journal article·2025-02-25Open access

Geochemical Background Values for the Characterization of Sediment Contamination with Trace Elements in Romania: A Case Study in the Lower Danube Basin

Anca-Marina Vîjdea, Iustina Popescu, Alexandru Anton Ivanov, Veronica Elena Alexe, Natalia-Silvia Asimopolos, Lidia Lenuța Bălan

Applied Sciences· Volume 15· Issue 5

Abstract

The contamination of the Lower Danube Basin with trace elements has been the subject of intense study in recent years, with several pollution indices being employed for the assessment of water, soil, and sediment quality. Most pollution indices are calculated by comparing the measured concentration to a reference value, with different values from various sources being used. In this study, the threshold values for trace elements (As, Cd, Cu, Hg, Ni, Pb, and Zn) in Romania were selected based on the median of their concentration in stream sediment from 167 locations, which were carefully selected to be far from contamination sources. The threshold values were established based on a calculation starting from the geochemical concentration presented in the Geochemical Atlas of Romania (scale: 1:3,000,000, developed in 2006 by a collaborative Romanian-German team). By using these thresholds, pollution indices were calculated for nine sampling locations, from which suspended sediment, bottom sediment, and active floodplain sediment samples were collected and analyzed in an accredited laboratory. Most of the selected thresholds were found to be below the limits for sediments established by Romanian legislation, except for Cr and Ni, the higher values of which are consistent with the specific geological background of the country and the broader Balkan region.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Geochemistry and Geologic Mapping · Heavy metals in environment · Radioactivity and Radon Measurements

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Geological Institute of Romania, 1 Caransebeș St., 012271 Bucharest, Romania

Funding

Ministry of Research, Innovation and Digitization of Romania through “Program Nucleu” · Interreg Danube Transnational Programme SIMONA

References (100+)

