journal article·2019-01-26Open access

Surface Tracking of MgO/Epoxy Nanocomposites: Effect of Surface Hydrophobicity

Zhaoliang Xing, Chong Zhang, Xiangnan Hu, Panhui Guo, Jingyuan Zhang, Ziyue Wang, Kangning Wu, Jianying Li

Applied Sciences· Volume 9· Issue 3

Abstract

Surface tracking has been one of the challenges for outdoor organic insulations, in electronic and electrical devices. In this paper, surface tracking behavior of nano-MgO/epoxy composite samples were measured according to the standard IEC 60112. Improved tracking resistance was obtained in nanocomposites with an 18.75% uplift in the comparative tracking index, and a decrease of 58.20% in the surface ablation area at a fixed 425 V. It was observed that the tracking resistance and surface hydrophobicity shared the same tendency—both, the comparative tracking index and surface contact angle increased with an increase of the nanofiller content. Samples with better hydrophobicity exhibited a higher tracking resistance. It could be the case that the conductive pathway of contamination was harder to form, as a result there were fewer discharging processes. With the development of surface tracking, the surface contact angle abruptly decreased, at first, and tended to be constant, which was also accomplished with the failure of samples. In addition, reduced surface resistivity was also found in the nanocomposites, which was beneficial for releasing surface charges and inhibiting distortions in the electric fields.
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Research context

OpenAlex topics: High voltage insulation and dielectric phenomena · Dielectric materials and actuators · Power Transformer Diagnostics and Insulation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Advanced Transmission Technology, Global Energy Interconnection Research Institute Co. Ltd., Beijing 102211, China

State key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206, China

State Grid Corporation of China, Beijing 100031, China

Northwest Electric Power Design Institute Co., Ltd. of China Power Engineering Consulting Group, Xi’an 710075, China

State Key Laboratory of electrical insulation and Power Equipment, Xi’an 710049, China

Funding

State Key Laboratory of Advanced Power Transmission Technology · National Key Research and Development Program of China · Power Electronics Science and Education Development Program of Delta Group

References (31)

