journal article·2021-03-30Open access

Grazing Incidence Small-Angle Neutron Scattering: Background Determination and Optimization for Soft Matter Samples

Tetyana Kyrey, Marina Ganeva, Judith Witte, Artem Feoktystov, Stefan Wellert, Olaf Holderer

Applied Sciences· Volume 11· Issue 7

Abstract

Grazing incidence small-angle neutron scattering (GISANS) provides access to interfacial properties, e.g., in soft matter on polymers adsorbed at a solid substrate. Simulations in the frame of the distorted wave Born approximation using the BornAgain software allow to understand and quantify the scattering pattern above and below the sample horizon, in reflection and transmission, respectively. The small-angle scattering from the interfacial layer, visible around the transmitted beam, which might contribute also on the side of the reflected beam, can be understood in this way and be included into the analysis. Background reduction by optimized sample cell design is supported by simulations, paving the way for an optimized GISANS cell.
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Research context

OpenAlex topics: Nuclear Physics and Applications · NMR spectroscopy and applications · Quantum, superfluid, helium dynamics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science (JCNS) at Heinz Maier-Leibnitz Zentrum (MLZ), 52425 Garching, Germany

Institute of Chemistry, Technical University Berlin, 10623 Berlin, Germany

Funding

Deutsche Forschungsgemeinschaft

References (43)

