journal article·2025-11-12Open access

Enhancing the Performance of Polypropylene/High-Density Polyethylene Blends by the Use of a Compatibilizer and Montmorillonite Nanoparticles

Georgios Moraitis, Petroula A. Tarantili

Applied Sciences· Volume 15· Issue 22

Abstract

Nanocomposites composed of compatibilized polyolefin blends and organically modified montmorillonite (OMMT) nanoparticles were produced through melt mixing using a twin-screw extruder. High-density polyethylene (HDPE) and polypropylene (PP) blends were compatibilized with maleic anhydride-grafted PE compatibilizer (COMP). Blends with a 10/25 (w/w) HDPE/PP content were prepared and were reinforced with 1, 2, and 3 phr OMMT. Characterization of nanocomposites was performed using X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), Tensile Testing, and Melt Flow Index (MFI) measurements. Preparation of polyolefin blend/OMMT nanocomposites with a twin-screw extruder was successful at low clay levels (1 phr). These nanocomposites presented increased onset temperature of thermal degradation, crystallinity, and stiffness, whereas their MFI values were lower than those of the pure matrix.
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Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Polymer crystallization and properties · Natural Fiber Reinforced Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory of Polymer Technology, School of Chemical Engineering, National Technical University of Athens, Zographou, 15780 Athens, Greece

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