Show source-provided references
1. The Danube river basin environmental programme: Plans and actions for a basin wide approach10.1016/S1366-7017(99)00025-2 ↗
2. Frincu, R.-M. (2021). Long-term trends in water quality indices in the Lower Danube and tributaries in Romania (1996–2017). Int. J. Environ. Res. Public Health, 18.10.3390/ijerph18041665 ↗
3. Gupta, A. (2022). The Danube: Morphology, Evolution, and Environmental Issues. Large Rivers, John Wiley & Sons.10.1002/9781119412632 ↗
4. The Danube Delta Evolution during the Holocene: Reconstruction attempt using geomorphological and geological data, and some of the existing cartographic elements
5. Riverbed erosion on the Hungarian Holocene: Section of the Danube
6. Habersack, H., and Bradley, C. (2022). Hydropower in the Danube River Basin: Current Status and Emerging Challenges. Reference Module in Earth Systems and Environmental Sciences, Elsevier.10.1016/B978-0-12-819166-8.00195-X ↗
7. (2024, November 14). Assessment Report on Hydropower Generation in the Danube Basin. ICPDR Report. Available online: https://www.icpdr.org/sites/default/files/nodes/documents/hydropower_assessment_report_danube_basin_-_final.pdf.
8. (2019). Manual on Danube Navigation. BMVIT Action Programme for the Danube, Viadonau–Österreichische Wasserstraßen-Gesellschaft mbH, Viadonau. [4th ed.]. Available online: https://www.viadonau.org/fileadmin/user_upload/Manual_on_Danube_Navigation.pdf.
9. (2025, January 14). Monitoring of Environmental Impact of the Works for Improvement of the Navigation Conditions on the Danube between Calarasi and Braila, km 375-km 175; Reports of ROMOMED Project. Available online: https://afdj.ro/en/content/romomed.
10. Pistocchi, A., Beck, H., Bisselink, B., Gelati, E., Lavalle, C., and Feher, J. (2015). Water Scenarios for the Danube River Basin: Elements for the Assessment of the Danube Agriculture-Energy-Water Nexus, Publications Office of the European Union.
11. Irrigation water use in the Danube Basin: Facts, governance and approach to sustainability10.2478/jengeo-2019-0007 ↗
12. Between Waterway and Railway–Industry along the Danube Riverside in Budapest10.3311/PPar.7554 ↗
13. Management of the Danube drainage basin: Implications of contaminant-metal dispersal for the implementation of the EU Water Framework Directive10.1080/15715121003715115 ↗
14. Pb isotope evidence for contaminant-metal dispersal in an international river system: The Lower Danube catchment, Eastern Europe10.1016/j.apgeochem.2010.04.012 ↗
15. Radu, C., Manoiu, V.-M., Hubiak-Wojcicka, K., Avram, E., Beteringhe, A., and Crăciun, A.-I. (2022). Romanian Danube River Hydrocarbon Pollution in 2011–2021. Water, 14.10.3390/w14193156 ↗
16. Assessing human risks through CSOIL exposure model for soil contamination associated to heavy metals
17. Schmedtje, U. (2005). Danube River Basin District. Part A: Basin-Wide Overview, ICPDR. Available online: https://www.icpdr.org/sites/default/files/ICPDR_gesamt_klein.pdf.
18. Relative influence of chemical and non-chemical stressors on invertebrate communities: A case study in the Danube River10.1016/j.scitotenv.2016.07.087 ↗
19. Preliminary investigation of Lower Danube pollution caused by potentially toxic metals10.1016/j.chemosphere.2020.128496 ↗
20. Nazal, M., and Zhao, H. (2021). Heavy Metal Sources and Their Effects on Human Health. Heavy Metals–Their Environmental Impact and Mitigation, IntechOpen.10.5772/intechopen.91574 ↗
21. Pollution indices as useful tools for the comprehensive evaluation of the degree of soil contamination–A review10.1007/s10653-018-0106-z ↗
22. Index of geoaccumulation in sediments of the Rhine River
23. An ecological risk index for aquatic pollution control. A sedimentological approach10.1016/0043-1354(80)90143-8 ↗
24. Composition of the continental crust
25. Kabata-Pendias, A., and Pendias, H. (2001). Trace Elements of Soils and Plants, CRC Press. [3rd ed.].10.1201/9781420039900 ↗
26. Kloke, A. (1979, January 20). Content of Arsenic, Cadmium, Chromium, Fluorite, Lead, Mercury and Nickel in Plants Grown on Contaminated Soil. Proceedings of the United Nations ECE Symp, on Effects of Airborne Pollution on Vegetation, Warsaw, Poland.
27. Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine sediments10.1007/BF02472006 ↗
