journal article·2025-05-05Open access

Innovative Characterisation of By-Products from Intensive Agriculture for Their Use as Reinforcement in Biocomposites and Construction Materials

Ana Cervilla-Maldonado, Ignacio Valverde-Palacios, Almudena Pérez-Rus, Raquel Fuentes-García

Applied Sciences· Volume 15· Issue 9

Abstract

The production of agricultural residues causes environmental pollution, especially in regions with intensive horticultural production. The solution is to maximise the use of residues, applying the ‘zero waste’ model and using them to develop construction materials. Natural fibres used to reinforce materials have environmental and economic benefits due to their low cost. This research presents an innovative characterisation using an inverted-plate optical microscope, a high-resolution scanning electron microscope (HRSEM) and a 3D X-ray microscope. A physico-mechanical and chemical characterisation of horticultural fibres was also conducted. The fibres analysed were those produced in the highest quantities, including those from tomatoes, peppers, zucchinis, cucumbers and aubergines. The viability of these natural fibres for use as reinforcements in biocomposites was investigated. The analysis centred on studying the microstructure, porosity, chemical composition, tensile strength, water absorption and environmental degradation of the natural fibres. The results showed a porosity ranging from 47.44% to 61.18%, which contributes to the lightness of the materials. Cucumber stems have a higher tensile strength than the other stems, with an average value of 19.83 MPa. The SEM analysis showed a similar chemical composition of the scanned fibres. Finally, the life cycle of the materials made from horticultural residue was analysed, and negative GWP (global warming potential) CO2eq values were obtained for two of the proposed materials, such as stabilised soil reinforced with agricultural fibres and insulation panels made of agricultural fibres.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Natural Fiber Reinforced Composites · Advanced Theoretical and Applied Studies in Material Sciences and Geometry · Mechanical Systems and Engineering

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Building Construction, Technical Upper School of Architecture, University of Granada, Campo del Principe, E18071 Granada, Spain

References (80)

