journal article·2025-10-24Open access

Electrodynamics of Carbon Nanotubes with Non-Local Surface Conductivity

Tomer Berghaus, Touvia Miloh, Oded Gottlieb, Gregory Ya. Slepyan

Applied Sciences· Volume 15· Issue 21

Abstract

A new framework that can be utilized for the electrodynamics of carbon nanotubes (CNTs) with non-local surface conductivity (spatial dispersion) is presented. The model of non-local conductivity is developed on the basis of the Kubo technique applied to the Dirac equation for pseudospins. As a result, the effective boundary conditions for the electromagnetic (EM) field on a CNT surface are formulated. The dispersion relation for the eigenmodes of an infinitely long CNT is obtained and analyzed. It is shown that due to nonlocality, a new type of eigenmode is created that disappears in the local conductivity limit. These eigenmodes should be properly accounted for in the correct formulation of the CNT end conditions for the surface current, which are manifested in the EM-field scattering problem. Additional boundary conditions that consider nonlocality effects are also formulated based on the exact solution obtained for the surface current by means of using the Wiener–Hopf (WH) technique for a semi-infinite CNT. The scattering pattern of the EM-field is simulated by a finite-length model of a CNT, using a numerically solved integral equation for the surface current density and its approximate analytical solution. Thus, the scattering field of a CNT, prevailing in a wide frequency range from THz to infrared light, is analytically solved and analyzed. Potential applications for the design of nanoantennas and other electronic devices, including pointing out some future directions, are also discussed.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Crystallography and Radiation Phenomena · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Mechanical Engineering, Tel Aviv University, Tel Aviv 69978, Israel

Faculty of Mechanical Engineering, Technion—Israel Institute of Technology, Haifa 32000, Israel

School of Electrical Engineering, Tel Aviv University, Tel Aviv 69978, Israel

Funding

BSF

References (83)

