journal article·2026-10-01Open access

A dual-functional curcumin strategy for light scattering mitigation in high-fidelity DLP ceramic 3D printing

Mingyue Cao, Wenxin Wang, Xingyu Yang, Wei Zhu, Xiaolong Zhu, Yinfeng He, Feng Chen, Xiaoxiao Han

Abstract

Abstract Light scattering remains a critical barrier in digital light processing (DLP)-based ceramic additive manufacturing, particularly for achieving high precision, fine resolution, and complex geometries. In this study, we present a novel light scattering mitigation strategy by incorporating a multifunctional reactive additive that combines physical light absorption near 405 nm and chemical free radical scavenging. Curcumin effectively suppresses undesired photopolymerization in non-target regions by neutralizing scattered-light-generated radicals, enabling the fabrication of intricate structures with dimensional fidelity approaching the optical resolution limit (∼2.6 pixels). The strategy operates effectively at low concentrations (0.01 wt%) without requiring process parameter tuning, offering a broad process window and high reproducibility. Furthermore, the strategy is generalizable across diverse ceramic systems, including light-colored ceramics (Al 2 O 3 , ZrO 2 , and SiO 2 ), and dark-colored ceramics (SiC) that are particularly susceptible to scattering. The geometric error of printed SiC components remains below 10% even at high exposure doses of 80 and 100 mJ · cm −2 , effectively addressing the long-standing trade-off between curing depth and lateral resolution. This work provides a simple, scalable, and versatile approach for improving resolution in DLP ceramic printing, advancing the reliable production of fine-scale (<50 μm) ceramic architectures for applications in biomedicine, microelectronics, and precision engineering.
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Research context

OpenAlex topics: Additive Manufacturing and 3D Printing Technologies · Pigment Synthesis and Properties · 3D Printing in Biomedical Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Hunan University

University of Nottingham

Funding

the National Key Research and Development program · The science and technology innovation Program of Hunan Province · the Hunan Provincial Graduate Student Scientific Research and Innovation Project · the Natural Science Foundation of Hunan Province · the National Natural Science Youth Foundation of China

References (60)

