journal article·2025-09-27Open access

Block Copolymer-Templated Synthesis of Fe–Ni–Co-Modified Nanoporous Alumina Films

Chinemerem Ozoude, Vasanta Gurung, Khalil D. Omotosho, Elena V. Shevchenko, Diana Berman

Applied Sciences· Volume 15· Issue 19

Abstract

Despite intense interest in the catalytic potential of transition metal oxide heterostructures, originating from their large surface area and tunable chemistry, the fabrication of well-defined multicomponent oxide coatings with controlled architectures remains challenging. Here, we demonstrate a simple and effective swelling-assisted sequential infiltration synthesis (SIS) strategy to fabricate hierarchically porous multicomponent metal-oxide electrocatalysts with tunable bimetallic composition. A combination of solution-based infiltration (SBI) of transition metals, iron (Fe), nickel (Ni), and cobalt (Co), into a block copolymer (PS73-b-P4VP28) template, followed by vapor-phase infiltration of alumina using sequential infiltration synthesis (SIS), was employed to synthesize porous, robust, conformal and transparent multicomponent metal-oxide coatings like Fe/AlOx, Fe+Ni/AlOx, and Fe+Co/AlOx. Electrochemical assessments for the oxygen evolution reaction (OER) in a 0.1 M KOH electrolyte demonstrated that the Fe+Ni/AlOx composite exhibited markedly superior catalytic activity, achieving an impressive onset potential of 1.41 V and a peak current density of 3.29 mA/cm2. This superior activity reflects the well-known synergistic effect of alloying transition metals with a trace of Fe, which facilitates OER kinetics. Overall, our approach offers a versatile and scalable path towards the design of stable and efficient catalysts with tunable nanostructures, opening new possibilities for a wide range of electrochemical energy applications.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Semiconductor materials and devices · Aluminum Alloys Composites Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials Science and Engineering Department, University of North Texas, 1155 Union Circle, Denton, TX 76203, USA

Center for Nanoscale Materials, Argonne National Laboratory, Argonne, IL 60439, USA

Department of Chemistry, James Franck Institute, University of Chicago, Chicago, IL 60637, USA

Funding

National Science Foundation · U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences

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