journal article·2025-07-25Open access

Experimental Testing of the Efficiency, Stability, and Compatibility of Fillers in the Conservation and Restoration of Water-Gilded Wooden Heritage

María-Ángeles Carabal-Montagud, Laura Osete-Cortina, Ángel Vicente-Escuder, Celia Laguarda-Gómez

Applied Sciences· Volume 15· Issue 15

Abstract

The conservation and restoration of water-gilded wooden cultural heritage, such as polychrome sculptures, frames, panels, altarpieces, etc., requires the use of fillers that guarantee structural stability, physicochemical and mechanical compatibility with the original support, and the ability to adapt to dimensional movements induced by thermo-hygrometric variations. This study, conducted as part of the DorART Project, analyzed the behavior of nine formulations, both commercial and non-commercial, selected through a review of the state-of-the-art specialized literature, along with the use of participatory science, which focused on the practices and materials most commonly used by professionals in the field. The experimental design was based on three types of specimens: two with wooden supports, selected for evaluating their interaction with the original material and with the traditional water gilding technique, and a third type for analyzing the individual behavior of the tested materials. Analyses of adhesion, tensile strength, Shore C hardness, gloss, abrasion test results, wettability, pH changes, and chemical composition were performed using ATR-FTIR spectroscopy. The results showed significant differences depending on the type of curing used and the composition and aging behavior of the specimen. Some of the fillers demonstrated improved compatibility with water-based gilding, facilitating workability and providing structural strength. M3 and M9 demonstrated an optimal balance of workability and aging stability. The results of this study can help restorers select materials based on their specific needs, considering the requirements of mechanical adaptation to the substrate, compatibility, and durability.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departmento de Conservación y Restauración de Bienes Culturales, Facultad Bellas Artes, Universitat Politècnica de València, 46022 Valencia, Spain

Instituto Universitario de Restauración del Patrimonio, Universitat Politècnica de València, 46022 Valencia, Spain

Instituto Universitario de Investigación de Tecnología de los Materiales, Universitat Politècnica de València, 46022 Valencia, Spain

Funding

Universitat Politècnica de València (UPV)

References (51)