Show source-provided references
1. Global Area Boom for Greenhouse Cultivation Revealed by Satellite Mapping10.1038/s43016-024-00985-0 ↗
2. López, J.C., Pérez, C., and Acien, F.G. (2025, April 29). Vegetable Waste from the Greenhouses of Almeria (Original Article in Spanish: Residuos Vegetales Procedentes de Los Invernaderos de Almería). Available online: https://www.cajamar.es/storage/documents/017-restos-vegetales-1466406472-2d5fa.pdf.
3. (2025, April 29). Junta de Andalucía Mapping of Greenhouses in Almería, Granada and Málaga (Original Document in Spanish: Cartografía de Invernaderos En Almería, Granada y Málaga). Consejería de Agricultura, Ganadería, Pesca y Desarrollo Sostenible, Junta de Andalucía. Available online: https://www.juntadeandalucia.es/export/drupaljda/producto_estadistica/19/06/Cartografia%20_inv_AL_GR_MA_v201127.pdf.
4. Céspedes, A.J., García, M.C., Pérez, J.J., and Cuadrado, I.M. (2025, April 29). Characterisation of the Protected Horticultural Exploitation of Almeria (Article Original in Spanish: Caracterización de La Explotación Hortícola Protegida de Almería). Available online: https://www.juntadeandalucia.es/export/drupaljda/noticias/16/07/160708_El%20Sistema%20de%20Producci%C3%B3n%20Hort%C3%ADcola%20de%20la%20Provincia%20de%20Almer%C3%ADa.pdf.
5. Sayadi-Gmada, S., Rodríguez-Pleguezuelo, C.R., Rojas-Serrano, F., Parra-López, C., Parra-Gómez, S., García-García, M.d.C., García-Collado, R., Lorbach-Kelle, M.B., and Manrique-Gordillo, T. (2019). Inorganic Waste Management in Greenhouse Agriculture in Almeria (SE Spain): Towards a Circular System in Intensive Horticultural Production. Sustainability, 11.10.3390/su11143782 ↗
6. (2025, April 29). Directive EU 2018/851 European Parliament Directive
7. (EU) 2018/851 of the European Parliament and of the Council of 30 May 2018 Amending Directive 2008/98/EC on Residue (Text with EEA Relevance). Available online: http://data.europa.eu/eli/dir/2018/851/oj/eng.
8. Cassou, E. (2025, April 29). Field Burning. Agricultural Pollution. Available online: https://documents1.worldbank.org/curated/en/989351521207797690/pdf/124342-repl-WB-Knowledge-Burning.pdf.
9. Does Growing Vegetables in Plastic Greenhouses Enhance Regional Ecosystem Services beyond the Food Supply?10.1890/100223 ↗
10. Sadh, P.K., Duhan, S., and Duhan, J.S. (2018). Agro-Industrial Wastes and Their Utilization Using Solid State Fermentation: A Review. Bioresour. Bioprocess., 5.10.1186/s40643-017-0187-z ↗
11. Biological Functions and Activities of Rice Bran as a Functional Ingredient: A Review10.1177/11786388211058559 ↗
12. Neitzel, N., Hosseinpourpia, R., Walther, T., and Adamopoulos, S. (2022). Alternative Materials from Agro-Industry for Wood Panel Manufacturing—A Review. Materials, 15.10.3390/ma15134542 ↗
13. Alternative Lignocellulosic Raw Materials in Particleboard Production: A Review10.1016/j.indcrop.2021.114162 ↗
14. Characterization of Banana, Sugarcane Bagasse and Sponge Gourd Fibers of Brazil10.1016/j.indcrop.2009.07.013 ↗
15. Physico-Chemical Characterization of Tunisian Plant Fibers and Its Utilization as Reinforcement for Plaster Based Composites10.1016/j.indcrop.2013.04.052 ↗
16. Optimisation of Compressed Earth Blocks (CEBs) Using Natural Origin Materials: A Systematic Literature Review10.1016/j.conbuildmat.2021.125140 ↗
17. Earth Composites as Construction Material Reinforced with Intensive Agricultural Fibres: Tomato, Pepper, Zucchini, Cucumber, Aubergine and Polypropylene Fibres10.1016/j.conbuildmat.2025.140538 ↗
18. Ductility Analysis of Vegetal-Fiber Reinforced Raw Earth Concrete by Mixture Design10.1016/j.conbuildmat.2019.117829 ↗
19. Effect of Flax Fibers on Early Age Shrinkage and Cracking of Earth Concrete10.1016/j.conbuildmat.2020.119315 ↗
20. Experimental Study on Shrinkage Behaviour of Earth Walling Materials with Fibers and Stabilizer for Cob Building10.1016/j.conbuildmat.2020.119449 ↗
21. The Mechanical Properties and Molecular Bonding Characteristics of Cla Y-Based Natural Composites Reinforced with Animal Fibres10.1166/jbmb.2013.1269 ↗
22. Hygroscopic Behavior of Water Absorbed by Capillarity and Stabilization of a Bio-Composite Building Material: Clay Reinforced with Chamarrops humilis Fibers10.1016/j.icheatmasstransfer.2022.106077 ↗
23. Monitoring of Drying Kinetics Evolution and Hygrothermal Properties of New Earth-Based Materials Using Climatic Chamber Simulation
24. Consolidation of Clay-Rich Earthen Building Materials: A Comparative Study at the Alhambra Fortress (Spain)10.1016/j.jobe.2022.104081 ↗
25. Improving the Bond between Polypropylene Fiber and Cement Matrix by Na No Calcium Carbonate Modification10.1016/j.conbuildmat.2020.121249 ↗
