Achieving exceptional strength-ductility synergy in additively manufactured Hastelloy X superalloys by stabilizing cellular structures via Ta addition
Source abstract
Abstract
Abstract Additive manufacturing of Hastelloy X superalloys remains challenges for practical aerospace applications due to the inadequate mechanical property at both ambient and high temperatures. To this end, this work proposes a novel Ta-modified strategy manipulating elemental segregation to stabilize cellular structures, thereby obtaining an outstanding combination between strength and ductility across a wide temperature regime. In particular, the tensile strength and elongation of Ta-modified superalloys can reach up to 1 214 MPa and 28.4%, respectively, highly increased by 47% and 10% compared to original Hastelloy X superalloys at 25 ℃. Meanwhile, the tensile strength and elongation at 650 ℃ significantly increase to 843 MPa and 26.8% respectively, 38% and 150% stronger than their counterparts of the original Ta-free Hastelloy X superalloys at identical conditions. Microstructural observations reveal that prominent local segregation of Ta/Mo elements and in situ MC precipitates along cellular boundaries synergistically enhanced the stability of cellular structures. The stabilized cellular structures serve as continuous and skeleton-like networks during deformation, synergistically contributing to outstanding ductility and enhanced mechanical strength, as well as sustained strain-hardening ability. The present work provides new insights into an efficient alloy design method for additively manufactured nickel-based superalloys with outstanding mechanical property within a wide temperature regime.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Additive Manufacturing Materials and Processes · Cellular and Composite Structures · High Temperature Alloys and Creep
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Laser powder bed fusion of GH3536 nickel-based superalloys: processing parameters, microstructure and mechanical properties10.1016/j.matchar.2023.113018 ↗
2. Two-step heat treatment for laser powder bed fusion of a nickel-based superalloy with simultaneously enhanced tensile strength and ductility10.1016/j.addma.2021.102168 ↗
3. Selective laser melting of GH3536 superalloy: microstructure, mechanical properties, and hydrocyclone manufacturing10.1016/j.apmate.2023.100134 ↗
4. Additive manufacturing of metals10.1016/j.actamat.2016.07.019 ↗
5. A defect-resistant Co-Ni superalloy for 3D printing10.1038/s41467-020-18775-0 ↗
6. Review on laser directed energy deposited aluminum alloys10.1088/2631-7990/ad16bb ↗
7. Mechanical field assisted additive manufacturing of ultrahigh strength aluminum alloy10.1088/2631-7990/adbb95 ↗
8. Additive manufacturing of heat-resistant aluminum alloys: a review10.1088/2631-7990/ad7f2e ↗
9. Laser powder bed fusion of Mo2C/Ti-6Al-4V composites with alternately laminated α′/β phases for enhanced mechanical properties10.1016/j.addma.2021.102134 ↗
10. Residual stress accumulation in large-scale Ti-6Al-4V wire-arc additive manufacturing10.1016/j.procir.2023.09.247 ↗
11. Recent innovations in laser additive manufacturing of titanium alloys10.1088/2631-7990/ad2545 ↗
12. Study of the intrinsic mechanisms of nickel additive for grain refinement and strength enhancement of laser aided additively manufactured Ti-6Al-4V10.1088/2631-7990/ac6b61 ↗
13. Enhancing plasticity in laser additive manufactured high-entropy alloys: the combined effect of thermal cycle induced dissolution and twinning10.1016/j.addma.2024.104427 ↗
14. Multiscale plastic deformation in additively manufactured FeCoCrNiMox high-entropy alloys to achieve strength–ductility synergy at elevated temperatures10.1016/j.ijplas.2024.104142 ↗
15. Fabrication of a strong and ductile FeCoCrNiMo0.3 high-entropy alloy with a micro-nano precipitate framework via laser powder bed fusion10.1016/j.compositesb.2023.111006 ↗
16. Effect of solution treatment on the microstructure, phase transformation behavior and functional properties of NiTiNb ternary shape memory alloys fabricated via laser powder bed fusion in-situ alloying10.1088/2631-7990/ad35fc ↗
17. Laser powder bed fusion additive manufacturing of NiTi shape memory alloys: a review10.1088/2631-7990/acc7d9 ↗
