journal article·2025-07-08Open access

Comparative Corrosion and Wear Behaviors of Cermet Coatings Obtained from Conventional and Recycled Powders

Dino Woelk, Julian Eßler, Ion-Dragos Utu, Gabriela Marginean

Applied Sciences· Volume 15· Issue 14

Abstract

Many components in industry are subjected to high loads during operation and therefore often do not reach their intended service life. Conventional steels frequently do not provide sufficient protection against wear and corrosion. One solution is to coat these components using methods like thermal spraying to apply cermet coatings such as Cr3C2-NiCr or WC-Co-Cr. In light of increasingly strict environmental regulations, more eco-friendly alternatives are needed, especially ones that use little or no Cr, Ni, Co, or W. Another alternative is the recycling of powder materials, which is the focus of this research project. This study investigated whether filter dust from an HVOF system could be used to develop a new coating suitable for use in applications requiring resistance to wear and corrosion. This is challenging as the filter dusts have heterogeneous compositions and irregular particle sizes. Nevertheless, this recycled material, referred to as “Green Cermets” (GCs), offers previously untapped potential that may also be of ecological interest. An established WC-Co-Cr coating served as a reference. In addition to friction wear and corrosion resistance, the study also examined particle size distribution, hardness, microstructure, and susceptibility to crack formation at the interface and inside the coating. Even though the results revealed a diminished performance of the GC coatings relative to the conventional WC-CoCr, they may still be applicable in various industrial applications.
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Research context

OpenAlex topics: Advanced materials and composites · High-Temperature Coating Behaviors · Metal Alloys Wear and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials and Manufacturing Engineering Department, Faculty of Mechanical Engineering, Politehnica University of Timisoara, Bvd. Mihai Viteazu nr. 1, 300222 Timisoara, Romania

Institute of Mechanical Engineering, Westphalian University of Applied Sciences, Neidenburgerstr. 43, 45897 Gelsenkirchen, Germany

References (43)

