The Characterization of Commercial and Historical Textiles Using a Combination of Micro-Chemical, Microscopic and Infrared Spectroscopic Methods
Source abstract
Abstract
The aim of this study is to identify the textile materials used to make Bulgarian folk costumes and to support the process of conservation and restoration of ethnographic objects. In the 18th and 19th centuries, folk costumes were made almost exclusively of natural materials, while in the first half and middle of the 20th century, they included contemporary synthetic and regenerated cellulose materials, as well as blends of these materials with natural fibers. A series of historical textiles and contemporary industrial fabrics were studied using a variety of analytical approaches, including micro-chemical staining and solubility tests, optical microscopy, scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS), and infrared (IR) spectroscopy. IR measurements were carried out in attenuated total reflectance (ATR) and external reflectance (ER) modes using a portable IR spectrometer, which enabled non-invasive analysis. The analysis revealed that the composition of the industrial fabrics and historical textiles encompassed synthetic fibers, such as polyester and polyamide, while others were made of regenerated cellulose fibers like viscose. Additionally, some textiles had a mixed composition of cotton and polyester or silk and viscose. The combined analytical approach provided reliable identification of both the synthetic and natural textile materials.
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Research context
OpenAlex topics: Cultural Heritage Materials Analysis · Building materials and conservation · Conservation Techniques and Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Build. 9, 1113 Sofia, Bulgaria
Department of Organic Chemistry, University of Chemical Technology and Metallurgy, 8 Kliment Ohridski Blvd., 1756 Sofia, Bulgaria
National Academy of Art, Faculty of Applied Arts and Design, 1113 Sofia, Bulgaria
Institute of Physical Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 11, 1113 Sofia, Bulgaria
Institute of Ethnology and Folklore Studies with Ethnographic Museum, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 6, 1113 Sofia, Bulgaria
Funding
European Union—NextGenerationEU—through the National Recovery and Resilience Plan of the Republic of Bulgaria
References (46)
Show source-provided references
1. Digital Color Images as a Tool for the Sustainable Use of Embroidery Elements from Folk Costumes10.3390/heritage6080303 ↗
2. Veleva, M.G., and Blagoeva, S.D. (1983). Bulgarian National Costumes and Folk Jewellery, Septemvri.
3. Bulgarian Folk Costumes, Symbols and Traditions
4. Komitska, A., and Borisova, V. (2000). Bulgarian Folk Costumes, Borika.
5. Nikolov, K. (1981). Women’s Bulgarian National Costumes, Septemvri.
6. (2025, August 25). Available online: https://www.omda.bg/public/engl/ethnography/female_costumes_en.htm.
7. Max, M. (2009). The role of fibre identification in textile conservation. Identification of Textile Fibers, Houck Woodhead Publishing.
8. Fiber identification in ethnological textile artefacts10.1179/sic.1981.26.3.119 ↗
9. Toncheva, V. (2012). The Unknown Gora (Original Title: (Nepoznatata Gora), IIK Pod.
10. (2025, August 25). Textile Coach, Identification of Textile Fibers. Available online: https://www.textilecoach.net/post/identification-of-textile-fibers.
11. A Review Paper on Textile Fiber Identification10.9790/019X-04021420 ↗
12. Committee on Paper Testing (1924). Paper Testing Methods, Technical Association of the Pulp and Paper Industry. [2nd ed.].
13. Mokrys, M., and Badura, S. (2016, January 6–10). A procedure for identifying cellulose fibers in paper artifacts. Proceedings of the 4th International Virtual Conference on Advanced Scientific Results (SCIECONF-2016), Zilina, Slovakia.10.18638/scieconf.2016.4.1.335 ↗
14. Implementation of methods for examination of paper-based library materials
15. Graff, H. (1940). Color Atlas for Fiber Identification, The Institute of Paper Chemistry.
16. Applications of the Ninhydrin Reaction for Analysis of Amino Acids, Peptides, and Proteins to Agricultural and Biomedical Sciences10.1021/jf030490p ↗
17. Advantages and Limitations of the Ninhydrin Test for Analysis of Historic Wool Fibers10.1557/PROC-352-233 ↗
18. Polarised light microscopy in conservation: A personal perspective10.1179/019713694806124757 ↗
19. Biodegradation and characterisation of water-degraded archaeological textiles created for conservation research10.1016/S0964-8305(96)00023-6 ↗