28. River sediment quality assessment using sediment quality indices for the Sydney basin, Australia affected by coal and coal seam gas mining10.1016/j.scitotenv.2017.10.259 ↗
29. geochemical background–concept and reality10.1016/j.scitotenv.2005.01.047 ↗
30. Geochemical background and baseline values of toxic elements in stream sediments of Campania region (Italy)10.1016/j.gexplo.2006.07.006 ↗
31. Distinguishing between natural and anthropogenic sources for elements in the environment: Regional geochemical surveys versus enrichment factors10.1016/j.scitotenv.2004.06.011 ↗
32. Intrinsec Flaws of Element Enrichment Factors (EFs) in Environmental Chemistry10.1021/es001339o ↗
33. Background and threshold: Critical comparison of methods of determination10.1016/j.scitotenv.2004.11.023 ↗
34. Establishing geochemical background variation and threshold values for 59 elements in Australian surface soil10.1016/j.scitotenv.2016.11.010 ↗
35. Enrichment and contamination level of trace metals in the Mediterranean marine sediments of Spain10.1016/j.scitotenv.2019.07.372 ↗
36. Bereș, I., Maftei, A.E., Dill, H.G., Buzatu, A., and Damian, G. (2024). Contamination Assessment of Toxic Elements in River Sediments from Baia Mare, Romania–Extreme Pollution from Mining Activities. Minerals, 14.10.3390/min14020135 ↗
37. Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
38. Ecological Risk Assessment of the Heavy metals in surface Sediments from the Danube River
39. Calmuc, V.A., Calmuc, M., Arseni, M., Topa, C.M., Timofti, M., Burada, A., Iticescu, C., and Georgescu, L.P. (2023). Assessment of heavy metal pollution levels in sediments and of ecological risk by quality indices, applying a case study: The Lower Danube River, Romania. Water, 13.10.3390/w13131801 ↗
40. Analysis and assessment of heavy metal pollution in suspended solids and sediments of the river Danube10.1016/S0045-6535(03)00217-0 ↗
41. Micropollutants in the Danube river basin10.2166/wst.1999.0497 ↗
42. (2025, February 19). Order of the Ministry of Environment and Waters no. 161/2006 for the Approval of the Norms on Reference Objectives for the Surface Water Quality Classification (including Quality Standards for Sediments). Official Monitor 2006, Part 1, no. 511 bis. Available online: https://legislatie.just.ro/Public/DetaliiDocument/72574.
43. Development and Evaluation of Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems10.1007/s002440010075 ↗
44. Sediments as Indicators of Heavy Metal Contamination in the Lower Danube River
45. Spatial and seasonal variations of heavy metals in water and sediment samples collected from the Lower Danube River
46. Assessment of heavy metals pollution in sediments from reservoirs of the Olt River as tool environmental risk management
47. Assessment of contamination with hazardous substances in surface sediments in the Lower Danube Basin10.47577/technium.v1i.17 ↗
48. Lower Danube water quality assessment using heavy metal indices
49. Heavy metal evaluation in the lower sector of Danube River
50. Actual aspects concerning the water quality monitoring on the Sulina Channel from the Danube Delta–Romania
51. Macro-and microelements abundance in some urban soils from Romania. Carpth
52. Clarke, F.W. (2024, July 05). The data of geochemistry, United States Geological Survey, Available online: https://pubs.usgs.gov/publication/b770.
53. Fiedler, H.J., and Rösler, H.J. (1998). Spurenelemente in der Umwelt (in German–Trace elements in the environment), Ferdinand Enke Verlag.
54. Estimations of Clarkes for Carbonaceous biolithes: World averages for trace element contents in black shales and coals10.1016/j.coal.2009.01.002 ↗
55. Heavy Metals Soil Pollution in Some Urban Locations from Romania
56. (2025, February 19). Order 756/1997 of the Ministry of Waters, Forests and Environmental Protection in Romania Approving the Regulation on the Assessment of Environmental Pollution. Official Monitor 1997, no. 300 bis. Available online: https://legislatie.just.ro/Public/DetaliiDocument/13572.
57. Ewers, U. (1991). Standards, Guidelines, and Legislative Regulations Concerning Metals and their Compounds. Metals and Their Compounds in the Environment, Merian, E., Ed., Wiley-VCH.