Show source-provided references
1. Mechanism evaluations of conventional and suspended HVOF thermal spraying based on EDC and EDM combustion models10.1016/j.applthermaleng.2024.122405 ↗
2. A review on High-Velocity Oxy-Fuel (HVOF) coating technique10.1007/s40033-022-00434-x ↗
3. Investigations of microstructure and corrosion resistance of WC-Co and WC-Cr3C2-Ni coatings deposited by HVOF on magnesium alloy substrates10.1016/j.surfcoat.2023.129355 ↗
4. Mechanism study on the influence of combustion models and spray gun geometric parameters on HVOF thermal spraying10.1016/j.jmapro.2023.05.022 ↗
5. Pradeep, D.G., Venkatesh, C.V., and Nithin, H.S. (2022). Review on tribological and mechanical behavior in HVOF thermal-sprayed composite coatings. J. Bio- Tribo-Corros., 8.10.1007/s40735-022-00631-x ↗
6. Time-varying evolutionary mechanism analysis of the multiphase flow during HVOF thermal spraying WC-12Co particle10.1016/j.surfcoat.2023.129435 ↗
7. Comprehensive study on the effect of HVOF processing parameters and particle size on high-temperature properties of NiCoCrAlYTa coatings10.1016/j.surfcoat.2023.129951 ↗
8. Cyclic oxidation characteristics of HVOF thermal-sprayed NiCoCrAlY and CoNiCrAlY coatings at 1000 °C10.1016/j.jallcom.2018.02.282 ↗
9. The aqueous corrosion and wear responses of HVOF-deposited TiC-Ni3Al, WC-Co, and WC-CoCr coatings on AISI 4130 steel substrates10.1016/j.surfcoat.2023.130018 ↗
10. HVOF coatings as an alternative to hard chrome for pistons and valves10.1016/j.wear.2005.12.005 ↗
11. Performance Evaluation of Thin Cermet Coatings Produced by HVAF Spray: A New Approach for Hard Chrome Replacement10.1007/s11666-023-01563-9 ↗
12. Studies on wear and microstructure assessment of WC-Co reinforced iron based HVOF coating10.1016/j.rsurfi.2024.100237 ↗
13. Effect of binder phases on the microstructure and sliding wear properties of HVOF-sprayed WC-based coatings10.1016/j.ijrmhm.2024.106742 ↗
14. Corrosion and wear of coatings fabricated by HVOF-spraying of nanostructured and conventional WC–10Co-4Cr powders on Al7075-T610.1016/j.ijrmhm.2023.106164 ↗
15. Process characteristics, particle behavior and coating properties during HVOF spraying of conventional, fine and nanostructured WC-12Co powders10.1016/j.surfcoat.2020.126716 ↗
16. Effect of heat treatment on the wet abrasion resistance of WC-10Co4Cr coatings deposited onto stainless steel by HVOF10.1080/17515831.2021.1938869 ↗
17. Influences of the compositions and mechanical properties of HVOF sprayed bimodal WC-Co coating on its high temperature wear performance10.1016/j.ijrmhm.2017.08.012 ↗
18. Wear behaviour of WC–Co HVOF coatings at different temperatures in air and argon10.1016/j.wear.2015.01.035 ↗
19. A comparison of cold spray, atmospheric plasma spray and high velocity oxy fuel processes for WC-Co coatings deposition through LCA and LCCA10.1016/j.heliyon.2024.e38961 ↗
20. Agnihotri, A., Vasudev, H., Singh, G., Singh, S., Hosalli, R., Veeresha, G., Prasad, C.D., Balu, R., and Tiwari, A. (2025). Evaluation of HVOF sprayed and burnished WC-Co-Cr coatings on boiler steel: Mechanical and microstructural properties. J. Bio- Tribo-Corros., 11.10.1007/s40735-025-00975-0 ↗
21. Wear and Corrosion of HVAF and HVOF-Sprayed WC-CoCr Coatings on Aluminum Alloy10.1007/s11666-024-01894-1 ↗
22. Corrosion behavior of HVOF sprayed WC-10Co4Cr coatings in the simulated seawater drilling fluid under the high pressure10.1016/j.engfailanal.2019.104338 ↗
23. Theoretical analysis of magnetorheological finishing of HVOF sprayed WC-Co coating10.1016/j.ijmecsci.2021.106629 ↗
24. Application of HVOF WC-Co-Cr coatings on the internal surface of small cylinders: Effect of internal diameter on the wear resistance10.1016/j.wear.2019.202965 ↗
25. TiC–NiCr thermal spray coatings as an alternative to WC-CoCr and Cr3C2–NiCr10.1016/j.wear.2020.203273 ↗
26. Abrasive wear resistance of WC-based composites, produced with Co or Ni-rich binders10.1016/j.wear.2021.203924 ↗
27. Cobalt free metallic binders for HVOF thermal sprayed wear resistant coatings10.1016/j.surfcoat.2023.129243 ↗
28. Microstructure and wear resistance of environmentally friendly NbC-FeCr coatings: An evaluation of HVOF process parameters10.1016/j.surfcoat.2025.132208 ↗
29. Advances in thermally sprayed WC-based wear-resistant coatings: Co-free binders, processing routes and tribological behavior10.1007/s11666-022-01358-4 ↗
30. Recycling of secondary tungsten resources10.1007/s12666-016-1003-8 ↗
31. Sustainable extraction of tungsten from the acid digestion product of tungsten concentrate by leaching-solvent extraction together with raffinate recycling10.1016/j.jclepro.2022.133924 ↗
32. Toward sustainable utilization of tungsten: Evidence from dynamic substance flow analysis from 2001 to 2019 in China10.1016/j.resconrec.2022.106307 ↗
33. Effect of heat treatments on the wear resistance of HVAF and HVOF sprayed tool steel coatings10.1016/j.surfcoat.2023.129508 ↗
34. Kumar, R., Kariminejad, A., Antonov, M., Goljandin, D., Klimczyk, P., and Hussainova, I. (2023). Progress in sustainable recycling and circular economy of tungsten carbide hard metal scraps for Industry 5.0 and onwards. Sustainability, 15.10.3390/su151612249 ↗
35. Gislev, M., Grohol, M., Mathieux, F., Ardente, F., Bobba, S., Nuss, P., Blengini, G., Alves Dias, P., Blagoeva, D., and Matos, C. (2018). Report on Critical Raw Materials and the Circular Economy, European Commission.
36. Recycling of tungsten: Current share, economic limitations, technologies and future potential10.1016/j.ijrmhm.2021.105546 ↗
37. An emergy-based comparison between primary and secondary tungsten production in China10.1016/j.eiar.2024.107548 ↗
38. Pacini, A., Lupi, F., Rossi, A., Seggiani, M., and Lanzetta, M. (2023). Direct recycling of WC-Co grinding chip. Materials, 16.10.3390/ma16041347 ↗
39. Study of the processing of a recycled WC–Co powder: Can it compete with conventional WC–Co powders?10.1007/s40831-021-00346-2 ↗
40. Influence of powder properties on residual stresses formed in high-pressure liquid fuel HVOF sprayed WC-CoCr coatings10.1016/j.surfcoat.2020.125604 ↗
41. Statistical comparison of processing different powder feedstock in an HVOF thermal spray process10.1007/s11666-022-01392-2 ↗
42. Role of thermal spray in combating climate change10.1007/s42247-021-00307-1 ↗
43. Microstructural, mechanical and wear behavior of HVOF and cold-sprayed high-entropy alloys (HEAs) coatings10.1007/s11666-021-01293-w ↗