Show source-provided references
1. Unger, A., Schniewind, A.P., and Unger, W. (2001). Conservation of Wood Artifacts. A Handbook, Springer. [1st ed.]. Available online: https://link.springer.com/book/10.1007/978-3-662-06398-9.10.1007/978-3-662-06398-9 ↗
2. Properties of wood in the conservation of historical wooden artifacts10.1016/j.culher.2012.03.014 ↗
3. Wood in cultural heritage. Properties and conservation of historical wooden artefacts
4. Fuster-López, L., Mecklenburg, M.F., Castell-Agusti, M., and Guerola-Blay, V. Idoneidad estructural de las masillas de relleno empleadas en pintura sobre lienzo. ¿Qué estamos buscando?. Preprints of the Papers to the Valencia Congress, 2, 3 and 4 November 2006, Proceedings of the 16th International Meeting on Heritage Conservation, Valencia, Spain, 2–4 November 2006, Available online: https://hdl.handle.net/10088/36009.
5. Evaluation of some pastes used for gap filling of archaeological bones10.1016/j.measurement.2018.06.061 ↗
6. Experimental study of gap-filling of ancient completely corroded copper bowl via nanopolymers
7. Pastas de relleno para reintegración volumétrica de esculturas en cera. Primeros resultados experimentales10.37558/gec.v6i0.236 ↗
8. A study of gap-fillers for wooden objects10.1179/sic.1988.33.2.71 ↗
9. Commercial Vinyl and Acrylic Fill Materials10.1179/019713698806082967 ↗
10. An evaluation of four barrier-coating and epoxy combinations in the structural repair of wooden objects10.1179/019713604806112605 ↗
11. Williams, D.C. (2009, January 17–18). Some experiences with flexible gap-filling adhesives for the conservation of wood objects. Proceedings of the Facing the Challenges of Panel Paintings Conservation: Trends, Treatments, and Training, Los Angeles, CA, USA. Available online: https://s3.amazonaws.com/theBarn/Articles/Conservation/Williams,Don-Gap_Filling_Adhesives.pdf.
12. An investigation of the use of cellulose-based materials to gap-fill wooden objects10.1080/00393630.2015.1109294 ↗
13. Dimensional stability and moisture properties of gap-fillers based on wood powder and glass microballoons10.1080/00393630.2019.1630567 ↗
14. Expanded vermiculite and polyvinyl acetate composite as gap filler for wooden objects conservation10.1016/j.culher.2022.02.012 ↗
15. Chen, T., Ma, Q., Li, Y., and Li, G. (2023). Preparation and characterization of wood composites for wood restoration. Forests, 14.10.3390/f14091743 ↗
16. Conservation and restoration of gilded antiques10.1080/01400096.1979.9635669 ↗
17. The use of wax for appliqué relief brocade on wooden statuary10.1179/sic.1963.021 ↗
18. Note on a fill material for water sensitive objects10.1179/019713686806027989 ↗
19. Wilson, D.M. (1998). Further uses for Paraloid B-72: Infilling systems for gild-ed, painted and lacquered wood. WAG-AIC Postprints, American Institute for Conservation of Historic and Artistic Works. Available online: https://www.wag-aic.org/1998/WAG_98_wilson.pdf.
20. Salimnejad, B. (2005). Formulating gesso fills with bismuth oxide for discrimination by X-radiography. Wooden Artifacts Group Postprints 2005, American Institute for Conservation.
21. Thornton, J. (1991). The Use of Nontraditional Gilding Methods and Materials in Conservation. Gilded Wood: Conservation and History, Sound View Press.
22. Pierce, E. (2015). As Good as Gold: Alternative Fill Materials for Gilding Conservation. [Dissertation for the Degree of MSc in Conservation of Archaeology and Museums, University College London]. Available online: https://static1.squarespace.com/static/58bed88ce4fcb552bc247201/t/5fbec43364571256541de87b/1606337600046/As_Good_As_Gold_Dissertation_PDF.pdf.
23. Non-traditional gilding revisited: Evaluation of gilded surfaces exposed to uncontrolled diurnal fluctuations for over 10 years10.1080/10344233.2017.1342889 ↗
24. Sui, D.Z., Elwood, S., and Goodchild, M.F. (2013). Citizen Science and Volunteered Geographic Information—Overview and typology of participation. Crowdsourcing Geographic Knowledge: Volunteered Geographic Information (VGI) in Theory and Practice, Springer.10.1007/978-94-007-4587-2 ↗
25. Survey on Material Used to Fill Wooden Objects During Conservation10.5334/joad.ad ↗
26. Willis, G.B. (2005). Cognitive Interviewing: A Tool for Improving Questionnaire Design, Sage Publications, Inc.. [3rd ed.].
27. Tashakkori, A., and Teddlie, C. (2009). Integrating Qualitative and Quantitative Approaches to Research. The SAGE Handbook of Applied Social Research Methods, SAGE. [2nd ed.].10.4135/9781483348858.n9 ↗
28. Determining Validity in Quantitative Inquiry10.1207/s15430421tip3903_2 ↗
29. Regulation (EU) 2016/679 of the European Parliament and of the Council
30. BOE (2018). Spanish Organic Law 3/2018 of 5 December on the Protection of Personal Data and Guarantee of Digital Rights, Official State Gazette (BOE).
31. Lacueva Gil, S. (2023). Participatory Citizen Science as a Tool to Activate the Collective Generation of Knowledge in Conservation and Restoration of Cultural Assets. State of the Art, Current International Catalog and Analysis of Its Implementation in a Research Project in the Field of Gilding and Polychromy. [Master Thesis, Department of Conservation and Restoration of Cultural Heritage, Universitat Politècnica de València]. Available online: https://riunet.upv.es/handle/10251/196955.
32. (2012). Plastics—Determination of Tensile Properties—Part 2: Test Conditions for Moulding and Extrusion Plastics (ISO 527-2:2012) (Standard No. UNE-EN ISO 527-2:2012). Adopted from EN ISO 527-2:2012, Original ISO 527-2:2012.
33. (2003). Adhesives—Guide to the Selection of Standard Laboratory Ageing Conditions for Testing Bonded Joints (Standard No. ISO 9142:2003).
34. Artioli, G. (2017). Scientific Methods and Cultural Heritage: An Introduction to the Application of Materials Science to Archaeometry and Conservation Science, Oxford University Press.
35. An investigation on machinability assessment of difficult-to-cut materials based on radar charts10.1177/0954405413497008 ↗
36. Pinzger, M., Gall, H., Fischer, M., and Lanza, M. (2005, January 14–15). Visualizing multiple evolution metrics. Proceedings of the 2005 ACM Symposium on Software Visualization, St. Louis, MO, USA.10.1145/1056018.1056027 ↗
37. (2024, December 22). Radar Chart. Available online: https://www.chartjs.org/docs/latest/charts/radar.html.
38. Harandi, D. (2021). Preparation of New Polymer Nanocomposites with Potential Use in Restorative Applications for the Consolidation of Historical Wooden Works. [Doctoral Dissertation, Universidad Carlos III].
39. Prakash, S., and Yeom, J. (2014). Nanofluidics and Microfluidics: Systems and Applications, William Andrew, Elsevier.
40. Puoti, F., Jervis, A.V., Ciabattoni, R., Cossa, E., Di Giovanni, A., Giuliani, M.R., Guida, G., and Ioele, M. (2017). Evaluation of leather cleaning with a rigid hidrogel of gellan gum on two composite Amharic shields from the Museo Nazionale Preistorico Etnografico ‘Luigi Pigorini’, Rome. Gels in the Conservation of Art, Archetype Publications.
41. Fuster López, L. (2020). Introducción a la Conservación y Restauración de Papel, Editorial de la Universidad Politécnica de Valencia. [1st ed.]. Available online: https://lectura.unebook.es/viewer/9788490488171/1.
42. (2010). Conservation of Cultural Property—Test Methods—Determination of Static Contact Angle (Standard No. UNE EN 15802:2010).
44. Getty Conservation Institute (2024, February 06). Making an Agarose Gel in a Microwave and Preparing an Agarose Plug. Available online: https://www.youtube.com/watch?v=V490KuFsU4k.
45. Hughes, A. (2017). Measurement of surface pH of paper using agarose gel plugs: A feasibility study. Gels in Conservation of Art, Archetype Publications Ltd.
46. (2003). Paints and Varnishes—Pull-Off Test for Adhesion (Standard No. ISO 4624:2003).
47. Use of shore hardness tests for in-process properties estimation/monitoring of silicone rubbers10.1016/j.msec.2015.05.013 ↗
48. (2015). Paints and Varnishes—Determination of Gloss Value at 20°, 60° and 85° (ISO 2813:2014) (Standard No. UNE-EN ISO 2813:2015). Adopted from EN ISO 2813:2014, Original ISO 2813:2014.
49. (2022). Paints and Varnishes—Determination of Resistance to Abrasion—Part 3: Method with Abrasive-Paper Covered Wheel and Linearly Reciprocating Test Specimen (Standard No. ISO 7784-3:2022).
50. Materials Science and engineering
51. Derrick, M.R., Stulik, D., and Getty Conservation Institute (1999). Infrared Spectroscopy in Conservation Science, Getty Conservation Institute.