58. Heineke, H.J., Eckelmann, W., Thomasson, A.-J., Jones, R.J.A., Montanarella, L., and Buckley, B. (1998). Apprising Levels of Soil Contamination and Pollution with Heavy Metals. Developments for Planning the Sustainable Use of Land Resources, European Commission, European Soil Bureau. Research Report no. 4.
59. Assessment of Minor and Trace Elements in Aquatic Macrophytes, Soils and Bottom Sediments Collected along Different Water Objects in the Black Sea Coastal Zone by Using Neutron Activation Analysis10.4236/ajac.2017.84018 ↗
60. Geochemical Atlas of Romania
61. Assessment of river sediment quality according to the EU Water Framework Directive in large river fluvial conditions. A case study in the Lower Danube River basin10.26471/cjees/2023/018/251 ↗
62. Assessment of the quality of river sediments in baseline national monitoring stations of 12 countries in the Danube River basin10.26471/cjees/2022/017/233 ↗
63. Impacts of Climate Change on the Hydrological Regime of the Danube River and Its Tributaries Using an Ensemble of Climate Scenarios10.3390/w7116139 ↗
64. Iordache, G., Catianis, I., Anghel, S., and Pop, I.C. (2021, January 14–22). Assesing Danube riverbed morphology as a response to natural and anthropogenic conditions using GIS: A case study of the Ceatal Izmail branching area. Proceedings of the 21st International Multidisciplinary Scientific Geo-Conference SGEM, Albena, Bulgaria.10.5593/sgem2021/2.1/s11.79 ↗
65. The Danube Delta Hydrologic database and modeling
66. Vogel, B., and Pall, K. (2001). Nine Geo-Morphological Danube Reaches Under Consideration of Anthropogenic Impacts, ICPDR Permanent Secretariat, Vienna International Centre. Available online: https://www.icpdr.org/sites/default/files/JDS%2005%20Chapt%203.pdf.
67. Săndulescu, M. (1984). Geotectonica României. (Geotectonics of Romania), Editura Tehnică. (In Romanian).
68. Peive, A.V., Khain, V.E., Mouratov, M.V., and Delany, F. (1981). Main tectonic subdivisions of Europe and adjacent continental and oceanic areas. Tectonics of Europe and Adjacent Areas. Cratons, Baikalides, Caledonides. Explanatory Note to the International Tectonic Map of Europe and Adjacent Areas, Scale 1:2.500.000. International Geological Congress, Commission for the Geological Map of the World, Sub-Commission for the Tectonic Map of the World, Nauka Publising House.
69. Upper Cretaceous magmatic series and associated mineralization in the Carpatho-Balkan Orogen10.1111/j.1751-3928.1998.tb00026.x ↗
70. Regional setting and geochronology of the Late Cretaceous Banatitic Magmatic and Metallogenetic Belt10.1007/s00126-002-0272-9 ↗
71. European Commission (2010). Common Implementation Strategy for the Water Framework Directive (2000/60/EC): Guidance Document No. 25 on Chemical Monitoring of Sediment and Biota Under the Water Framework Directive, Office for Official Publications of the European Communities. Technical Report-2010–041.
72. (2017). Water quality—Sampling—Part 12: Guidance on sampling of bottom sediments from rivers, lakes and estuarine areas (Standard No. ISO 5667–12:2017).
73. (2008). Water quality—Sampling—Part 17: Guidance on sampling of bulk suspended solids (reviewed and confirmed in 2017) (Standard No. ISO 5667–17:2008).
74. (2012). Danube Atlas Hazard and Risk Maps, Samia Publishing House.
75. Assessment of the natural and anthropogenic sources of chemical elements in alluvial soils from the Drava River using multivariate statistical methods10.1016/j.gexplo.2011.06.009 ↗
76. Salminen, R. (2005). Geochemical Atlas of Europe. Part 1—Background Information, Methodology and Maps, Geological Survey of Finland.
77. Assessment of sediment toxicity by metal speciation in different particle-size fractions of river sediment10.2166/wst.2003.0694 ↗
78. Lability of potentially toxic elements in soils affected by smelting activities10.1016/j.chemosphere.2012.09.091 ↗
79. Zhang, J., Liu, Y., Hong, S., Wen, M., Zheng, C., and Liu, P. (2023). Speciation Analysis and Pollution Assessment of Heavy Metals in Farmland Soil of a Typical Mining Area: A Case Study of Dachang Tin Polymetallic Ore, Guangxi. Appl. Sci., 13, Available online: https://www.mdpi.com/2076-3417/13/2/708.10.3390/app13020708 ↗
80. Sheng, Y., Jiang, W., and Zhang, M. (2023). Mobilization, Speciation, and Transformation of Organic and Inorganic Contaminants in Soil–Groundwater Ecosystems. Appl. Sci., 13.10.3390/app132011454 ↗