26. Ali, S.M., Lepech, C., D. Lemos, C., and Soto-Oviedo, M.A. (2020, January 17–20). Tailoring of Polypropylene Fibers for the Design of Sustainable Fiber-Reinforced Cement-Based Composites. Proceedings of the IIBCC, International Inorganic-Bonded Fiber Composites Conference, Colombo, Sri Lanka. Available online: hhttps://www.iibcc.biz/wp-content/uploads/2019/05/IIBCC2014-Proceedings-Tailoring-polypropylene-fibers-design-sustainable-fiber-reinforced-cement-based-composites.pdf.
27. Macro Synthetic Fibre Reinforced Concrete: Influence of the Matrix Mix Design on Interfacial Bond Behavior10.1088/1757-899X/596/1/012025 ↗
28. Rebuilding Green Infrastructure in Boreal Production Forest given Future Global Wood Demand10.1111/1365-2664.14175 ↗
29. Boosting the Strength and Toughness of Polymer Blends via Ligand-Modulated MOFs10.1002/advs.202407593 ↗
30. Robust and Durable Biodegradable Polymer-Based Triboelectric Nanogenerators Enabled by Trace Amounts of Melanin-like Nanoparticles10.1016/j.nanoen.2025.110643 ↗
31. Review on the Influencing Factors towards Improving Properties of Composite Insulation Panel Made of Natural Waste Fibers for Building Application10.1177/15280837231151440 ↗
32. A Mini-Review on Building Insulation Materials from Perspective of Plastic Pollution: Current Issues and Natural Fibres as a Possible Solution10.1016/j.jhazmat.2022.129449 ↗
33. Estimation of Methane Production through the Anaerobic Digestion of Greenhouse Horticultural Waste: A Real Case Study for the Almeria Region10.1016/j.scitotenv.2021.151012 ↗
34. Sayadi-Gmada, S., Torres-Nieto, J.M., Parra Gómez, S., García-García, M.C., and Parra-López, C. (2019, January 27–31). Critical Point Analysis in Solid Inorganic Waste Production in the Protected Cultivation Systems in Almeria—Approaches to Reduce the Impact. Proceedings of the XI International Symposium on Protected Cultivation in Mild Winter Climates and I International Symposium on Nettings and Screens in Horticulture, Tenerife, Spain.10.17660/ActaHortic.2020.1268.27 ↗
35. Analysis of Water Absorption of Different Natural Fibers10.4236/jtst.2021.74013 ↗
36. Effects of Fibre Moisture Content on the Mechanical Properties of Jute Reinforced Compressed Earth Composites10.1016/j.conbuildmat.2023.130848 ↗
37. (2025, March 24). Meteorological station Granada Summary of Meteorogical Data of Granada-Albayzín (Original in Spanish: Resumen de Datos Meteo de Granada-Albayzín). Available online: https://www.ugr.es/~velilla/meteo-albayzin/resumen.htm.
38. (2025, April 29). ASTM D3822 Standard Test Method for Tensile Properties of Single Textile Fibers. Available online: https://store.astm.org/d3822_d3822m-14r20.html.
39. Proceedings of Scanning
40. Ultrastructure of Iodine Treated Wood10.1515/HF.2004.034 ↗
41. Scanning and Transmission Electron Microscopy of the Soybean Carpel Pericarp
42. Environmental Management—Life Cycle Assessment—Principles and Framework. Standard No. UNE-EN ISO 14040:2006. Available online: https://www.une.org/encuentra-tu-norma/busca-tu-norma/norma?c=N0038060.
43. Environmental Management—Life Cycle Assessment—Requirements and Guidelines—Amendment 2. Standard No. UNE-EN ISO 14044:2006/A2:2021. Available online: https://www.une.org/encuentra-tu-norma/busca-tu-norma/norma?c=N0066259.
44. Alsabri, A., Tahir, F., and Al-Ghamdi, S.G. (2021). Life-Cycle Assessment of Polypropylene Production in the Gulf Cooperation Council (GCC) Region. Polymers, 13.10.3390/polym13213793 ↗
45. (2024). Cype 2024 FNA010 Stabilised Earth Retaining Wall (Original Document in Spanish: Muro de Carga de Fábrica de Tapia de Tierra Estabilizada).
46. (2024). Cype 2024 RBE050 Base Layer of Cement Mortar on Interior Face (Original Document in Spanish: Capa Base de Mortero de Cemento Sobre Paramento Interior).
47. (2024). Cype 2024 NVF020 Thermal Insulation with Wood Fibre Panels. (Original Document in Spanish: Aislamiento Térmico Con Paneles de Fibras de Madera).
48. Fuentes-Garcia, R., Valverde-Espinosa, I., and Valverde-Palacios, I. (2009). Procedure of preparing soil for use in construction by spraying (original in Spanish: Procedimiento para la adecuacion de tierra para ser puesta en obra mediante proyeccion).
49. Fuentes-García, R., Valverde-Palacios, I., and Valverde-Espinosa, I. (2023, October 03). A New Procedure to Adapt Any Type of Soil for the Consolidation and Construction of Earthen Structures: Projected Earth System|Materiales de Construcción. Available online: https://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/1856.
50. Environmental Assessment of a New Building Envelope Material Derived from Urban Agriculture Wastes: The Case of the Tomato Plants Stems10.1007/s11367-023-02152-2 ↗
51. Valverde-Palacios, I., Fuentes-García, R., Cervilla-Maldonado, A., and Valverde-Espinosa, I. (2022). Earth as a Sustainable Construction Material. Characterization of Different Mixtures and Implementation Using the Projected Earth System. New Technologies in Building and Construction: Towards Sustainable Development, Springer.10.1007/978-981-19-1894-0_17 ↗
