journal article·2024-11-01Open access

Prediction of the R3 Test-Based Reactivity of Supplementary Cementitious Materials: A Machine Learning Approach Utilizing Physical and Chemical Properties

Jinyoung Yoon, Aidarus Yonis, Sungwoo Park, Farshad Rajabipour, Sukhoon Pyo

Abstract

Abstract This study utilized machine learning (ML) models to investigate the effect of physical and chemical properties on the reactivity of various supplementary cementitious materials (SCMs). Six SCMs, including ground granulated blast furnace slag (GGBFS), pulverized coal fly ash (FA), and ground bottom ash (BA), underwent thorough material characterization and reactivity tests, incorporating the modified strength activity index (ASTM C311) and the R3 (ASTM C1897) tests. A data set comprising 46 entries, derived from both experimental results and literature sources, was employed to train ML models, specifically artificial neural network (ANN), support vector machine (SVM), and random forest (RF). The results demonstrated the robustness of the ANN model, achieving superior prediction accuracy with a testing mean absolute error (MAE) of 9.6%, outperforming SVM and RF models. The study classified SCMs into reactivity classes based on correlation analysis, establishes a comprehensive database linking material properties to reactivity, and identifies key input parameters for predictive modeling. While most SCMs exhibited consistent predictions across types, GGBFS displayed significant variations, prompting a recommendation for the inclusion of additional input parameters, such as fineness, to enhance predictive accuracy. This research provided valuable insights into predicting SCM reactivity, emphasizing the potential of ML models for informed material selection and optimization in concrete applications.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Concrete Properties and Behavior

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (52)

Show source-provided references
1. Al-Shmaisani, S., Kalina, R. D., Ferron, R. D., & Juenger, M. C. G. (2022). Comparison of SCM reactivity to performance in cement-based mixtures. Materials and Structures, 55(10), 1–20. https://doi.org/10.1617/S11527-022-02072-X/FIGURES/810.1617/S11527-022-02072-X/FIGURES/8 ↗
2. ASTM C188-17, Standard test method for density of hydraulic cement (2017).
3. ASTM C311/C311M-18, Standard test methods for sampling and testing fly ash or natural Pozzolans for use in portland-cement concrete (2018).
4. ASTM C618-19, Standard specification for coal fly ash and raw or calcined natural Pozzolan for use in concrete (2019).
5. ASTM C1897-20, Standard test methods for measuring the reactivity of supplementary cementitious materials by isothermal calorimetry and bound water measurements (2020).
6. Avet, F., Li, X., Ben Haha, M., Bernal, S. A., Bishnoi, S., Cizer, Ö., et al. (2022). Report of RILEM TC 267-TRM phase 2: Optimization and testing of the robustness of the R3 reactivity tests for supplementary cementitious materials. Materials and Structures, 55(3), 1–14. https://doi.org/10.1617/S11527-022-01928-6/TABLES/610.1617/S11527-022-01928-6/TABLES/6 ↗
7. Avet, F., Snellings, R., Alujas Diaz, A., Ben Haha, M., & Scrivener, K. (2016). Development of a new rapid, relevant and reliable (R3) test method to evaluate the pozzolanic reactivity of calcined kaolinitic clays. Cement and Concrete Research, 85, 1–11. https://doi.org/10.1016/j.cemconres.2016.02.01510.1016/j.cemconres.2016.02.015 ↗
8. Blotevogel, S., Ehrenberg, A., Steger, L., Doussang, L., Kaknics, J., Patapy, C., & Cyr, M. (2020). Ability of the R3 test to evaluate differences in early age reactivity of 16 industrial ground granulated blast furnace slags (GGBS). Cement and Concrete Research, 130, 105998. https://doi.org/10.1016/J.CEMCONRES.2020.10599810.1016/J.CEMCONRES.2020.105998 ↗
9. Breiman, L. (2001). Random forests. Machine Learning.
10. Cortes, C., & Vapnik, V. (1995). Support-vector networks. Machine Learning., 20, 237.10.1007/BF00994018 ↗
11. de Azevedo Basto, P., Estolano de Lima, V., & de Melo Neto, A. (2023). Capability of R3 test to evaluate pozzolanicity of ground raw and calcined sugarcane bagasse ashes. Materials Today Proceedings. https://doi.org/10.1016/J.MATPR.2023.04.04810.1016/J.MATPR.2023.04.048 ↗
12. de Chapelle, J. (1958). Attaque sulfocalcique des laitiers et pouzzolanes. Revue Des Materiaux De Construction, 512, 136–145.