20. Perry, R. (1985). Identification of Textile Materials, The Textile Institute. [7th ed.].
21. The application of microscopy to textile history10.1179/004049685793701061 ↗
22. Identifying plant fibres in cultural heritage with optical and electron microscopy: How to present results and avoid pitfalls10.1186/s40494-023-01122-z ↗
23. Markova, I. (2019). Textile Fiber Microscopy—A Practical Approach, John Wiley & Sons Ltd.10.1002/9781119320029 ↗
24. Evaluation of Microscopy Techniques and ATR-FTIR Spectroscopy on Textile Fibers from the Vesuvian Area: A Pilot Study on Degradation Processes That Prevent the Characterization of Bast Fibers
25. A Combination of Techniques to Study Chinese Traditional Lajian Paper10.1016/j.culher.2019.01.008 ↗
26. A Procedure for Identifying Textile Bast Fibres Using Microscopy: Flax, Nettle/Ramie, Hemp and Jute10.1016/j.ultramic.2010.04.014 ↗
27. The Intimate Soul of the Pyres: New Archaeological Data from the Terre di Rogo (Pyre Debris) of Pre-Roman Necropolis in Padua (Northern Italy)10.3390/heritage6020047 ↗
28. Changes in the production materials of Burmese textiles in the nineteenth century—Dyes, mordants and fibres of Karen garments from the British Museum’s collection10.1186/s40494-023-00978-5 ↗
29. The application of FTIR microspectroscopy in a non-invasive and non-destructive way to the study and conservation of mineralised excavated textiles10.1186/s40494-019-0304-8 ↗
30. Reflectance FT-IR spectroscopy as a viable option for textile fiber identification10.1186/s40494-019-0337-z ↗
31. Investigations of the historic textiles excavated from Ancient Ainos (Enez—Turkey) by multiple analytical techniques10.1016/j.molstruc.2014.03.068 ↗
32. Differentiating between Natural and Modified Cellulosic Fibres Using ATR-FTIR Spectroscopy10.3390/heritage5040213 ↗
33. FTIR Spectroscopy of Biodegraded Historical Textiles10.1016/j.polymdegradstab.2010.12.016 ↗
34. Duguleană, M., Carrozzino, M., Gams, M., and Tanea, I. (2018, January 29–30). Application of Fourier-Transform Infrared Spectroscopy (FTIR) for the Study of Cultural Heritage Artifacts. Proceedings of the VR Technologies in Cultural Heritage, VRTCH 2018, Brasov, Romania. Communications in Computer and Information Science.10.1007/978-3-030-05819-7 ↗
35. Dyes and biological sources in nineteenth to twentieth century ethnographic textiles from Transylvania, Romania10.1186/s40494-019-0255-0 ↗
36. Imaging Diagnostics Coupled with Non-Invasive and Micro-Invasive Analyses for the Restoration of Ethnographic Artifacts from French Polynesia10.3390/heritage5010012 ↗
37. Kim, H.J., Liu, Y., and Zeng, L. (2024). Fourier Transform Infrared (FT-IR) Spectroscopy and Simple Algorithm Analysis for Rapid and Non-Destructive Assessment of Cotton Fiber Maturity and Crystallinity for Plant Mapping. Sensors, 24.10.3390/s24092888 ↗
38. Surface modification of polyester fabric by non-thermal plasma treatment and its effect on coloration using natural dye
39. Caban, R., and Gnatowski, A. (2023). Structural and Thermal Examinations of Polyamide Modified with Fly Ash from Biomass Combustion. Materials, 16.10.3390/ma16155277 ↗
40. Identification and classification of textile fibres using ATR-FT-IR spectroscopy with chemometric methods10.1016/j.saa.2016.09.007 ↗
41. Non-invasive identification of historical textiles and leather by means of external reflection FTIR spectroscopy10.1016/j.saa.2024.125184 ↗
42. Non-invasive FTIR study of mortar model samples: Comparison among innovative and traditional techniques10.1140/epjp/i2019-12667-1 ↗
43. External reflectance FTIR dataset (4000–400 cm−1) for the identification of relevant mineralogical phases forming Cultural Heritage materials10.1016/j.infrared.2020.103266 ↗
44. Non-invasive identification of red and yellow oxide and sulfide pigments in wall-paintings with portable ER-FTIR spectroscopy10.1016/j.culher.2023.07.019 ↗
45. Non-invasive identification of paint binders in illuminated manuscripts by ER-FTIR spectroscopy: A systematic study of the influence of different pigments on the binders’ characteristic spectral features10.1186/s40494-019-0249-y ↗
46. In-situ non-invasive analysis of conservation materials on mural paintings: A systematic approach in Dahuting Han Dynasty Tomb10.1186/s40494-024-01165-w ↗