52. Crawford, T., Stroehlein, J., and Kuehl, R. (2018). Manganese Stresses and Mineral Nutrition of Cucumber Plants, College of Agriculture, University of Arizona. Vegetable Report.
53. Source Limitation by Defoliation and Its Effect on Dry Matter Production and Yield of Cucumber10.21273/HORTSCI.23.4.704 ↗
54. Physical and Mechanical Characteristics of Raw Jute Fibers, Threads and Diatons10.1016/j.conbuildmat.2022.126903 ↗
55. Bui, H., Hussain, M., Levacher, D., Bui, H., Hussain, M., and Levacher, D. (2022). Recycling of Tropical Natural Fibers in Building Materials. Natural Fiber, IntechOpen.10.5772/intechopen.102999 ↗
56. Physical, Mechanical and Durability Properties of Soil Building Blocks Reinforced with Natural Fibres10.1016/j.conbuildmat.2015.10.069 ↗
57. Mechanisms by Which the Inclusion of Natural Fibres Enhance the Proper Ties of Soil Blocks for Construction10.1177/0021998317693293 ↗
58. Potential Use of Alfa Fibers in Construction Material: Physico-Mechanical and Thermal Characterisation of Reinforced Specimen10.1016/j.conbuildmat.2022.127787 ↗
59. Thermal Degradation and Fire Retardant Behaviour of Natural Fibre Reinforced Polymeric Composites- A Comprehensive Review10.1016/j.jmrt.2024.04.085 ↗
60. Tensile Properties of Single Oil Palm Empty Fruit Bunch (OPEFB) Fibre
61. Mechanical Testing of Tomato Plant Stem in Relation to Structural Composition10.1007/s40003-016-0209-7 ↗
62. The Effect of Fiber Morphology on the Tensile Strength of Natural Fibers10.1016/j.jmrt.2013.02.003 ↗
63. Review: Current International Research into Cellulosic Fibres and Composites10.1023/A:1017512029696 ↗
64. A Review of Recent Developments in Natural Fibre Composites and Their Mechanical Performance10.1016/j.compositesa.2015.08.038 ↗
65. Tensile and Compressive Properties of Flax Fibres for Natural Fibre Reinforced Composites10.1023/A:1014925621252 ↗
66. Fibre Reinforced Concrete Containing Waste Coconut Shell Aggregate, Fl y Ash and Polypropylene Fibre10.17533/10.17533/udea.redin.20190403 ↗
67. Composition, Structure, and Mechanical Properties of Hemp Fiber Reinforced Composite with Recycled High-Density Polyethylene Matrix10.1177/0021998311427778 ↗
68. Dallel, M. (2012). Evaluation Du Potentiel Textile Des Fibres d’Alfa (Stipa tenacissima L.): Caractérisation Physico-Chimique de La Fibre Au Fil. [Ph.D. Thesis, Université de Haute Alsace-Mulhouse].
69. Performance of Polypropylene Fibre Reinforced Concrete
70. Materials Selection and Design for Development of Sustainable Products10.1016/j.matdes.2005.09.006 ↗
71. Geotechnic. Compactation Test. Standard Proctor. Standard No. UNE 103500:1994. Available online: https://en.tienda.aenor.com/norma-une-103500-1994-n0007850.
72. Geotechnical Investigation and Testing—Laboratory Testing of Soil—Part 7: Unconfined Compression Test (ISO 17892-7:2017). Standard No. UNE EN ISO 17892-7:2019. Available online: https://www.en-standard.eu/une-en-iso-17892-7-2019-geotechnical-investigation-and-testing-laboratory-testing-of-soil-part-7-unconfined-compression-test-iso-17892-7-2017/.
73. Methods of Test for Mortar for Masonry—Part 2: Bulk Sampling of Mortars and Preparation of Test Mortars. Standard No. UNE-EN 1015-2:1999. Available online: https://www.une.org/encuentra-tu-norma/busca-tu-norma/norma?c=N0009378.
74. Methods of Test for Mortar for Masonry—Part 11: Determination of Flexural and Compressive Strength of Hardened Mortar. Standard No. UNE-EN 1015-11:2020. Available online: https://www.une.org/encuentra-tu-norma/busca-tu-norma/norma?c=N0063703.
75. Wood-Based Panels—Determination of Modulus of Elasticity in Bending and of Bending Strength. Standard No. UNE-EN 310:1994. Available online: https://www.une.org/encuentra-tu-norma/busca-tu-norma/norma?c=N0008516.
76. Occupational Exposure to Inhalable Wood Dust in the Member States of the European Union
77. Peña, S.V., Plágaro, A.V., Rojas, I.M., Hernando, J., and Laína, R. (2025, April 29). The Wood Industry in Spain in the Context of the World and of Europe (Article Original in Spanish: La Industria Maderera en España en el Contexto del Mundo Y de Europa), Technical Report from Universidad Politécnica de Madrid, Identifying Number DC: 2014. Available online: https://oa.upm.es/23225/.
78. Araya-Letelier, G., Maturana, P., Carrasco, M., Antico, F.C., and Gómez, M.S. (2019). Mechanical-Damage Behavior of Mortars Reinforced with Recycled Polypropylene Fibers. Sustainability, 11.10.3390/su11082200 ↗
79. Mechanical Properties and Microstructure of Polypropylene Fiber Reinforced Cement Mortar Soil10.1007/s12205-021-1125-3 ↗
80. Influence of Aggregates, Glass Fibre Reinforcement and Recycled Aggregates on Polyester Mortar10.1016/j.conbuildmat.2021.123534 ↗