journal article·2024-12-21Open access

Modified Kapok Fibers (Ceiba pentandra (L.) Gaerth) for Oil Spill Remediation

Leonardo M. T. M. Oliveira, Eduardo J. S. Fonseca, Vanderson B. Bernardo, Carmem L. P. S. Zanta, Laís F. A. M. Oliveira, Jennifer N. S. R. de Oliveira, Samuel T. de Souza, José Leandro da Silva Duarte

Applied Sciences· Volume 14· Issue 24

Abstract

The search for efficient oil spill remediation techniques leads to the use of physical, chemical, and biological methods, featuring both natural and modified lipophilic materials. Kapok fibers (Ceiba pentandra (L.) Gaerth) have been studied as a result of their unusual natural oil sorption capacity, which can be improved even further through physical or chemical treatments that augment their rugosity and alter their functional properties. Furthermore, the exact role of fiber morphology is not completely clear regarding the sorption process. Hence, this study investigated the efficacy of kapok fibers using different treatments, based on chemical and physical approaches, and characterized using advanced techniques (FTIR, SEM, AFM), aiming to improve the understanding of application possibilities in oil contamination scenarios. The results indicate that treatments using a low thermal intensity and low concentration do not lead to variation in sorption properties nor in surface structural features. Fiber rugosity varied from 4.40 to 12.35 nm, whereas an excessive increase in roughness was observed when the material was subject to more extreme conditions, such as a temperature of 120 °C and high concentrations (2.0 M) of both acid or alkali, accompanied by a loss in functionality and affecting the material sorption capacity. Thus, the study provides conditions to suggest that these treatments are not necessary for this type of material when inserted into sorption processes.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Oil Spill Detection and Mitigation · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory of Materials for Environmental Remediation (LabMARE), Technology Center, Federal University of Alagoas, Maceió 57072-900, AL, Brazil

Physics Institute, Federal University of Alagoas, Av. Lourival Melo Mota, s/n, Campus A.C. Simões, Tabuleiro do Martins, Maceió 57072-970, AL, Brazil

Chemistry and Biotechnology Institute, Federal University of Alagoas, Av. Lourival Melo Mota, s/n, Campus A.C. Simões, Tabuleiro do Martins, Maceió 57072-970, AL, Brazil

Department of Chemical Engineering and Materials, Faculty of Chemical Sciences, Complutense University of Madrid, Avenida Complutense s/n, 28040 Madrid, Spain

Funding

Alagoas State Research Support Foundation (FAPEAL/Brazil)

References (33)

Show source-provided references
1. The declining performance of the oil sector: Implications for global climate change mitigation10.1016/j.apenergy.2021.117210 ↗
2. Reducing maritime accidents in ships by tackling human error: A bibliometric review and research agenda10.1186/s41072-021-00098-y ↗
3. Risk assessment of petroleum product transportation by road: A framework for regulatory improvement10.1016/j.ssci.2015.06.022 ↗
4. Liu, J., Jiao, P., and Xu, Y. (2023). Research on oil boom performance based on Smoothed Particle Hydrodynamics method. PLoS ONE, 18.10.1371/journal.pone.0289276 ↗
5. Dispersants as an oil spill clean-up technique in the marine environment: A review10.1016/j.heliyon.2022.e10153 ↗
6. A comprehensive study on diesel oil bioremediation under microcosm conditions using a combined microbiological, enzymatic, mass spectrometry, and metabarcoding approach10.1007/s11356-023-29474-w ↗
7. Sorption as a rapidly response for oil spill accidents: A material and mechanistic approach10.1016/j.jhazmat.2020.124842 ↗
8. Super-hydrophobic chitosan/graphene-based aerogels for oil absorption10.1016/j.molliq.2023.123071 ↗
9. Waste plastic-derived aerogel modified with graphene oxide for hygroscopic material and oil spill treatment10.1016/j.molstruc.2023.135737 ↗
10. Niehaus, D., Hofmann, S., Kumar, S.B., Hoffmann, M., Cisneros-Aguirre, J., and Schlüter, M. (2022). Experimental characterisation and field experience of a reusable, modified polyurethane foam for the mechanical clean-up of oil spills on the sea surface. J. Mar. Sci. Eng., 10.10.3390/jmse10101369 ↗
11. Chitosan and chitosan composites for oil spills treatment: Review of recent literature10.1016/j.jwpe.2023.104193 ↗
12. Application of Agricultural Waste from Main Brazilian Crops as Adsorbent for Wastewater Treatment10.21577/1984-6835.20230017 ↗
13. Polysaccharides in agro-industrial biomass residues10.3390/polysaccharides3010005 ↗
14. A novel polyurethane-based sorbent material for oil spills management10.1016/j.jece.2023.111386 ↗
15. Fürtauer, S., Hassan, M., Elsherbiny, A., Gabal, S.A., Mehanny, S., and Abushammala, H. (2021). Current status of cellulosic and nanocellulosic materials for oil spill cleanup. Polymers, 13.10.3390/polym13162739 ↗
16. Hydrothermal treatment and transesterification modification of rice straw for oil spill absorption material
17. Kekik, B., Yakışık, H., and Özveren, U. (2022). Investigation of light crude oil removal using biocoal from torrefaction of biomass waste. Bioresour. Technol. Rep., 19.10.1016/j.biteb.2022.101139 ↗
18. Oil spill remediation and valorization of oil-soaked peat sorbent to biofuel by hydrothermal liquefaction10.1007/s13399-021-01887-y ↗
19. Study of acid treated mixed sawdust as natural oil sorbent for oil spill10.1016/j.matpr.2019.11.156 ↗
20. Novel kapok pods (Ceiba pentandra (L.) Gaerth) adsorbent and its reusability by transformation on hydrochar with an outstanding adsorptive capacity for Rhodamine B removal10.1016/j.seppur.2023.124787 ↗
21. Ultrafast diesel oil spill removal by fibers from silk-cotton tree: Characterization and sorption potential evaluation10.1016/j.jclepro.2020.121448 ↗
22. Effect of kapok fiber treated with various solvents on oil absorbency10.1016/j.indcrop.2012.03.002 ↗
23. Sorption kinetics and mechanism of various oils into kapok assembly10.1016/j.marpolbul.2014.11.044 ↗
24. Acetylated modification of kapok fiber and application for oil absorption10.1007/s12221-013-1834-4 ↗
25. Effect of roughness and shape factor on flotation characteristics of glass beads10.1016/j.colsurfa.2015.12.025 ↗
26. Fouling of roughened stainless steel surfaces during convective heat transfer to aqueous solutions10.1016/j.enconman.2007.09.034 ↗
27. Surface inorganic scale formation in oil and gas industry: As adhesion and deposition processes10.1016/j.petrol.2015.11.005 ↗
28. Oil sorbents with high sorption capacity, oil/water selectivity and reusability for oil spill cleanup10.1016/j.marpolbul.2014.05.005 ↗
29. A facile energy-efficient approach to prepare super oil-sorbent thin films10.1016/j.egyr.2022.12.098 ↗
30. Effect of surface composition and roughness on the apparent surface free energy of silica aerogel materials10.1063/1.3635398 ↗
31. Adsorption of methylene blue by kapok fiber treated by sodium chlorite optimized with response surface methodology10.1016/j.cej.2012.01.049 ↗
32. Investigation of acetylated kapok fibers on the sorption of oil in water10.1016/S1001-0742(12)60031-X ↗
33. Exploring the potential of Desert Rose fibers (Adenium obesum) for the remediation of oil-contaminated sites10.1016/j.jwpe.2024.106390 ↗