Show source-provided references
1. Quantum transport in carbon nanotubes10.1103/RevModPhys.87.703 ↗
2. Baydin, A., Tay, F., Fan, J., Manjappa, M., Gao, W., and Kono, J. (2022). Carbon Nanotube Devices for Quantum Technology. Materials, 15.10.3390/ma15041535 ↗
3. Mechanisms and applications of carbon nanotubes in terahertz devices: A review10.1016/j.carbon.2018.02.005 ↗
4. Terahertz science and technology of carbon nanomaterials10.1088/0957-4484/25/32/322001 ↗
5. Carbon-nanotube photonics and optoelectronics10.1038/nphoton.2008.94 ↗
6. Proposal for a Nanomechanical Qubit
7. Steady-state Peierls transition in nanotube quantum simulator10.1038/s41534-022-00675-4 ↗
8. Near-Infrared Fluorescent Single-Walled Carbon Nanotubes for Biosensing10.1002/smll.202502542 ↗
9. A Review on the Properties and Application of Carbon Nanotubes as Biological Nanomotors: Advantages and Challenges10.1007/s13369-024-09288-9 ↗
10. Terahertz conductivity peak in composite materials containing carbon nanotubes: Theory and interpretation of experiment10.1103/PhysRevB.81.205423 ↗
11. Experimental evidence of localized plasmon resonance in composite materials containing single-wall carbon nanotubes10.1103/PhysRevB.85.165435 ↗
12. Collective antenna effects in the terahertz and infrared response of highly aligned carbon nanotube arrays10.1103/PhysRevB.87.161401 ↗
13. Signal propagation in carbon nanotubes of arbitrary chirality10.1109/TNANO.2009.2034262 ↗
14. A transmission line model for metallic carbon nanotube interconnects10.1002/cta.396 ↗
15. Terahertz sensing with carbon nanotube layers coated on silica fibers: Carrier transport versus nanoantenna effects10.1063/1.3478009 ↗
16. Theory of optical scattering by achiral carbon nanotubes and their potential as optical nanoantennas10.1103/PhysRevB.73.195416 ↗
17. Fundamental Transmitting Properties of Carbon Nanotube Antennas10.1109/TAP.2005.858865 ↗
18. Infrared and Optical Properties of Carbon Nanotube Dipole Antennas10.1109/TNANO.2006.883475 ↗
19. A carbon nanotube optical rectenna10.1038/nnano.2015.220 ↗
20. Electronic transport in bent carbon nanotubes10.1103/PhysRevB.107.195424 ↗
21. Hybrid Quantum Device with Nitrogen-Vacancy Centers in Diamond Coupled to Carbon Nanotubes10.1103/PhysRevLett.117.015502 ↗
22. A review of the interfacial characteristics of polymer nanocomposites containing carbon nanotubes10.1039/C8RA04205E ↗
23. Conducting linear chains of sulphur inside carbon nanotubes10.1038/ncomms3162 ↗
24. Agranovich, V.M., and Ginzburg, V.L. (1984). Crystal Optics with Spatial Dispersion and Excitons, Springer.10.1007/978-3-662-02406-5 ↗
25. Landau, L.D., Pitaevskii, L.P., and Lifshitz, E.M. (1984). Electrodynamics of Continuous Media (Course of Theoretical Physics), Pergamon Press.10.1016/B978-0-08-030275-1.50007-2 ↗
26. Akhiezer, I.A., Polovin, R.V., Sitenko, A.G., and Stepanov, K.N. (2017). Plasma Electrodynamics: Linear Theory, Elsevier.
27. Simovski, C. (2018). Composite Media with Weak Spatial Dispersion, Jenny Stanford Publishing. [1st ed.].10.1201/9781351166249 ↗
28. 3D metamaterials10.1038/s42254-018-0018-y ↗
29. Nonlocal flat optics10.1038/s41566-022-01098-5 ↗
30. Mesoscopic electrodynamics at metal surfaces, from quantum-corrected hydrodynamics to microscopic surface-response formalism10.1515/nanoph-2021-0156 ↗
31. Near-zero refractive index photonics10.1038/nphoton.2017.13 ↗
32. Spatial dispersion in negative-index composite metamaterials10.1103/PhysRevA.77.013807 ↗
33. Causality, Nonlocality, and Negative Refraction10.1103/PhysRevLett.118.134301 ↗
34. Topological photonics10.1103/RevModPhys.91.015006 ↗
35. Topological nanophotonics10.1515/nanoph-2019-0197 ↗
36. Optical conductivity of graphene in the visible region of the spectrum10.1103/PhysRevB.78.085432 ↗
37. Dyadic Green’s functions and guided surface waves for a surface conductivity model of graphene10.1063/1.2891452 ↗
38. Optical far-infrared properties of a graphene monolayer and multilayer10.1103/PhysRevB.76.153410 ↗
39. Dynamical polarizability of graphene with spatial dispersion10.1103/PhysRevB.103.125421 ↗
40. Semiclassical spatially dispersive intraband conductivity tensor and quantum capacitance of graphene10.1103/PhysRevB.87.115429 ↗
41. Drift-Diffusion: A Model for Teaching Spatial-Dispersion Concepts and the Importance of Screening in Nanoscale Structures10.1109/MAP.2010.5687538 ↗
42. Additional boundary conditions: An historical mistake10.1103/PhysRevLett.80.2889 ↗
43. Comment on additional boundary conditions: An historical mistake10.1103/PhysRevLett.83.1263 ↗
44. Comment on additional boundary conditions: An historical mistake10.1103/PhysRevLett.83.1264 ↗
45. Additional boundary conditions—Critical comparison between theory and experiment10.1103/PhysRevLett.48.1500 ↗
46. Katsnelson, M.I., and Novoselov, K.S. (2007). Graphene: New bridge between condensed matter physics and quantum electrodynamics. arXiv.10.1016/j.ssc.2007.02.043 ↗