18. Mechanical property and biological behaviour of additive manufactured TiNi functionally graded lattice structure10.1088/2631-7990/ac94fa ↗
19. Additively manufactured crack-free nickel-based superalloy with synergistic strength and plasticity via grain refinement and striped oxides inhibition10.1016/j.compositesb.2024.112038 ↗
20. In-situ remelting induced healing of cracks and strength-ductility synergy in additively manufactured Haynes 230 alloy10.1016/j.addma.2025.104638 ↗
21. Alloys-by-design: application to new superalloys for additive manufacturing10.1016/j.actamat.2020.09.023 ↗
22. Additive manufacturing of Ni-based superalloys: residual stress, mechanisms of crack formation and strategies for crack inhibition10.1016/j.nanoms.2022.08.001 ↗
23. Delineating dislocation structures and residual stresses in additively manufactured alloys10.1016/j.actamat.2023.119413 ↗
24. Cracking mechanism of Hastelloy X superalloy during directed energy deposition additive manufacturing10.1016/j.addma.2022.102792 ↗
25. The effect of subsequent heating treatment on the microstructure and mechanical properties of additive manufactured Hastelloy X alloy10.1016/j.matchar.2022.111799 ↗
26. Effect of process parameters on the mechanical properties of Hastelloy X alloy fabricated by selective laser melting10.1007/s11665-019-04275-w ↗
27. Improving the strength–ductility of laser powder bed fusion René 104 through high-density stacking faults induced by Sc and Y microalloying10.1016/j.jmst.2024.01.010 ↗
28. New alloy design approach to inhibiting hot cracking in laser additive manufactured nickel-based superalloys10.1016/j.actamat.2023.118736 ↗
29. Additive manufacturing of high-strength crack-free Ni-based Hastelloy X superalloy10.1016/j.addma.2019.100919 ↗
30. Compositional regulation in additive manufacturing of precipitation-hardening (CoCrNi)94Ti3Al3 medium-entropy superalloy: cellular structure stabilization and strength enhancement10.1016/j.compositesb.2024.111570 ↗
31. New insights on cellular structures strengthening mechanisms and thermal stability of an austenitic stainless steel fabricated by laser powder-bed-fusion10.1016/j.actamat.2020.11.018 ↗
32. Cracking behaviour and its suppression mechanisms with TiB2 additions in the laser additive manufacturing of solid-solution-strengthened Ni-based alloys10.1016/j.compositesb.2023.111023 ↗
33. Modelling of additive manufacturability of nickel-based superalloys for laser powder bed fusion10.1016/j.actamat.2022.118307 ↗
34. Microstructure and mechanical behavior of additively manufactured CoCrFeMnNi high-entropy alloys: laser directed energy deposition versus powder bed fusion10.1016/j.actamat.2023.118884 ↗
35. Effect of Ta addition on the microstructure and tensile properties of a Ni-Co base superalloy10.1007/s11661-020-06081-9 ↗
36. High-throughput investigation of Nb and Ta alloying effects on the microstructure and properties of a novel Ni-Co-based superalloy10.1016/j.scriptamat.2022.115215 ↗
37. Influence of Ta content on microstructure and creep behavior of a Ni-Co base disc superalloy10.1016/j.msea.2020.140646 ↗
38. Enhancing microstructural stability and creep properties by Ta addition in Ni-based single crystal superalloys10.1016/j.msea.2024.146873 ↗
39. Investigation of microstructure and mechanical property of a novel SLM Ni-Co-based superalloys with Ta addition10.1016/j.matchar.2023.113229 ↗
40. Nanoscale L12 phase precipitation induced superb ambient and high temperature mechanical properties in Ni–Co–Cr–Al system high-entropy superalloys10.1016/j.msea.2023.145995 ↗
41. Effect of Hf and Ta on the tensile properties of PM Ni-based superalloys10.1016/j.jallcom.2022.167653 ↗
42. Unique crystallographic texture formation in Inconel 718 by laser powder bed fusion and its effect on mechanical anisotropy10.1016/j.actamat.2021.116876 ↗
43. Selective laser melting of an equiatomic CoCrFeMnNi high-entropy alloy: processability, non-equilibrium microstructure and mechanical property10.1016/j.jallcom.2018.02.298 ↗
44. Effect of the scanning strategy on microstructure and mechanical anisotropy of Hastelloy X superalloy produced by laser powder bed fusion10.1016/j.matchar.2021.110951 ↗