Show source-provided references
1. 3D printing of layered ceramic/carbon fiber composite with improved toughness10.1016/j.addma.2021.102543 ↗
2. 4D additive–subtractive manufacturing of shape memory ceramics10.1002/adma.202302108 ↗
3. A review on additive manufacturing of ceramic matrix composites10.1016/j.jmst.2022.06.039 ↗
4. Fabrication of dense cordierite ceramics with high mechanical properties via interlayer defect-free digital light processing (DLP)10.1016/j.ceramint.2025.04.031 ↗
5. Extrusion‐based additive manufacturing of carbonaceous and non‐carbonaceous electrode materials for electrochemical energy storage devices10.1002/admt.202400136 ↗
6. An overview on ceramic multi-material additive manufacturing: progress and challenges10.1088/2631-7990/adbc75 ↗
7. Low-temperature fabrication of high-specific strength SiC-based ceramics via photopolymerization 3D printing with controllable anisotropy10.1088/2631-7990/add2e1 ↗
8. Digital light processing based multimaterial 3D printing: challenges, solutions and perspectives10.1088/2631-7990/ad4a2c ↗
9. Manufacturing and characterization of dental crowns made of 5-mol% yttria stabilized zirconia by digital light processing10.3390/ma16041447 ↗
10. Vat photopolymerization of Al2O3/borosilicate glass low temperature co-fired ceramic substrates with integrated micropore patterning device10.1109/TMAT.2025.3598753 ↗
11. High-precision BaTiO3 piezoelectric ceramics via vat photopolymerization 3D printing10.1016/j.jeurceramsoc.2024.116706 ↗
12. A novel wearable device integrating ECG and PCG for cardiac health monitoring10.1038/s41378-024-00858-3 ↗
13. Ultra-miniaturized, high-performance filters on alumina ribbon ceramic substrates for 5G small-cell applications10.1109/TCPMT.2024.3370725 ↗
14. Novel screen-printed ceramic MEMS microhotplate for MOS sensors10.1016/j.sna.2024.115907 ↗
15. Integrated 1×3 MEMS silicon nitride photonics switch10.1364/OE.460533 ↗
16. Slippery hydrogel with desiccation-tolerant ‘skin’ for high-precision additive manufacturing10.1088/2631-7990/ad1730 ↗
17. Photoinhibiting via simultaneous photoabsorption and free-radical reaction for high-fidelity light-based bioprinting10.1038/s41467-023-38838-2 ↗
18. Transparent pyrochlore ceramics–optical properties of pyrochlores and light scattering study10.1016/j.jeurceramsoc.2023.09.049 ↗
19. Efficient light-based bioprinting via Rutin nanoparticle photoinhibitor for advanced biomedical applications10.1021/acsnano.4c05380 ↗
20. High‐precision 3D printing of high‐strength polymer‐derived ceramics: impact of precursor’s molecular structure10.1002/adem.202200269 ↗
21. Accuracy controlling and mechanical behaviors of precursor-derived ceramic SiOC microlattices by projection micro stereolithography (PμSL) 3D printing10.26599/JAC.2023.9220818 ↗
22. Forming deviation coupling model and control method in the photopolymerization process of ceramic slurry10.1016/j.ceramint.2023.12.184 ↗
23. Effects of a UV absorber in silica-loaded resin on DLP silica fiber preform fabrication10.1364/AO.516246 ↗
24. Improving cure performance of Si3N4 suspension with a high refractive index resin for stereolithography-based additive manufacturing10.1016/j.ceramint.2022.01.124 ↗
25. The cure performance of modified ZrO2 coated by paraffin via projection based stereolithography10.1016/j.ceramint.2018.10.003 ↗
26. Light scattering in absorbing ceramic suspensions: effect on the width and depth of photopolymerized features10.1016/j.jeurceramsoc.2014.12.006 ↗
27. Flashing light curing strategy for shape fidelity improvement in photopolymerization-based ceramic additive manufacturing10.1016/j.addma.2025.104726 ↗
28. Mechanism of ceramic slurry light scattering affecting contour accuracy and method of projection plane correction10.1016/j.ceramint.2023.01.085 ↗
29. Mitigating scattering effects in light-based three-dimensional printing using machine learning10.1115/1.4046986 ↗
30. Enhancement of solubility, stability, cellular uptake, and bioactivity of curcumin by polyvinyl alcohol10.3390/ijms25116278 ↗
31. Curcumin as a photosensitizer: from molecular structure to recent advances in antimicrobial photodynamic therapy10.1016/j.jphotochemrev.2020.100384 ↗
32. Photostabilities and anti-tumor effects of curcumin and curcumin-loaded polydopamine nanoparticles10.1039/D4RA01246A ↗
33. Stereolithography-based additive manufacturing of lightweight and high-strength Cf/SiC ceramics10.1016/j.addma.2020.101199 ↗
34. Acrylate‐based photosensitive resin for stereolithographic three‐dimensional printing10.1002/app.47487 ↗
35. Ceramic 3D printing via dye-sensitized photopolymerization under green LED10.1089/3dp.2021.0204 ↗
36. Curcumin nanoparticles as a multipurpose additive to achieve high-fidelity SLA-3D printing and controlled delivery10.1016/j.bioadv.2023.213527 ↗
37. Effects of UV absorber on zirconia fabricated with digital light processing additive manufacturing10.3390/ma15248726 ↗
38. Molecular design of curcumin analogues with potent antioxidant properties and thermodynamic evaluation of their mechanism of free radical scavenge10.1186/s42269-020-00391-z ↗
39. Free radical inhibition using a water-soluble curcumin complex, NDS27: mechanism study using EPR, chemiluminescence, and docking10.3390/antiox13010080 ↗
40. Facilely prepared blue-green light sensitive curcuminoids with excellent bleaching properties as high performance photosensitizers in cationic and free radical photopolymerization10.1039/C8PY00166A ↗
41. Biomacromolecule-based agent for high-precision light-based 3D hydrogel bioprinting10.1016/j.xcrp.2022.100985 ↗
42. High-resolution projection-based 3D bioprinting10.1038/s44222-024-00218-w ↗
43. High-precision and high-strength SiC ceramic green body by stereolithography: slurry design and defect control10.1016/j.jallcom.2025.180860 ↗
44. SiC paste with high curing thickness for stereolithography10.1016/j.ceramint.2022.06.183 ↗
45. Stereolithography‐based additive manufacturing of gray‐colored SiC ceramic green body10.1111/jace.16648 ↗
46. Additive manufacturing of bioceramic implants for restoration bone engineering: technologies, advances, and future perspectives10.1021/acsbiomaterials.2c01164 ↗
47. High-fidelity 3D printing using flashing photopolymerization10.1016/j.addma.2019.100834 ↗
48. Combinations of photoinitiator and UV absorber for cell-based digital light processing (DLP) bioprinting10.1088/1758-5090/abfd7a ↗
49. High‐resolution projection microstereolithography for patterning of neovasculature10.1002/adhm.201500721 ↗
50. Vat photopolymerization 3D printing of polymer-derived SiOC ceramics with high precision and high strength10.1016/j.addma.2023.103889 ↗
51. Ultrastrong and damage-tolerant ceramic architectures via 3D printing10.1016/j.addma.2022.103361 ↗
52. Liquid crystal display technique (LCD) for high resolution 3D printing of triply periodic minimal surface lattices bioceramics10.1016/j.addma.2023.103720 ↗
53. Thermal debinding for stereolithography additive manufacturing of advanced ceramic parts: a comprehensive review10.1016/j.matdes.2024.112632 ↗
54. Effect of non-reactive diluent on defect-free debinding process of 3D printed ceramics10.1016/j.addma.2023.103475 ↗
55. Study on defect-free debinding green body of ceramic formed by DLP technology10.1016/j.ceramint.2019.09.237 ↗
56. Preparation of a defect-free alumina cutting tool via additive manufacturing based on stereolithography–optimization of the drying and debinding processes10.1016/j.ceramint.2016.04.050 ↗
57. Enhanced curing behavior, mechanical and thermal properties of 3D printed aluminum nitride ceramics using a powder coating strategy10.1016/j.addma.2023.103732 ↗
58. Fabrication of complex-shaped zirconia ceramic parts via a DLP-stereolithography-based 3D printing method10.1016/j.ceramint.2017.11.135 ↗
59. Effects of fine grains and sintering additives on stereolithography additive manufactured Al2O3 ceramic10.1016/j.ceramint.2020.09.071 ↗
60. Micro-fabrication of ceramics: additive manufacturing and conventional technologies10.1007/s40145-020-0422-5 ↗