47. Bordag, M., Khusnutdinov, N., Klimchitskaya, G.L., and Mostepanenko, V.M. (2025). Comment on “Electric conductivity of graphene: Kubo model versus a nonlocal quantum field theory model”. arXiv.
48. Electric conductivity in graphene: Kubo model versus a nonlocal quantum field theory model10.1103/PhysRevB.111.115428 ↗
49. Landau, L.D., and Lifshitz, E.M. (1980). Statistical Physics (Course of Theoretical Physics), Pergamon Press. [3rd ed.]. Part 1, Volume 5.10.1016/B978-0-08-023039-9.50007-X ↗
50. Statistical-mechanical theory of irreversible processes. I. general theory and simple applications to magnetic and conduction problems10.1143/JPSJ.12.570 ↗
51. Noble, B. (1958). Methods Based on the Wiener—Hopf Technique for the Solution of Partial Differential Equations, Pergamon.
52. Weinstein, L.A. (1969). The Theory of Diffraction and the Factorization Method, Golem.
53. Ilyinsky, A.S., Slepyan, G.Y., and Slepyan, A.Y. (1993). Propagation, Scattering and Dissipation of Electromagnetic Waves, Peter Peregrinus Ltd.10.1049/PBEW036E ↗
54. Scattering of Electromagnetic Waves by a Semi-Infinite Carbon Nanotube10.1078/1434-8411-00041 ↗
55. Theory of plasmonic edge states in chiral bilayer systems10.1103/PhysRevB.104.115422 ↗
56. Electrodynamics of carbon nanotubes: Dynamic conductivity, impedance boundary conditions, and surface wave propagation10.1103/PhysRevB.60.17136 ↗
57. Balanis, C.A. (1997). Antenna Theory-Analysis and Design, Wiley. [3rd ed.].
58. Hanson, G.W., and Yakovlev, A.B. (2001). Operator Theory for Electromagnetics, Springer. [1st ed.].10.1007/978-1-4757-3679-3 ↗
59. Ishimaru, A. (1991). Radiation and Electromagnetic Wave Propagation Scattering, Prentice-Hall, Englewood Cliffs.
60. Theoretical investigation into the transmitting and receiving quality of antennae
61. Levin, B. (2021). Antennas Rigorous Methods of Analysis and Synthesis, CRC Press. [1st ed.].10.1201/9781003043546 ↗
62. Leontovich’s researches in electrodynamics: For M. A. Leontovich’s 80th birthday10.1070/PU1983v026n04ABEH004389 ↗
63. A new formulation of Pocklington’s equation for thin wires using the exact kernel10.1109/TAP.2011.2164211 ↗
64. On the oscillations appearing in numerical solutions of solvable and nonsolvable integral equations for thin-wire antennas10.1109/TAP.2010.2044319 ↗
65. Absorption, cross-section and near-field enhancement in finite-length carbon nanotubes in the terahertz-to-optical range10.1166/jctn.2009.1258 ↗
66. Integral equation technique for scatterers with mesoscopic insertions: Application to a carbon nanotube10.1103/PhysRevB.96.205414 ↗
67. Theory of multiwall carbon nanotubes as waveguides and antennas in the infrared and the visible regimes10.1103/PhysRevB.79.155403 ↗
68. Thermal radiation from carbon nanotubes in the terahertz range10.1103/PhysRevLett.99.147403 ↗
69. Maksimenko, S.A., Shuba, M.V., Kuzhir, P.P., Batrakov, K.G., and Slepyan, G.Y. (2015, January 8–10). Challenges and Perspectives of Nanoelectromag-netics in the THz range. Proceedings of the IEEE Computer Society Annual Symposium, Montpellier, France.10.1109/ISVLSI.2015.20 ↗
70. Scattering of electromagnetic waves by two crossing metallic single-walled carbon nanotubes of finite length10.1103/PhysRevB.103.075438 ↗
71. Spontaneous decay of the excited state of an emitter near a finite-length metallic carbon nanotube10.1103/PhysRevB.82.235411 ↗
72. Optical scattering from a planar array of finite-length metallic carbon nanotubes10.1103/PhysRevB.75.165416 ↗
73. Katsnelson, M.I. (2020). Graphene: Carbon in Two Dimensions, Cambridge University Press. [2nd ed.].
74. Landau, L.D., and Lifshitz, E.M. (1980). Physical Kinetics (Course of Theoretical Physics), Pergamon Press. [3rd ed.].
75. Korn, G.A., and Korn, T.M. (2000). Mathematical Handbook for Scientists and Engineers: Definitions, Theorems, and Formulas for Reference and Review, Courier Corporation.
76. The behavior of electromagnetic fields at edges10.1109/TAP.1972.1140243 ↗
77. Jackson, J.D. (1999). Classical Electrodynamics, John Wiley & Sons. [3rd ed.].
78. Felsen, L.B., and Marcuvitz, N. (1972). Radiation and Scattering of Waves, Prentice-Hall.
79. Omoriyekomwan, J.E., Tahmasebi, A., Zhang, J., and Yu, J. (2022). Synthesis of super-long carbon nanotubes from cellulosic biomass under microwave radiation. Nanomaterials, 12.10.3390/nano12050737 ↗
80. Gao, Z., Oudjedi, L., Faes, R., Moroté, F., Jaillet, C., Poulin, P., Lounis, B., and Cognet, L. (2015). Optical detection of individual ultra-short carbon nanotubes enables their length characterization down to 10 nm. Sci. Rep., 5.10.1038/srep17093 ↗
81. Joule heating in nanowires10.1103/PhysRevB.84.054437 ↗
82. Gradient-induced long-range optical pulling force based on photonic band gap10.1038/s41377-024-01452-y ↗
83. Many-body electrohydrodynamic contactdynamics in alternating-current dielectrophoresis: Resolving hierarchical assembly of soft binarycolloids10.1063/5.0281415 ↗