13. Dhandapani, Y., Santhanam, M., Kaladharan, G., & Ramanathan, S. (2021). Towards ternary binders involving limestone additions—A review. Cement and Concrete Research, 143, 106396. https://doi.org/10.1016/J.CEMCONRES.2021.10639610.1016/J.CEMCONRES.2021.106396 ↗
14. Donatello, S., Tyrer, M., & Cheeseman, C. R. (2010). Comparison of test methods to assess pozzolanic activity. Cement and Concrete Composites, 32(2), 121–127. https://doi.org/10.1016/j.cemconcomp.2009.10.00810.1016/j.cemconcomp.2009.10.008 ↗
15. EN 196-5. Standard methods for testing cement. Part 5: Pozzolanicity test for pozzolanic cements (1988).
16. Eskandari-Naddaf, H., & Kazemi, R. (2017). ANN prediction of cement mortar compressive strength, influence of cement strength class. Construction and Building Materials, 138, 1–11.10.1016/j.conbuildmat.2017.01.132 ↗
17. Flegar, M., Serdar, M., Londono-Zuluaga, D., & Scrivener, K. (2020). Regional waste streams as potential raw materials for immediate implementation in cement production. Materials, 13(23), 5456. https://doi.org/10.3390/MA1323545610.3390/MA13235456 ↗
18. Frattini, N. (1949). Richerche sulla calce di idrolisi nelle paste di cimento. Annali di Chimica.
19. Han, Q., Gui, C., Xu, J., & Lacidogna, G. (2019). A generalized method to predict the compressive strength of high-performance concrete by improved random forest algorithm. Construction and Building Materials, 226, 734–742. https://doi.org/10.1016/J.CONBUILDMAT.2019.07.31510.1016/J.CONBUILDMAT.2019.07.315 ↗
20. Inorganic Chemistry Structure Databases (ICSD). (2012). https://icsd.products.fiz-karlsruhe.de/
21. Jafari, K., Yoon, J., Tokpatayeva, R., Olek, J., & Rajabipour, F. (2022). Surfactant-assisted purification of an impure kaolinite clay to improve its pozzolanic reactivity in concrete. Journal of Materials in Civil Engineering, 34(6), 04022094. https://doi.org/10.1061/(ASCE)MT.1943-5533.000421610.1061/(ASCE)MT.1943-5533.0004216 ↗
22. Kaladharan, G., Ghantous, R. M., & Rajabipour, F. (2023). Early age hydration behavior of portland cement-based binders incorporating fly ash contaminated with flue gas desulfurization products. Cement and Concrete Composites, 139, 105062. https://doi.org/10.1016/J.CEMCONCOMP.2023.10506210.1016/J.CEMCONCOMP.2023.105062 ↗
23. Kasaniya, M., Alaibani, A., Thomas, M. D. A., & Riding, K. A. (2022). Exploring the efficacy of emerging reactivity tests in screening pozzolanic materials. Construction and Building Materials, 325, 126781. https://doi.org/10.1016/J.CONBUILDMAT.2022.12678110.1016/J.CONBUILDMAT.2022.126781 ↗
24. Kim, H. K. (2015). Utilization of sieved and ground coal bottom ash powders as a coarse binder in high-strength mortar to improve workability. Construction and Building Materials, 91, 57–64. https://doi.org/10.1016/j.conbuildmat.2015.05.01710.1016/j.conbuildmat.2015.05.017 ↗
25. Kim, Y. H., Kim, H. Y., Yang, K. H., & Ha, J. S. (2021). Effect of concrete unit weight on the mechanical properties of bottom ash aggregate concrete. Construction and Building Materials, 273, 121998. https://doi.org/10.1016/J.CONBUILDMAT.2020.12199810.1016/J.CONBUILDMAT.2020.121998 ↗
26. Lee, J. Y., Choi, J. S., Yuan, T. F., Yoon, Y. S., & Mitchell, D. (2019). Comparing properties of concrete containing electric arc furnace slag and granulated blast furnace slag. Materials, 12(9), 1371. https://doi.org/10.3390/MA1209137110.3390/MA12091371 ↗
