journal article·2025-06-07Open access

Alternative HPLC-DAD Direct-Phase Approach to Measurement of Enantiopurity of Lactic Acid Derivatives

Maria Montrone, Cosimo Cardellicchio, Maria Annunziata M. Capozzi

Applied Sciences· Volume 15· Issue 12

Abstract

Lactic acid (LA) is a natural organic acid that can be used in a wide variety of industries. Recently, the production of lactic acid by fermentation protocols has gained relevance. However, these biotechnological processes often encounter challenges in the production of enantiopure D- or L-lactic acid. Thus, the measurement and control of the enantiopurity of lactic acid and its derivatives is a crucial step in these productions, especially when monomers have to be used to synthesize polymers, such as polylactic acid (PLA). In the present work, we propose a measurement of the enantiopurity of lactic acid mixtures with HPLC-DAD by using direct-phase conditions, which are mild, and a large set of different employable chiral columns. To this end, we report the synthesis of two new LA derivatives (2-nitrobenzyl 2-hydroxypropanoate and 2,4-dinitrobenzyl 2-hydroxypropanoate) and benzyl 2-hydroxypropanoate, with a selective and non-racemizing chemical functionalization. Then, three commercially available HPLC direct-phase chiral columns are tested to achieve a method for measuring the enantiomeric purity of lactic acid derivatives. The 2-nitrobenzyl lactate was chosen as the best lactic acid derivative and the Chiralpak IA column was chosen as the most effective chiral column to achieve a new and efficient protocol (Rs = 3.57 and α = 1.13) for the measurement of the enantiopurity of lactic acid.
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Research context

OpenAlex topics: Analytical Chemistry and Chromatography · biodegradable polymer synthesis and properties · Microbial Metabolic Engineering and Bioproduction

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Affiliations

Dipartimento di Chimica, Università di Bari, Via Orabona 4, 70126 Bari, Italy

CNR ICCOM, Dipartimento di Chimica, Università di Bari, Via Orabona 4, 70126 Bari, Italy

METEA Research Center, Via C. Ulpiani, 70126 Bari, Italy

Funding

MIUR–PERCIVAL

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