Show source-provided references
1. Light-Induced Color Changes of Microgel-Based Etalons10.1021/am501330z ↗
2. Pulsatile Release of Insulin from Layer-by-Layer Assembled Microgel Thin Films10.1002/masy.200550928 ↗
3. Patterned Thermoresponsive Microgel Coatings for Noninvasive Processing of Adherent Cells10.1021/acs.biomac.5b01728 ↗
4. Polymer-based sensors: A review10.1016/j.polymertesting.2018.03.024 ↗
5. First-principles determination of hybrid bilayer membrane structure by phase-sensitive neutron reflectometry10.1016/S0006-3495(00)76564-7 ↗
6. Effect of benzocaine and propranolol on phospholipid-based bilayers10.1039/C7CP06077G ↗
7. Jaksch, S., Lipfert, F., Koutsioumpas, A., Mattauch, S., Holderer, O., Ivanova, O., Frielinghaus, H., Hertrich, S., Fischer, S.F., and Nickel, B. (2015). Influence of ibuprofen on phospholipid membranes. Phys. Rev. E, 91.10.1103/PhysRevE.91.022716 ↗
8. Nanostructured Diblock Copolymer Films: A Grazing Incidence Small-Angle Neutron Scattering Study10.1021/la0267241 ↗
9. Grazing incidence scattering—Status and perspectives in soft matter and biophysics10.1016/j.cocis.2019.04.001 ↗
10. Grazing-incidence small-angle neutron scattering from structures below an interface10.1107/S1600576717007518 ↗
11. Grazing incidence SANS and reflectometry combined with simulation of adsorbed microgel particles10.1016/j.physb.2018.03.049 ↗
12. The active layer morphology of organic solar cells probed with grazing incidence scattering techniques10.1002/adma.201304187 ↗
13. Influence of the cross-linker content on adsorbed functionalised microgel coatings10.1016/j.polymer.2019.02.037 ↗
14. Structure formation in two-dimensionally confined diblock copolymer films10.1021/la010448t ↗
15. Responsive Microgels at Surfaces and Interfaces10.1515/zpch-2014-0568 ↗
16. GISAXS and GISANS as metrology technique for understanding the 3D morphology of block copolymer thin films10.1016/j.eurpolymj.2016.04.007 ↗
17. Relationship between structure and fluctuations of lipid nonlamellar phases deposited at the solid-liquid interface10.1021/acs.jpcb.6b11038 ↗
18. Lipfert, F., Frielinghaus, H., Holderer, O., Mattauch, S., Monkenbusch, M., Arend, N., and Richter, D. (2014). Polymer enrichment decelerates surfactant membranes near interfaces. Phys. Rev. E, 89.10.1103/PhysRevE.89.042303 ↗
19. Frielinghaus, H., Kerscher, M., Holderer, O., Monkenbusch, M., and Richter, D. (2012). Acceleration of membrane dynamics adjacent to a wall. Phys. Rev. E, 85.10.1103/PhysRevE.85.041408 ↗
20. Bulk phase and surface dynamics of PEG microgel particles10.1021/acs.macromol.5b00788 ↗
21. Accurate background correction in neutron reflectometry studies of soft condensed matter films in contact with fluid reservoirs10.1107/S160057671901481X ↗
22. Optimization of reflectometry experiments using information theory10.1107/S1600576718017016 ↗
23. IsGISAXS: A program for grazing-incidence small-angle X-ray scattering analysis of supported islands10.1107/S0021889802006088 ↗
24. Kyrey, T., Ganeva, M., Witte, J., von Klitzing, R., Wellert, S., and Holderer, O. (2021). Understanding near-surface polymer dynamics by a combination of grazing-incidence neutron scattering and virtual experiments. J. Appl. Crystallogr., 54.10.1107/S1600576720014739 ↗
25. BornAgain: Software for simulating and fitting grazing-incidence small-angle scattering10.1107/S1600576719016789 ↗
26. Kyrey, T. (2019). Internal Structure and Dynamics of PNIPAM Based Microgels in Bulk and Adsorbed State at Different Internal Crosslinker Distributions. [Ph.D. Thesis, Technische Universität].
27. Grazing incidence small-angle neutron scattering: Challenges and possibilities10.1038/pj.2012.190 ↗
28. Korolkov, D. (2008). Structural Analysis of Diblock Copolymer Nanotemplates Using Grazing Incidence Scattering, Forschungszentrum Jülich.
29. Ares, A.E. (2017). Grazing incidence Small Angle X-ray Scattering as a Tool for In-Situ Time-Resolved Studies. X-ray Scattering, INTECH. Chapter 2.
30. Dewetting of thin polymer blend films: Examined with GISAS10.1016/S0921-4526(99)01891-8 ↗
31. Neutron grazing incidence techniques for nano-science
32. Anomalous surface reflection of X rays10.1103/PhysRev.131.2010 ↗
33. Schwartzkopf, M., and Roth, S.V. (2016). Investigating polymer-metal interfaces by grazing incidence small-angle X-ray scattering from gradients to real-time studies. Nanomaterials, 6.10.3390/nano6120239 ↗
34. On the nature of the evanescent wave10.1366/12-06707 ↗
35. Polymer thin films and interfaces characterized with evanescent light10.1002/macp.1991.021921201 ↗
36. Dosch, H. (1992). Critical Phenomena at Surfaces and Interfaces, Springer Tracts in Modern Physics.10.1007/BFb0045209 ↗
37. KWS–1 high–resolution small–angle neutron scattering instrument at JCNS: Current state10.1107/S1600576714025977 ↗
38. Zentrum, H.M.L. (2015). KWS-1: Small–angle scattering diffractometer. J. Large-Scale Res. Facil., 1.10.17815/jlsrf-1-26 ↗
39. KWS-2: Small angle scattering diffractometer10.17815/jlsrf-1-27 ↗
40. Radulescu, A., Pipich, V., Frielinghaus, H., and Appavou, M.-S. (2012). KWS-2, the high intensity/wide Q-range small-angle neutron diffractometer for soft-matter and biology at FRM II. J. Phys. Conf. Ser., 351.10.1088/1742-6596/351/1/012026 ↗
41. Nanobubbles and their precursor layer at the interface of water against a hydrophobic substrate10.1021/la026731p ↗
42. Small–angle neutron scattering on polymer gels: Phase behavior, inhomogeneities and deformation mechanisms10.1038/pj.2010.110 ↗
43. In situ dynamic light scattering complementing neutron spin echo measurements on protein samples10.1134/S1027451020070046 ↗