27. Li, X., Snellings, R., Antoni, M., Alderete, N. M., Ben Haha, M., Bishnoi, S., et al. (2018). Reactivity tests for supplementary cementitious materials: RILEM TC 267-TRM phase 1. Materials and Structures, 51(6), 1–14. https://doi.org/10.1617/S11527-018-1269-X/TABLES/510.1617/S11527-018-1269-X/TABLES/5 ↗
28. Li, Z., Yoon, J., Zhang, R., Rajabipour, F., Srubar, W. V., Dabo, I., & Radlińska, A. (2022). Machine learning in concrete science: applications, challenges, and best practices. NPJ Computational Materials, 8(1), 1–17. https://doi.org/10.1038/s41524-022-00810-x10.1038/s41524-022-00810-x ↗
29. Londono-Zuluaga, D., Gholizadeh-Vayghan, A., Winnefeld, F., Avet, F., Ben Haha, M., Bernal, S. A., et al. (2022). Report of RILEM TC 267-TRM phase 3: Validation of the R3 reactivity test across a wide range of materials. Materials and Structures, 55(5), 1–16. https://doi.org/10.1617/S11527-022-01947-3/FIGURES/1010.1617/S11527-022-01947-3/FIGURES/10 ↗
30. Mehta, P. K., & Monteiro, P. J. M. (2013). Concrete: Microstructure, properties, and materials. McGraw Hill Professional.
31. PANalytical X’Pert HighScore Plus [Computer software], Lelyweg, Almelo, the Netherlands.
32. Parashar, A., & Bishnoi, S. (2020). A comparison of test methods to assess the strength potential of plain and blended supplementary cementitious materials. Construction and Building Materials, 256, 119292. https://doi.org/10.1016/J.CONBUILDMAT.2020.11929210.1016/J.CONBUILDMAT.2020.119292 ↗
33. Parashar, A., Medepalli, S., & Bishnoi, S. (2023). Reactivity assessment of supplementary cementitious materials and their binary blends using R3 test. Journal of Materials in Civil Engineering, 35(2), 04022434. https://doi.org/10.1061/(ASCE)MT.1943-5533.000460710.1061/(ASCE)MT.1943-5533.0004607 ↗
34. Pormmoon, P., Abdulmatin, A., Charoenwaiyachet, C., Tangchirapat, W., & Jaturapitakkul, C. (2021). Effect of cut-size particles on the pozzolanic property of bottom ash. Journal of Materials Research and Technology, 10, 240–249. https://doi.org/10.1016/J.JMRT.2020.12.01710.1016/J.JMRT.2020.12.017 ↗
35. Scarlett, N. V. Y., & Madsen, I. C. (2006). Quantification of phases with partial or no known crystal structures. Powder Diffraction, 21(4), 278–284. https://doi.org/10.1154/1.236285510.1154/1.2362855 ↗
36. Shiuly, A., Hazra, T., Sau, D., & Maji, D. (2022). Performance and optimisation study of waste plastic aggregate based sustainable concrete—A machine learning approach. Cleaner Waste Systems, 2, 100014. https://doi.org/10.1016/J.CLWAS.2022.10001410.1016/J.CLWAS.2022.100014 ↗
37. Singh, G. V. P. B., Asce, S. M., Subramaniam, K. V. L., & Asce, M. (2016). Quantitative XRD analysis of binary blends of siliceous fly ash and hydrated cement. Journal of Materials in Civil Engineering, 28(8), 04016042. https://doi.org/10.1061/(ASCE)MT.1943-5533.000155410.1061/(ASCE)MT.1943-5533.0001554 ↗
38. Sivakumar, P. P., Matthys, S., De Belie, N., & Gruyaert, E. (2021). Reactivity assessment of modified ferro silicate slag by R3 method. Applied Sciences, 11(1), 366. https://doi.org/10.3390/APP1101036610.3390/APP11010366 ↗
39. Tironi, A., Trezza, M. A., Scian, A. N., & Irassar, E. F. (2013). Assessment of pozzolanic activity of different calcined clays. Cement and Concrete Composites, 37(1), 319–327. https://doi.org/10.1016/j.cemconcomp.2013.01.00210.1016/j.cemconcomp.2013.01.002 ↗
