsorption on low-silica zeolites—from single to dual and to multiple cation sites10.1039/b709073k ↗
72. Thermodynamics of reversible gas adsorption on alkali-metal exchanged zeolites—the interplay of infrared spectroscopy and theoretical calculations10.1039/B615535A ↗
73. Carbon monoxide poisoning10.1016/j.emc.2004.05.003 ↗
74. Carbon monoxide poisoning10.1056/NEJMcp0808891 ↗
75. The CO Poisoning Mechanism of the Hydrogen Oxidation Reaction in Proton Exchange Membrane Fuel Cells10.1149/1.1473775 ↗
76. Multi-dimentional modeling of copoisoning effects on proton Exchange membrane fuel cells (PEMFCs)10.1007/s12206-008-0207-1 ↗
77. The CO Poisoning Effect in PEMFCs Operational at Temperatures up to 200 °C10.1149/1.1619984 ↗
78. Diatomic molecular probes for mid-IR studies of zeolites10.1039/CS9962500187 ↗
79. IR spectroscopy of small and weakly interacting molecular probes for acidic and basic zeolites10.1039/a802189i ↗
80. Characterization of oxide surfaces and zeolites by carbon monoxide as an IR probe molecule10.1016/S0360-0564(02)47008-3 ↗
81. Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy10.1039/c0cs00117a ↗
82. Infrared spectroscopic and thermodynamic assessment of extraframework cationic adsorption sites in the zeolite K-L by using CO as probe molecule10.1016/j.cplett.2015.09.028 ↗
83. Brønsted acidity of H-MCM-22 as probed by variable-temperature infrared spectroscopy of adosrbed CO and N210.1016/j.cattod.2013.09.013 ↗
84. Measuring the Brønsted acid strength of zeolites—Does it correlate with the O-H frequency shift probed by a weak base?10.1039/C3CP54738H ↗
85. Computational and Fourier Transform Infrared Spectroscopic Studies on Carbon Monoxide Adsorption on the Zeolites Na-ZSM-5 and K-ZSM-5: Evidence of Dual-Cation Sites10.1021/jp7109934 ↗
86. Photochemical and photophysical studies of organic molecules included within zeolites10.1021/ar00019a005 ↗
87. Zeolites as solid solvents10.1016/S1381-1169(98)00021-1 ↗
88. The catalytic activity of zeolites: Confinement effect within voids of molecular dimensions10.1039/c3cc40731d ↗
89. Chemistry in Confining Reaction Fields with Special Emphasis on Nanoporous Materials10.1002/chem.200800674 ↗
90. CO adsorption complexes in zeolites: How does the inclusion of dispersion interactions affect predictions made from DFT calculations? The case of Na-CHA10.1007/s00214-015-1692-9 ↗
91. The vibrational dynamics of carbon monoxide in a confined space—CO in zeolites10.1039/B612238H ↗
92. Periodic density functional and FTIR spectroscopic studies on CO adsorption on the zeolite Na-FER10.1016/j.micromeso.2007.02.049 ↗
93. Low-temperature CO and 15N2 adsorption and co-adsorption on alkali cation exchanged EMT zeolites: An FTIR study10.1039/a904171k ↗
94. FTIR study of the low-temperature adsorption and co-adsorption of CO and N2 on NaY zeolite: Evidence of simultaneous coordination of two molecules to one Na+ site10.1016/S0009-2614(99)00229-8 ↗
95. Carbon monoxide bond-length, force constant and infrared intensity variations in strong electric fields: Valence shell calculations, with applications to properties of adsorbed and complexed CO10.1016/0022-2852(74)90241-0 ↗
96. Stretching frequencies of cation-CO adducts in alkali-metal exchanged zeolites: An elementary electrostatic approach10.1063/1.470249 ↗
97. Isomeric states of polar molecules on ionic surfaces: Electrostatic model and FTIR studies10.1016/j.apsusc.2004.05.242 ↗
98. Calorimetric heats of adsorption and adsorption isotherms. 2. O2, N2, Ar, CO2, CH4, C2H6 and SF6 on NaX, H-ZSM-5, and Na-ZSM-5 zeolites10.1021/la960496r ↗
99. Variable-Temperature IR Spectroscopic and Theoretical Studies on CO2 Adsorbed in Zeolite K-FER10.1002/cphc.201000995 ↗
100. Experimental and quantum-chemical studies on the adsorption of carbon dioxide in alkali-metal-exchanged ZSM-5 zeolites10.1021/jp000555g ↗