45. Manipulating stacking fault energy to achieve crack inhibition and superior strength-ductility synergy in an additively manufactured high-entropy alloy10.1002/adma.202310160 ↗
46. Effects of TiC content on microstructure and mechanical properties of nickel-based hastelloy X nanocomposites manufactured by selective laser melting10.1016/j.msea.2020.140008 ↗
47. Selective laser melting of Hastelloy X nanocomposite: effects of TiC reinforcement on crack elimination and strength improvement10.1016/j.compositesb.2020.108442 ↗
48. Design of a novel crack-free precipitation-strengthened nickel-based superalloy and composites for laser powder bed fusion10.1080/17452759.2023.2224769 ↗
49. High temperature thermal and mechanical stability of high-strength nanotwinned Al alloys10.1016/j.actamat.2018.11.011 ↗
50. Investigation of microstructures and strengthening mechanisms in an N-doped Co-Cr-Mo alloy fabricated by laser powder bed fusion10.1080/17452759.2023.2219665 ↗
51. Anisotropic response in mechanical and corrosion properties of hastelloy X fabricated by selective laser melting10.1016/j.conbuildmat.2019.06.132 ↗
52. Crack elimination and mechanical properties enhancement in additive manufactured Hastelloy X via in-situ chemical doping of Y2O310.1016/j.msea.2021.141867 ↗
53. Effect of temperature on the microstructure and tensile properties of micro-crack free hastelloy X produced by selective laser melting10.1016/j.addma.2019.100995 ↗
54. Effects of micrometer-sized TiB2 on crack mitigation, mechanical and electrochemical performance of a Ni-based alloy fabricated by selective laser melting10.1016/j.optlastec.2021.107240 ↗
55. Effects of TiB2 content on the processability and mechanical performance of Hastelloy-X based composites fabricated by selective laser melting10.1016/j.optlastec.2022.108441 ↗
56. Influence of post heat treatments on anisotropy of mechanical behaviour and microstructure of Hastelloy-X parts produced by selective laser melting10.1016/j.msea.2016.04.086 ↗
57. Mechanical property study on rapid additive layer manufacture Hastelloy® X alloy by selective laser melting technology10.1007/s00170-011-3423-2 ↗
58. Microstructure and mechanical properties at room and elevated temperature of crack-free Hastelloy X fabricated by laser powder bed fusion10.1016/j.msea.2020.139177 ↗
59. Reduction of micro-cracking in nickel superalloys processed by selective laser melting: a fundamental alloy design approach10.1016/j.actamat.2015.04.035 ↗
60. The role of overlap region width in multi-laser powder bed fusion of Hastelloy X superalloy10.1080/17452759.2022.2142802 ↗
61. Room and elevated temperature tensile and fatigue behaviour of additively manufactured Hastelloy X10.1016/j.msea.2023.145479 ↗
62. Davis · 2000
63. Laser powder bed fusion of Ni-based Hastelloy X superalloy: microstructure, anisotropic mechanical properties and strengthening mechanisms10.1016/j.msea.2021.142076 ↗
64. Deformation behaviour of additively manufactured Hastelloy X at high temperatures: the role of concurrent carbide precipitation10.1016/j.jallcom.2025.179636 ↗
65. Strength-ductility synergy of additively-manufactured GH3536 superalloys achieved by dual-heterostructures10.1016/j.jmst.2025.02.079 ↗
66. Laser powder bed fusion of advanced submicrometer TiB2 reinforced high-performance Ni-based composite10.1016/j.msea.2021.141416 ↗
67. Exceptional strength-ductility combination of additively manufactured high-entropy alloy matrix composites reinforced with TiC nanoparticles at room and cryogenic temperatures10.1016/j.addma.2022.102918 ↗
68. Modulating hierarchical microstructural components to enhance strength-ductility synergy of a high-entropy alloy containing brittle sigma phase10.1016/j.msea.2024.146511 ↗
69. Enhanced fatigue resistance and fatigue-induced substructures in an additively manufactured CoCrNi medium-entropy alloy treated by ultrasonic surface rolling process10.1016/j.ijplas.2023.103721 ↗
70. Local element segregation-induced cellular structures and dominant dislocation planar slip enable exceptional strength-ductility synergy in an additively-manufactured CoNiV multicomponent alloy with ageing treatment10.1016/j.ijplas.2024.104112 ↗
71. Chromium gradient stainless steels with simultaneous high strength, ductility, and corrosion-resistant: in-depth study of continuous hardening mechanisms10.1016/j.ijplas.2024.104082 ↗