40. Vashistha, P., Oinam, Y., Kim, H. K., & Pyo, S. (2023). Effect of thermo-mechanical activation of waste concrete powder (WCP) on the characteristics of cement mixtures. Construction and Building Materials, 362, 129713. https://doi.org/10.1016/J.CONBUILDMAT.2022.12971310.1016/J.CONBUILDMAT.2022.129713 ↗
41. Vayghan, A. G., Horckmans, L., Snellings, R., Peys, A., Teck, P., Maier, J., et al. (2021). Use of treated non-ferrous metallurgical slags as supplementary cementitious materials in cementitious mixtures. Applied Sciences, 11(9), 4028. https://doi.org/10.3390/APP1109402810.3390/APP11094028 ↗
42. Vladić Kancir, I., & Serdar, M. (2022). Contribution to understanding of synergy between red mud and common supplementary cementitious materials. Materials, 15(5), 1968. https://doi.org/10.3390/MA1505196810.3390/MA15051968 ↗
43. Walker, R., & Pavía, S. (2011). Physical properties and reactivity of pozzolans, and their influence on the properties of lime-pozzolan pastes. Materials and Structures, 44(6), 1139–1150. https://doi.org/10.1617/S11527-010-9689-2/FIGURES/810.1617/S11527-010-9689-2/FIGURES/8 ↗
44. Wang, Y. (2023). Reactivity and reactivity tests for unconventional fly ashes. University of Miami.
45. Wang, Y., Burris, L., Shearer, C. R., Hooton, D., & Suraneni, P. (2021). Strength activity index and bulk resistivity index modifications that differentiate inert and reactive materials. Cement and Concrete Composites, 124, 104240. https://doi.org/10.1016/J.CEMCONCOMP.2021.10424010.1016/J.CEMCONCOMP.2021.104240 ↗
46. Weise, K., Ukrainczyk, N., & Koenders, E. (2021). A mass balance approach for thermogravimetric analysis in pozzolanic reactivity R3 test and effect of drying methods. Materials, 14(19), 5859. https://doi.org/10.3390/MA1419585910.3390/MA14195859 ↗
47. Yoon, J., Jafari, K., Tokpatayeva, R., Peethamparan, S., Olek, J., & Rajabipour, F. (2022). Characterization and quantification of the pozzolanic reactivity of natural and non-conventional pozzolans. Cement and Concrete Composites, 133, 104708. https://doi.org/10.1016/J.CEMCONCOMP.2022.10470810.1016/J.CEMCONCOMP.2022.104708 ↗
48. Yoon, J., Kim, H., Ju, S., Li, Z., & Pyo, S. (2023). Framework for rapid characterization of fresh properties of cementitious materials using point cloud and machine learning. Construction and Building Materials, 400, 132647. https://doi.org/10.1016/J.CONBUILDMAT.2023.13264710.1016/J.CONBUILDMAT.2023.132647 ↗
49. Yoon, J. Y., Kim, H., Lee, Y.-J., & Sim, S.-H. (2019a). Prediction model for mechanical properties of lightweight aggregate concrete using artificial neural network. Materials, 12(17), 2678.10.3390/ma12172678 ↗
50. Yoon, J. Y., Lee, J. Y., & Kim, J. H. (2019b). Use of raw-state bottom ash for aggregates in construction materials. Journal of Material Cycles and Waste Management, 21, 1–12. https://doi.org/10.1007/s10163-019-00841-510.1007/s10163-019-00841-5 ↗
51. Yu, Y., Li, W., Li, J., & Nguyen, T. N. (2018). A novel optimised self-learning method for compressive strength prediction of high performance concrete. Construction and Building Materials, 184, 229–247.10.1016/j.conbuildmat.2018.06.219 ↗
52. Zhu, X., Zhang, M., Yang, K., Yu, L., & Yang, C. (2020). Setting behaviours and early-age microstructures of alkali-activated ground granulated blast furnace slag (GGBS) from different regions in China. Cement and Concrete Composites, 114, 103782. https://doi.org/10.1016/J.CEMCONCOMP.2020.10378210.1016/J.CEMCONCOMP.2020.103782 ↗