81. (1993). Soil Quality—Determination of Dry Matter and Water Content on a Mass Basis—Gravimetric Method (Standard No. ISO 11465:1993).
82. Characterization of Sludges—Determination of Dry Residue and Water Content (Standard No. EN 12880:2000). Available online: https://standards.iteh.ai/catalog/standards/cen/5495e0f6-cfe6-46fe-a9c1-81be439f8a7d/en-12880-2000?srsltid=AfmBOoqKaS9jCMsH-JMAX1OBWo2vFV6-NLm7bUYulLF_38PdkxgLxE2T.
83. Characterization of Waste—Calculation of Dry Matter by Determination of Dry Residue or Water Content (Standard No. EN 14346:2006). Available online: https://standards.iteh.ai/catalog/standards/cen/c345ad72-3222-4b57-920b-29865d273a3c/en-14346-2006?srsltid=AfmBOopvCjUmLGQQBvrFoubmbjtFF2azeK9_KrxCx6mNoL0gDG9H3Lt1.
84. Characterization of Waste Digestion for Subsequent Determination of Aqua Regia Soluble Portion of Elements (Standard No. EN 13657:2002). Available online: https://standards.iteh.ai/catalog/standards/cen/b3a7f7ab-26b5-42db-9c7a-d31a9bb4f18b/en-13657-2002?srsltid=AfmBOoox7egkjq76Ee4kPmmb8POdFVki-ufwwK1wPw-j1eh4aY_McNBN.
85. (1995). Soil Quality—Extraction of Trace Elements Soluble in Aqua Regia (Standard No. ISO 11466:1995).
86. Water Quality—Determination of Mercury—Method Using Atomic Fluorescence Spectrometry (Standard No. EN ISO 17852:2008). Available online: https://www.google.com.hk/url?sa=t&source=web&rct=j&opi=89978449&url=https://cdn.standards.iteh.ai/samples/27658/e8aa18d5bbb249bd8615e002afa6d185/SIST-EN-ISO-17852-2008.pdf&ved=2ahUKEwih4v2Y_92LAxWzr1YBHYU0FUcQFnoECBMQAQ&usg=AOvVaw0kOu1ju7TwOWac8z0nJV_3.
87. (2004). Soil Quality—Determination of Mercury in Aqua Regia Soil Extracts with Cold-Vapour Atomic Spectrometry or Cold-Vapour Atomic Fluorescence Spectrometry (Standard No. ISO 16772:2004).
88. (2025, February 19). P S Analytical Application Notes APP025—Determination of Mercury in Contaminated Soil. Available online: https://www.psanalytical.com/information/applicationnotes.html.
89. U.S. EPA (2025, February 19). Method 200.8: Determination of Trace Elements in Waters and Wastes by Inductively Coupled Plasma-Mass Spectrometry. Revision 5.4. Cincinnati, OH, Available online: https://www.google.com.hk/url?sa=t&source=web&rct=j&opi=89978449&url=https://www.epa.gov/sites/default/files/2015-06/documents/epa-200.8.pdf&ved=2ahUKEwj8oYv9_92LAxVc3TQHHZEoDEoQFnoECA0QAQ&usg=AOvVaw0HvcsBrEuHXEAz7L--i6lV.
90. Water Quality—Application of Inductively Coupled Plasma Mass Spectrometry (ICP-MS)—Part 2: Determination of Selected Elements Including Uranium Isotopes (Standard No. EN ISO 17294-2:2023). Available online: https://www.iso.org/standard/82245.html.
91. EPA (2025, February 19). Method 6020A (SW-846): Inductively Coupled Plasma-Mass Spectrometry. Revision 1, Available online: https://www.google.com.hk/url?sa=t&source=web&rct=j&opi=89978449&url=https://19january2017snapshot.epa.gov/sites/production/files/2015-07/documents/epa-6020a.pdf&ved=2ahUKEwibg8rkgN6LAxUErlYBHdN4J1UQFnoECBYQAQ&usg=AOvVaw21FJkOQuUPjWXPIMaKNCNl.
92. Wilcox, R.R. (2003). Summarizing Data. Applying Contemporary Statistical Technique, Academic Press.10.1016/B978-012751541-0/50024-9 ↗
93. Development of a hycrid pollution index for heavy metals in marine and estuarine sediments10.1007/s10661-015-4563-x ↗
94. Nemerow, N.L. (1970). Benefits of Water Quality Enhancement.
95. Application of single Factor and Multi-Factor Pollution Indices Assessment for Human-Impacted River Basins: Water Quality Classification and Pollution Indicators
96. Su, K., Wang, Q., Li, L., Cao, R., Xi, Y., and Li, G. (2022). Water quality assessment based on Nemerow pollution index method: A case study of Heilongtan reservoir in central Sichuan province, China. PLoS ONE, 17.10.1371/journal.pone.0273305 ↗
97. Application and comparison of four assessment methods for water quality of Sancha Lake in Central Sichuan Province, China10.2166/wpt.2023.186 ↗
98. Assessment of contamination level, pollution risk and source apportionment of heavy metals in the Halda River water, Bangladesh10.1016/j.heliyon.2021.e08625 ↗
99. Ecological Indices of the Heavy Metals in the Soil of Shewasoor Sub-Basin, Kirkuk NE Iraq
100. Assessment and mapping of environmental quality in agricultural soils of Zhejiang Province, China10.1016/S1001-0742(07)60008-4 ↗