journal article·2017-09-15Open access

Pt-Based Nanostructures for Observing Genuine SERS Spectra of p-Aminothiophenol (PATP) Molecules

Yinong Wang, Haofei Zhao, En Cao, Yinghui Sun, Huanyu Ye, Weihua Lin, Rongming Wang

Applied Sciences· Volume 7· Issue 9

Abstract

By one-pot wet chemical method, Pt-based hollow nanostructures were synthesized at room temperature. Because of the highly damping optical response of the metal, these Pt-based hollow nanostructures exhibited weak thermal effects with a laser focal spot on 4-aminothiophenol (PATP) molecules limiting dimerisation. The isolated surface enhanced Raman scattering (SERS) spectra of PATP, in which the vibrational bands from 4,4′-dimercaptoazobenzene (DMAB) molecules are not observed, were able to be seen, and this was in good agreement with the Raman spectra of PATP powder. In addition, the concentration of PATP molecules was varied, and the illumination time was increased to 2000 s, respectively. It was found that spectra were stable with varied PATP concentrations, and the plasmon-driven chemical conversion of PATP to DMAB was still suppressed, even when the laser illumination time was increased to 2000 s.
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Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Quantum Dots Synthesis And Properties · Nanocluster Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physics, Beihang University, Beijing 100191, China

Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface Science, School of Mathematics and Physics, University of Science and Technology Beijing, Beijing 100083, China

Funding

the National Natural Science Foundation of Chin · Beijing Municipal Science and Technology Project

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