Show source-provided references
1. Kim, J., Lee, W., Kim, T., Kim, H., Seo, B., Lim, C., and Cheong, I. (2018). Synthesis of thermally stable reactive polyurethane and its physical effects in epoxy composites. Appl. Sci., 8.10.3390/app8091587 ↗
2. Electrical conductivity of chemically modified multiwalled carbon nanotube/epoxy composites10.1016/j.carbon.2004.08.015 ↗
3. Development of epoxy resin composites with high thermal conductivity10.1109/MEI.2010.5383936 ↗
4. Octasilsesquioxane-reinforced DGEBA and TGDDM epoxy nanocomposites: Characterization of thermal, dielectric and morphological properties10.1016/j.actamat.2010.02.008 ↗
5. Investigations of surface degradation of high-density polyethylene materials resulting from tracking, using physicochemical analysis10.1002/app.10260 ↗
6. Analysis of surface degradation of epoxy nanocomposite due to tracking under AC and DC voltages10.1016/j.polymdegradstab.2007.01.014 ↗
7. Effects of nano-SiO2 particles on surface tracking characteristics of silicone rubber composites10.1063/1.4895734 ↗
8. Surface treeing and segmented worm model of tracking behavior in MgO/Epoxy nanocomposites10.1109/TDEI.2018.007120 ↗
9. Effects of thermally conducting particles on resistance to tracking failure of polyimide/BN composites10.1109/TDEI.2014.004310 ↗
10. Nanometric dielectrics10.1109/94.326653 ↗
11. Frechette, M.F., Trudeau, M.L., Alamdari, H.D., and Boily, S. (2001, January 14–17). Introductory remarks on nanodielectrics. Proceedings of the 2001 Annual Report Conference on Electrical Insulation and Dielectric Phenomena (CEIDP), Kitchener, ON, Canada.
12. Proposal of a multi-core model for polymer nanocomposite dielectrics10.1109/TDEI.2005.1511092 ↗
13. Interfaces are the dominant feature of dielectrics at the nanometric level10.1109/TDEI.2004.1349779 ↗
14. Xie, Q., Fu, K., Liang, S., Liu, B., Lu, L., Yang, X., Huang, Z., and Lü, F. (2018). Micro-structure and thermomechanical properties of crosslinked epoxy composite modified by nano-SiO2: A molecular dynamics simulation. Polymers, 10.10.3390/polym10070801 ↗
15. Haleem, Y., Song, P., Liu, D., Wang, C., Gan, W., Saleem, M., and Song, L. (2016). The effect of high concentration and small size of nanodiamonds on the strength of interface and fracture properties in epoxy nanocomposite. Materials, 9.10.3390/ma9070507 ↗
16. Dombek, G., Nadolny, Z., and Marcinkowska, A. (2018). Effects of nanoparticles materials on heat transfer in electro-insulating liquids. Appl. Sci., 8.10.3390/app8122538 ↗
17. Li, Z., Su, J., Du, B., Hou, Z., and Han, C. (2018). Inhibition effect of graphene on space charge injection and accumulation in low-density polyethylene. Nanomaterials, 8.10.3390/nano8110956 ↗
18. Hassan, M., Abukmail, A., Hassiba, A., Mauritz, K., and Elzatahry, A. (2018). PVA/Chitosan/Silver nanoparticles electrospun nanocomposites: Molecular relaxations investigated by modern broadband dielectric spectroscopy. Nanomaterials, 8.10.3390/nano8110888 ↗
19. Thermal distribution analysis and suppression mechanism of carbonized tracking and erosion in silicone rubber/SiO2 nanocomposites10.1016/j.polymertesting.2018.07.013 ↗
20. Influence of surface charge on DC flashover characteristics of epoxy/BN nanocomposites10.1109/TDEI.2013.004137 ↗
21. Space charge trapping in electrical potential well caused by permanent and induced dipoles for LDPE/MgO nanocomposite10.1109/T-DEI.2008.4446746 ↗
22. Kawano, M., Murakami, Y., Nagao, M., Sekiguchi, Y., Reddy, C.C., and Murata, Y. (2009, January 19–23). Treeing breakdown phenomena in MgO/LDPE nanocomposite material. Proceedings of the 9th International Conference on Properties and Applications of Dielectric Materials (ICPADM), Harbin, China.10.1109/ICPADM.2009.5252202 ↗
23. Murata, Y., and Kanaoka, M. (2006, January 26–30). Development History of HVDC Extruded Cable with Nanocomposite Material. Proceedings of the 8th International Conference on Properties and Applications of Dielectric Materials (ICPADM), Bali, Indonesia.10.1109/ICPADM.2006.284214 ↗
24. Assessment of the resistance to tracking of polymers in clean and salt fogs due to flashover arcs and partial discharges degrading conditions on one insulator model10.1049/iet-gtd.2015.0751 ↗
25. Dynamic behavior of water droplets and flashover characteristics on a superhydrophobic silicone rubber surface10.1063/1.4983714 ↗
26. Lu, J., Xie, P., Hu, J., Jiang, Z., and Fang, Z. (2018). AC flashover performance of 10 kV rod-plane air-gapped arresters under rain conditions. Energies, 11.10.3390/en11061563 ↗
27. Surface charge migration and dc surface flashover of surface-modified epoxy-based insulators10.1088/1361-6463/aa5207 ↗
28. Effects of surface roughness on surface charge accumulation characteristics and surface flashover performance of alumina-filled epoxy resin spacers10.1063/1.5043239 ↗
29. Chen, C., Wang, F., Chang, S., and Yang, C. (2018). Using oxygen plasma pretreatment to enhance the properties of F-doped ZnO films prepared on polyimide substrates. Materials, 11.10.3390/ma11091501 ↗
30. (2009). Method for Determining the Comparative and the Proof Tracking Indices of Solid Insulating Materials, International Electrotechnical Commission (IEC). IEC60112, Ed.4.
31. Motoyama, T., and Hackam, R. (2001, January 14–17). Effect of temperature and water salinity on hydrophobicity of epoxy resin. Proceedings of the 2001 Annual Report Conference on Electrical Insulation and Dielectric Phenomena (CEIDP), Kitchener, ON, Canada.