journal article·2019-06-27Open access

Effect of TiO2 Addition on Mortars: Characterization and Photoactivity

M. J. Hernández-Rodríguez, R. Santana Rodríguez, R. Darias, O. González Díaz, J. M. Pérez Luzardo, J. M. Doña Rodríguez, E. Pulido Melián

Applied Sciences· Volume 9· Issue 13

Abstract

In this study, mortar specimens were prepared with a cement:sand:water ratio of 1:3:0.5, in accordance with standard EN196-1. Portland CEM I 52.5 R grey (G) and white (W) cements were used, together with normalised sand and distilled water. Different amounts of TiO2 photocatalyst were incorporated in the preparation of the mortar samples. The effect of the addition of TiO2 was studied on mechanical properties of the mortar and cement including compressive and flexural strength, consistency (the flow table test), setting time and carbonation. Characterization techniques, including thermogravimetry, mercury porosimetry and X-ray diffraction spectroscopy (XRD), were applied to study the physico-chemical properties of the mortars. It was shown that adding the photocatalyst to the mortar had no negative effect on its properties and could be used to accelerate the setting process. Specimen photoactivity with the incorporated photocatalyst was tested for NOx oxidation in different conditions of humidity (0% RH and 65% RH) and illumination (Vis or Vis/UV), with the results showing an important activity even under Vis radiation.
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Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Grupo de Fotocatálisis y Espectroscopia para Aplicaciones Medioambientales (FEAM, Unidad Asociada al CSIC), Dpto. de Química, Instituto de Estudios Ambientales y Recursos Naturales (i-UNAT), Universidad de Las Palmas de Gran Canaria, 35017 Las Palmas de Gran Canaria, Spain

Departamento de Construcción Arquitectónica (Materiales Ecoestructurales), Universidad de Las Palmas de Gran Canaria, 35017 Las Palmas de Gran Canaria, Spain

Funding

Spanish Ministry of Economy and Competitiveness · Spanish Ministry of Economy and Competitiveness (co-funded by the ERDF)

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