72. The Portevin–Le Chatelier (PLC) effect and shear band formation in an AA5754 alloy10.1016/j.actamat.2007.03.007 ↗
73. Origins of strengthening and toughening effects in twinned nanocrystalline alloys of low stacking fault energy with heterogeneous grain structure10.1016/j.jmps.2023.105305 ↗
74. Enhancing strength and strain hardenability via deformation twinning in fcc-based high entropy alloys reinforced with intermetallic compounds10.1016/j.actamat.2018.12.010 ↗
75. Ultra-strong and ductile precipitation-strengthened high entropy alloy with 0.5 % Nb addition produced by laser additive manufacturing10.1016/j.jmst.2023.11.053 ↗
76. Effect of heat treatment on microstructural heterogeneity and mechanical properties of 1%C-CoCrFeMnNi alloy fabricated by selective laser melting10.1016/j.addma.2021.102283 ↗
77. CALPHAD-aided design for superior thermal stability and mechanical behavior in a TiZrHfNb refractory high-entropy alloy10.1016/j.actamat.2023.118728 ↗
78. 3D printing of high-strength aluminium alloys10.1038/nature23894 ↗
79. Kurz · 1992
80. Modelling of inoculation of metallic melts: application to grain refinement of aluminium by Al–Ti–B10.1016/S1359-6454(00)00094-X ↗
81. Demonstrating the roles of solute and nucleant in grain refinement of additively manufactured aluminium alloys10.1016/j.addma.2021.102516 ↗
82. Investigation of strengthening mechanisms in an additively manufactured Haynes 230 alloy10.1016/j.actamat.2021.117404 ↗
83. Deformation mechanisms of additively manufactured TiNbTaZrMo refractory high-entropy alloy: the role of cellular structure10.1016/j.ijplas.2024.103884 ↗
84. In-situ preparation and formation of TiB/Ti-6Al-4V nanocomposite via laser additive manufacturing: microstructure evolution and tribological behavior10.1016/j.powtec.2018.09.088 ↗
85. Solute enrichment induced dendritic fragmentation in directional solidification of nickel-based superalloys10.1016/j.actamat.2021.117043 ↗
86. Solute trapping and non-equilibrium microstructure during rapid solidification of additive manufacturing10.1038/s41467-023-43563-x ↗
87. Nanoindentation creep behavior of diverse microstructures in a pre-strained interstitial high-entropy alloy by high-throughput mapping10.1016/j.msea.2022.143988 ↗
88. Inhibiting cracking and improving strength for additive manufactured AlxCoCrFeNi high entropy alloy via changing crystal structure from BCC-to-FCC10.1016/j.addma.2023.103584 ↗
89. Laser powder bed fusion of Al-Mg-Zr alloy: microstructure, mechanical properties and dynamic precipitation10.1016/j.msea.2022.144181 ↗
90. Additive manufacturing of ultrastrong and ductile nickel matrix composites via hetero-deformation induced strengthening10.1088/2631-7990/adbb32 ↗
91. Achieving well-balanced strength and ductility in laser powder bed fusion additively manufactured nickel-based superalloys by doping multiple oxides10.1016/j.msea.2023.145773 ↗
92. Effect of solution heat treatment and hot isostatic pressing on the microstructure and mechanical properties of Hastelloy X manufactured by electron beam powder bed fusion10.1016/j.jmst.2021.04.059 ↗
93. Hall-Petch breakdown at elevated temperatures10.2320/matertrans.MA201309 ↗
94. Role of heat treatment and build orientation in the microstructure sensitive deformation characteristics of IN718 produced via SLM additive manufacturing10.1016/j.addma.2018.04.032 ↗
95. Grain boundary network evolution in Inconel 718 from selective laser melting to heat treatment10.1016/j.msea.2018.04.045 ↗
96. Heterophase interface-mediated formation of nanotwins and 9R phase in aluminum: underlying mechanisms and strengthening effect10.1016/j.actamat.2019.05.053 ↗
97. Kinetics of annealing-induced detwinning in chemical vapor deposited nickel10.1016/j.actamat.2019.08.010 ↗
98. Slip transmission assisted by Shockley partials across α/β interfaces in Ti-alloys10.1016/j.actamat.2019.04.013 ↗
99. Gradient cell–structured high-entropy alloy with exceptional strength and ductility10.1126/science.abj8114 ↗
100. Correlation between microstructure evolution and mechanical response in a moderately low stacking-fault-energy austenitic Fe–Mn–Si–Al alloy during low-cycle fatigue deformation10.1016/j.msea.2021.141766 ↗